Copper alloy metal strip for zinc air anode cans
View Patent ↗The present disclosure generally relates to a zinc air cell having an anode can made of a copper alloy. The anode can material reduces internal gassing within the electrochemical cell while being compatible with the internal chemistry of the anode and the alkaline electrolyte of the cell itself.
1. An electrochemical cell comprising:
a zinc anode comprising an anode can, wherein the entire anode can consists of an alloy comprising copper, wherein the alloy is selected from the group consisting of an alloy of copper, aluminum, silicon and cobalt;
an alloy of copper, zinc, aluminum and cobalt; and, an alloy of copper, silicon, tin and chromium;
a cathode;
a gasket disposed between the anode and the cathode; and,
an electrolyte comprising a solute and an aqueous solvent.
2. The electrochemical cell of claim 1 , wherein the copper is present in an amount of from about 70% to about 95%, by weight of the alloy.
3. The electrochemical cell of claim 1 , wherein the aluminum is present in an amount of from about 1% to about 5%, by weight of the alloy.
4. The electrochemical cell of claim 1 , wherein the silicon is present in an amount of from about 1% to about 5%, by weight of the alloy.
5. The electrochemical cell of claim 1 , wherein the cobalt is present in an amount of from about 0.1% to about 1%, by weight of the alloy.
6. The electrochemical cell of claim 1 , wherein the tin is present in an amount of from about 1% to about 5%, by weight of the alloy.
7. The electrochemical cell of claim 1 , wherein the chromium is present in an amount of from about 0.1% to about 1%, by weight of the alloy.
8. The electrochemical cell of claim 1 , wherein the zinc is present in an amount of from about 20% to about 25%, by weight of the alloy.
9. The electrochemical cell of claim 1 , wherein the alloy of copper has a thickness of from about 75 microns to about 300 microns.
10. A zinc anode comprising an anode can, wherein the entire anode can consists of an alloy comprising copper, wherein the alloy selected from the group consisting of an alloy of copper, aluminum, silicon and cobalt; an alloy of copper, zinc, aluminum and cobalt; and, an alloy of copper, silicon, tin and chromium.
11. The zinc anode of claim 10 , wherein the copper is present in an amount of from about 70% to about 95%, by weight of the alloy.
12. The zinc anode of claim 10 , wherein the aluminum is present in an amount of from about 1% to about 5%, by weight of the alloy.
13. The zinc anode of claim 10 , wherein the silicon is present in an amount of from about 1% to about 5%, by weight of the alloy.
14. The zinc anode of claim 10 , wherein the cobalt is present in an amount of from about 0.1% to about 1%, by weight of the alloy.
15. The zinc anode of claim 10 , wherein the tin is present in an amount of from about 1% to about 5%, by weight of the alloy.
16. The zinc anode of claim 10 , wherein the chromium is present in an amount of from about 0.1% to about 1%, by weight of the alloy.
17. The zinc anode of claim 10 , wherein the zinc is present in an amount of from about 20% to about 25%, by weight of the alloy.
18. The zinc anode of claim 10 , wherein the alloy of copper has a thickness of from about 75 microns to about 300 microns.
19. The electrochemical cell of claim 1 , wherein the anode can comprises an alloy comprising from about 70% to about 95% copper, from about 1% to about 5% aluminum, from about 1% to about 5% silicon, and from about 0.1% to about 1% cobalt, by weight of the alloy.
20. The electrochemical cell of claim 1 , wherein the anode can comprises an alloy comprising from about 70% to about 95% copper, from about 20% to about 25% zinc, from about 1% to about 5% aluminum, and from about 0.1% to about 1% cobalt, by weight of the alloy.