Flame-retardant polymer composition and article
View Patent ↗A flame-retardant polymer composition includes specific amounts of polyamide, acid-functionalized poly(phenylene ether), polyimide, and metal dialkylphosphinate. The composition, which exhibits improved flame retardancy and tensile modulus relative to known blends of poly(phenylene ether), polyamide, and polyimide, is useful for forming electrical components, such as photovoltaic junction boxes and connectors, inverter housings, automotive electrical connectors, electrical relays, and charge couplers.
1. A composition comprising the product of melt blending:
40 to 70 weight percent polyamide;
20 to 50 weight percent acid-functionalized poly(phenylene ether);
5 to 30 weight percent polyimide; and
an amount of metal dialkylphosphinate effective to provide a flammability rating of V-1 or V-0 in the 20 mm Vertical Burning Flame Test of Underwriter's Laboratory Bulletin 94 “Tests for Flammability of Plastic Materials, UL 94”;
wherein all weight percents are based on the total weight of the composition.
2. The composition of claim 1 , wherein the polyamide is selected from the group consisting of polyamide-6, polyamide-6,6, polyamide-4,6, polyamide-11, polyamide-12, polyamide-6,10, polyamide-6,12, polyamide 6/6,6, polyamide-6/6,12, polyamide MXD,6, polyamide-6,T, polyamide-6,I, polyamide-6/6,T, polyamide-6/6,I, polyamide-6,6/6,T, polyamide-6,6/6,I, polyamide-6/6,T/6,I, polyamide-6,6/6,T/6,I, polyamide-6/12/6,T, polyamide-6,6/12/6,T, polyamide-6/12/6,I, polyamide-6,6/12/6,I, and combinations thereof.
3. The composition of claim 1 , wherein the polyamide is selected from the group consisting of polyamide-6, polyamide-6,6, and combinations thereof.
4. The composition of claim 1 , wherein the polyamide comprises polyamide-6,6.
5. The composition of claim 1 , wherein the acid-functionalized poly(phenylene ether) is the product of melt blending 95 to 99.5 parts by weight of a poly(phenylene ether) with 0.5 to 5 parts by weight of a functionalizing agent selected from the group consisting of citric acid, fumaric acid, maleic acid, maleic anhydride, and combinations thereof.
6. The composition of claim 5 , wherein the poly(phenylene ether) comprises a homopolymer or copolymer of monomers selected from the group consisting of 2,6-dimethylphenol, 2,3,6-trimethylphenol, and combinations thereof.
7. The composition of claim 6 , comprising 4 to 15 weight percent of the metal dialkylphosphinate.
8. The composition of claim 5 , wherein the poly(phenylene ether) comprises a poly(phenylene ether)-polysiloxane block copolymer.
9. The composition of claim 8 , comprising 2 to 15 weight percent of the metal dialkylphosphinate.
10. The composition of claim 8 , wherein the poly(phenylene ether)-polysiloxane block copolymer contributes 0.4 to 4 weight percent of polysiloxane blocks to the composition.
11. The composition of claim 1 , wherein the polyimide comprises a polyetherimide comprising 10 to 1000 repeating units having the structure
wherein T is —O— or a group of the formula —O—Z—O— wherein the divalent bonds of the —O— or the —O—Z—O— group are in the 3,3′, 3,4′, 4,3′, or the 4,4′ positions, and wherein Z is selected from the group consisting of
wherein Q is divalent moiety selected from the group consisting of —O—, —S—, —C(O)—, —SO 2 —, —SO—, —C y H 2 — where y is 1 to 8, and —C p H q F r — where p is from 1 to 8, q is 0 to 15, r is 1 to 16, and q+r=2p.
12. The composition of claim 1 , further comprising 2 to 20 weight percent glass fibers.
13. The composition of claim 1 , comprising less than 2 weight percent glass fibers.
14. The composition of claim 1 ,
wherein the polyamide comprises polyamide-6,6;
wherein the polyamide amount is 42 to 50 weight percent;
wherein the acid-functionalized poly(phenylene ether) is the product of melt blending 96 to 99 parts by weight of a poly(phenylene ether) with 1 to 4 parts by weight of a functionalizing agent selected from the group consisting of citric acid, fumaric acid, maleic acid, maleic anhydride, and combinations thereof; wherein the poly(phenylene ether) comprises a homopolymer or copolymer of monomers selected from the group consisting of 2,6-dimethylphenol, 2,3,6-trimethylphenol, and combinations thereof;
wherein the acid-functionalized poly(phenylene ether) amount is 30 to 48 weight percent;
wherein the polyimide comprises a polyetherimide comprising 10 to 1000 repeating units having the structure
wherein T is —O— or a group of the formula —O—Z—O— wherein the divalent bonds of the —O— or the —O—Z—O— group are in the 3,3′, 3,4′, 4,3′, or the 4,4′ positions, and wherein Z is selected from the group consisting of
wherein Q is divalent moiety selected from the group consisting of —O—, —S—, —C(O)—, —SO 2 —, —SO—, —C y H 2 — where y is 1 to 8, and —C p H q F r — where p is from 1 to 8, q is 0 to 15, r is 1 to 16, and q+r=2p;
wherein the polyimide amount is 5 to 15 weight percent;
wherein the metal dialkylphosphinate comprises aluminum tris(diethylphosphinate); and
wherein the metal dialkyphosphinate amount is 4 to 10 weight percent.
15. The composition of claim 1 ,
wherein the polyamide comprises polyamide-6,6;
wherein the polyamide amount is 42 to 50 weight percent;
wherein the acid-functionalized poly(phenylene ether) is the product of melt blending 96 to 99 parts by weight of a poly(phenylene ether) with 1 to 4 parts by weight of a functionalizing agent selected from the group consisting of citric acid, fumaric acid, maleic acid, maleic anhydride, and combinations thereof; wherein the poly(phenylene ether) comprises a poly(phenylene ether)-polysiloxane block copolymer;
wherein the poly(phenylene ether)-polysiloxane block copolymer contributes 0.8 to 3 weight percent of polysiloxane blocks to the composition;
wherein the acid-functionalized poly(phenylene ether) amount is 30 to 48 weight percent;
wherein the polyimide comprises a polyetherimide comprising 10 to 1000 repeating units having the structure
wherein T is —O— or a group of the formula —O—Z—O— wherein the divalent bonds of the —O— or the —O—Z—O— group are in the 3,3′, 3,4′, 4,3′, or the 4,4′ positions, and wherein Z is selected from the group consisting of
wherein Q is divalent moiety selected from the group consisting of —O , —S—, —C(O)—, —SO 2 —, —SO—, —C y H 2 — where y is 1 to 8, and —C p R q F r — where p is from 1 to 8, q is 0 to 15, r is 1 to 16, and q+r=2p;
wherein the polyimide amount is 5 to 15 weight percent;
wherein the metal dialkylphosphinate comprises aluminum tris(diethylphosphinate); and
wherein the metal dialkyphosphinate amount is 3 to 10 weight percent.
16. An article comprising a composition comprising the product of melt blending:
40 to 70 weight percent polyamide;
20 to 50 weight percent acid-functionalized poly(phenylene ether);
5 to 30 weight percent polyimide; and
an amount of metal dialkylphosphinate effective to provide a flammability rating of V-1 or V-0 in the 20 mm Vertical Burning Flame Test of Underwriter's Laboratory Bulletin 94 “Tests for Flammability of Plastic Materials, UL 94”;
wherein all weight percents are based on the total weight of the composition.
17. The article of claim 16 ,
wherein the polyamide comprises polyamide-6,6;
wherein the polyamide amount is 42 to 50 weight percent;
wherein the acid-functionalized poly(phenylene ether) is the product of melt blending 96 to 99 parts by weight of a poly(phenylene ether) with 1 to 4 parts by weight of a functionalizing agent selected from the group consisting of citric acid, fumaric acid, maleic acid, maleic anhydride, and combinations thereof; wherein the poly(phenylene ether) comprises a homopolymer or copolymer of monomers selected from the group consisting of 2,6-dimethylphenol, 2,3,6-trimethylphenol, and combinations thereof;
wherein the acid-functionalized poly(phenylene ether) amount is 30 to 48 weight percent;
wherein the polyimide comprises a polyetherimide comprising 10 to 1000 repeating units having the structure
wherein T is —O— or a group of the formula —O—Z—O— wherein the divalent bonds of the —O— or the —O—Z—O— group are in the 3,3′, 3,4′, 4,3′, or the 4,4′ positions, and wherein Z is selected from the group consisting of
wherein Q is divalent moiety selected from the group consisting of —O—, —S—, —C(O)—, —SO 2 —, —SO—, —C y H 2 — where y is 1 to 8, and —C p H q F r — where p is from 1 to 8, q is 0 to 15, r is 1 to 16, and q+r=2p;
wherein the polyimide amount is 5 to 15 weight percent;
wherein the metal dialkylphosphinate comprises aluminum tris(diethylphosphinate); and
wherein the metal dialkyphosphinate amount is 4 to 10 weight percent.
18. The article of claim 16 ,
wherein the polyamide comprises polyamide-6,6;
wherein the polyamide amount is 42 to 50 weight percent;
wherein the acid-functionalized poly(phenylene ether) is the product of melt blending 96 to 99 parts by weight of a poly(phenylene ether) with 1 to 4 parts by weight of a functionalizing agent selected from the group consisting of citric acid, fumaric acid, maleic acid, maleic anhydride, and combinations thereof; wherein the poly(phenylene ether) comprises a poly(phenylene ether)-polysiloxane block copolymer;
wherein the poly(phenylene ether)-polysiloxane block copolymer contributes 0.8 to 3 weight percent of polysiloxane blocks to the composition;
wherein the acid-functionalized poly(phenylene ether) amount is 30 to 48 weight percent;
wherein the polyimide comprises a polyetherimide comprising 10 to 1000 repeating units having the structure
wherein T is —O— or a group of the formula —O—Z—O— wherein the divalent bonds of the —O— or the —O—Z—O— group are in the 3,3′, 3,4′, 4,3′, or the 4,4′ positions, and wherein Z is selected from the group consisting of
wherein Q is divalent moiety selected from the group consisting of —O—, —S—, —C(O)—, —SO 2 —, —SO—, —C y H 2 — where y is 1 to 8, and —C p R q F r — where p is from 1 to 8, q is 0 to 15, r is 1 to 16, and q+r=2p;
wherein the polyimide amount is 5 to 15 weight percent;
wherein the metal dialkylphosphinate comprises aluminum tris(diethylphosphinate); and
wherein the metal dialkyphosphinate amount is 3 to 10 weight percent.