Poly(phenylene ether) composition and article
View Patent ↗A composition includes specific amounts of a poly(phenylene ether), a specific radial block copolymer, a polystyrene-poly(ethylene-butylene)polystyrene triblock copolymer, a specific organophosphate ester, a hydrocarbon resin, and benzoin. The composition exhibits a desirable balance of multiaxial impact strength, light transmittance, and optical clarity, and it can be used to mold a variety of articles including animal cages, ink cartridges, tubes, pipes, and pipe fittings.
1. A composition comprising:
30 to 60 weight percent of a poly(phenylene ether);
10 to 40 weight percent of a radial block copolymer of an alkenyl aromatic monomer and a conjugated diene; wherein the radial block copolymer has a polystyrene content of about 68 weight percent and a melt flow rate of about 9 grams per 10 minutes measured at 200° C. and 5 kilograms load;
5 to 20 weight percent of a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer having a polystyrene content based on the weight of the triblock copolymer of 55 to 80 weight percent;
5 to 20 weight percent of an organophosphate ester selected from the group consisting of resorcinol bis(diphenyl phosphate), triphenyl phosphate, alkylated triphenyl phosphate, and combinations thereof;
a hydrogenated terpene resin having a softening point of at least 120° C. measured according to ASTM E28; wherein the hydrogenated terpene resin is present in an amount effective to provide the composition with a multiaxial impact strength of at least 25 joules, measured at 23° C. according to ASTM D3763-08a; and
0.05 to 2 weight percent of benzoin;
wherein the composition comprises less than 0.5 weight percent tridecyl phosphite;
wherein the composition comprises less than or equal to 1 weight percent of fillers; and
wherein all weight percents are based on the total weight of the composition, unless a different weight basis is specified.
2. The composition of claim 1 , exhibiting
a multiaxial impact strength of at least 25 joules, measured at 23° C. according to ASTM D3763-08,
a haze of less than or equal to 15 percent, measured at 23° C. according to ASTM D1003-00 at a thickness of 3.2 millimeters, and
a transmittance of at least 75 percent, measured at 23° C. according to ASTM D1003-00 at a thickness of 3.2 millimeters.
3. The composition of claim 1 , excluding tridecyl phosphite.
4. The composition of claim 1 , wherein the polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer has a polystyrene content of about 60 to about 67 weight percent.
5. The composition of claim 1 , wherein the polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer has a polystyrene content of about 67 weight percent.
6. The composition of claim 1 , wherein the hydrogenated terpene resin has a softening point of 120 to 180° C.
7. The composition of claim 1 , wherein the hydrogenated terpene resin has a softening point of about 150° C. and is used in an amount of 2 to 10 weight percent.
8. The composition of claim 1 , comprising less than or equal to 0.5 weight percent of a poly(phenylene ether)-polysiloxane block copolymer.
9. The composition of claim 1 , comprising less than or equal to 25 weight percent of total polyolefin, wherein total polyolefin consists of polyolefins and the polyolefin content of block copolymers comprising a poly(alkenyl aromatic) block and a polyolefin block.
10. The composition of claim 1 , comprising less than or equal to 0.5 weight percent of metal dialkylphosphinate.
11. The composition of claim 1 , comprising less than or equal to 1 weight percent of each of homopolystyrenes, rubber-modified polystyrenes, polyamides, polyolefins, and polyesters.
12. A composition comprising:
40 to 50 weight percent of a poly(2,6-dimethyl-1,4-phenylene ether);
20 to 30 weight percent of a radial block copolymer of an alkenyl aromatic monomer and a conjugated diene; wherein the radial block copolymer has a polystyrene content of about 68 weight percent and a melt flow rate of about 9 grams per 10 minutes measured at 200° C. and 5 kilograms load;
8 to 17 weight percent of a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer; wherein the polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer has a polystyrene content of about 67 weight percent;
7 to 17 weight percent of resorcinol bis(diphenyl phosphate);
3 to 8 weight percent of a hydrogenated terpene resin, wherein the hydrogenated terpene resin has a softening point of about 150° C.; and
0.05 to 2 weight percent of benzoin;
wherein the composition comprises less than or equal to 0.3 weight percent tridecyl phosphite;
wherein the composition comprises less than or equal to 1 weight percent of fillers;
wherein all weight percents are based on the total weight of the composition.
13. The composition of claim 12 , exhibiting
a multiaxial impact strength of at least 45 joules, measured at 23° C. according to ASTM D3763-08,
a haze of less than or equal to 5 percent, measured at 23° C. according to ASTM D1003-00 at a thickness of 3.2 millimeters, and
a transmittance of at least 80 percent, measured at 23° C. according to ASTM D1003-00 at a thickness of 3.2 millimeters.
14. An article comprising the composition of claim 1 .
15. An article comprising the composition of claim 12 .