Adhesive compositions for bonding composites
View Patent ↗The present invention relates to a non-thermosetting composition made by reacting epichlorohydrin and a primary amine, to the use of that composition for making thermosetting (curable) adhesives suitable for bonding composites, to a method of preparing composites using the thermosetting (curable) adhesives, and to the related composites bonded with the thermosetting (curable) adhesives.
1. A non-thermosetting composition, comprising:
wood particles; and
a reaction product of: (a) epichlorohydrin and (b) an amine selected from the group consisting of ammonia, a primary amine, and mixtures thereof,
wherein the reaction product is produced by reacting the epichlorohydrin and the amine in a ratio of 0.25 to 0.60 moles of epichlorohydrin per atom equivalent of amine hydrogen, and wherein the reaction product is produced by reacting in a serial fashion separate portions of the epichlorohydrin and separate portions of the amine at a temperature of not greater than 60° C.
2. The non-thermosetting composition of claim 1 , wherein the reaction product is produced by reacting the epichlorohydrin and the amine in a ratio of 0.25 to 0.40 moles of epichlorohydrin per atom equivalent of amine hydrogen.
3. The non-thermosetting composition of claim 1 , wherein the reaction product is produced by reacting the epichlorohydrin and the amine in a ratio of 0.40 to 0.60 moles of epichlorohydrin per atom equivalent of amine hydrogen.
4. The non-thermosetting composition of claim 1 , wherein the ammonia is present.
5. The non-thermosetting composition of claim 1 , wherein the primary amine is present and has the formula R1-NH 2 , wherein R1is a linear alkyl of 1-4 carbon atoms, a linear hydroxy alkyl of 1-4 carbon atoms, or a linear amino alkyl of 1-4 carbon atoms.
6. The non-thermosetting composition of claim 1 , wherein the primary amine is present and comprises methyl amine, ethyl amine, n-propyl amine, ethanolamine, ethylene diamine, or a mixture thereof.
7. The non-thermosetting composition of claim 1 , wherein the non-thermosetting composition is in the form of an aqueous mixture containing the reaction product in an amount of about 20 wt % to about 80 wt %, based on the combined weight of the reaction product and water.
8. The non-thermosetting composition of claim 1 , wherein the non-thermosetting composition is in the form of a powdered solid.
9. A non-thermosetting composition, comprising:
wood particles; and
a reaction product of epichlorohydrin and an amine,
wherein the amine is selected from the group consisting of: ammonia, one or more primary amines, and any mixture thereof, and
wherein the reaction product is produced by reacting the epichlorohydrin and the amine in a ratio of 0.25 to 0.60 moles of epichlorohydrin per atom equivalent of amine hydrogen.
10. The non-thermosetting composition of claim 9 , wherein the reaction product is produced by reacting the epichlorohydrin and the amine in a ratio of 0.25 to 0.40 moles of epichlorohydrin per atom equivalent of amine hydrogen.
11. The non-thermosetting composition of claim 9 , wherein the reaction product is produced by reacting the epichlorohydrin and the amine in a ratio of 0.40 to 0.60 moles of epichlorohydrin per atom equivalent of amine hydrogen.
12. The non-thermosetting composition of claim 9 , wherein the ammonia is present.
13. The non-thermosetting composition of claim 9 , wherein the primary amine is present and has the formula R1-NH 2 , wherein R1is a linear alkyl of 1-4 carbon atoms, a linear hydroxy alkyl of 1-4 carbon atoms, or a linear amino alkyl of 1-4 carbon atoms.
14. The non-thermosetting composition of claim 9 , wherein the non-thermosetting composition is in the form of an aqueous mixture containing the reaction product in an amount of about 20 wt % to about 80 wt %, based on the combined weight of the reaction product and water.
15. The non-thermosetting composition of claim 9 , wherein the non-thermosetting composition is in the form of a powdered solid.
16. A non-thermosetting composition, comprising:
wood particles; and
a reaction product of epichlorohydrin and an amine reacted at an epichlorohydrin to amine ratio of 0.25 to 0.60 moles of epichlorohydrin per atom equivalent of amine hydrogen, wherein the amine is selected from the group consisting of ammonia, one or more primary amines, and any mixture thereof, and wherein the non-thermosetting composition is in the form of an aqueous mixture containing the reaction product in an amount of about 20 wt % to about 80 wt %, based on the combined weight of the reaction product and water.
17. The non-thermosetting composition of claim 16 , wherein the epichlorohydrin and amine are reacted at an epichlorohydrin to amine ratio of 0.25 to 0.40 moles of epichlorohydrin per atom equivalent of amine hydrogen.