White lighting device
According to the embodiment, a white lighting device includes a semiconductor light-emitting element emitting near-ultraviolet light, and a phosphor layer containing at least a blue-green phosphor emitting blue-green light and a red phosphor emitting red light and emits white light having a correlated color temperature of 5000 K or less and a deviation duv from a blackbody locus of not less than −0.01 nor more than 0.01, in which a ratio of a content of the red phosphor to a content of the blue-green phosphor in the phosphor layer by mass is not less than 35 nor more than 50.
1. A white lighting device, comprising:
a semiconductor light-emitting element emitting near-ultraviolet light; and
a phosphor layer containing a blue-green phosphor having an emission peak in a wavelength region of not less than 480 nm nor more than 520 nm, a red phosphor having an emission peak in a wavelength region of not less than 585 nm nor more than 630 nm, and two or more phosphors each having an emission peak in a wavelength region other than the wavelength regions and emits white light having a correlated color temperature of 5000 K or less and a deviation duv from a blackbody locus of not less than −0.01 nor more than 0.01,
wherein a ratio of a content of the red phosphor to a content of the blue-green phosphor in the phosphor layer by mass is not less than 35 nor more than 50.
2. The white lighting device according to claim 1 ,
wherein the blue-green phosphor is made of a europium-activated barium strontium orthosilicate phosphor having a composition represented by a general formula:
(Ba 1-x-y Sr x Eu y ) 2 SiO 4 (1)
where, x is a number satisfying 0≦x<0.5 and y is a number satisfying 0.005≦y<0.25.
3. The white lighting device according to claim 1 ,
wherein the red phosphor is made of a europium-activated lanthanum oxysulfide phosphor having a composition represented by a general formula:
(La 1-x-y Eu x M y ) 2 O 2 S (2)
where, M represents at least one element selected from Sm, Ga, Sb, and Sn, and x and y are numbers satisfying 0.008≦x<0.16 and 0.000001≦y<0.003.
4. The white lighting device according to claim 1 ,
wherein an average color rendering index Ra of the white light is equal to or more than 85 and a special color rendering index R9 of the white light is equal to or more than 85.
5. The white lighting device according to claim 1 ,
wherein an average color rendering index Ra of the white light is equal to or more than 90 and a special color rendering index R9 of the white light is equal to or more than 90.
6. The white lighting device according to claim 1 ,
wherein the semiconductor light-emitting element has an emission peak in a wavelength region of not less than 360 nm nor more than 440 nm.
7. The white lighting device according to claim 1 ,
wherein the semiconductor light-emitting element is a light-emitting diode or a laser diode.
8. The white lighting device according to claim 1 ,
wherein the two or more phosphors are a blue phosphor having an emission peak in a wavelength region of not less than 440 nm nor more than 460 nm and a yellow phosphor having an emission peak in a wavelength region of not less than 525 nm nor more than 575 nm.
9. The white lighting device according to claim 8 ,
wherein the blue phosphor is made of a europium-activated alkaline earth chlorophosphate phosphor having a composition represented by a general formula:
(Sr 1-x-y-z Ba x Ca y Eu z ) 5 (PO 4 ) 3 Cl (3)
where, x, y, and z are numbers satisfying 0≦x<0.45, 0≦y<0.03, and 0.005≦z<0.03.
10. The white lighting device according to claim 8 ,
wherein the yellow phosphor is made of a europium and manganese-activated alkaline earth magnesium silicate phosphor having a composition represented by a general formula:
(Sr 1-x-y-z-u Ba x Mg y Eu z Mn u ) 2 SiO 4 (4)
where, x, y, z and u are numbers satisfying 0.1≦x<0.35, 0.025≦y<0.105, 0.025≦z<0.25, and 0.0005≦u<0.02.