Magnesium-based alloy wire and method of its manufacture
View Patent ↗Magnesium-based alloy wire excelling in strength and toughness, its method of manufacture, and springs in which the magnesium-based alloy wire is utilized are made available. The magnesium-based alloy wire contains, in mass %, 0.1 to 12.0% Al, and 0.1 to 1.0% Mn, and is provided with the following constitution. Diameter d that is 0.1 mm or more and 10.0 mm or less; length L that is 1000d or more; tensile strength that is 250 MPa or more; necking-down rate that is 15% or more; and elongation that is 6% or more. Such wire is produced by draw-forming it at a working temperature of 50° C. or more, and by heating it to a temperature of 100° C. or more and 300° C. or less after the drawing process has been performed.
1. A magnesium-based alloy wire containing, in mass %, 0.1 to 12.0% Al, and 0.1 to 1.0% Mn, wherein said alloy wire:
is made by drawing;
has a diameter d of 0.1 mm more and 10.0 mm or less;
has a length L of 1000d or more;
has a tensile strength of 300 MPa or more;
has a necking-down rate of 15% or more;
has an elongation of 6% or more;
has an average crystal grain size of 10 microns or less; and
has a surface roughness, R z , of 10 microns or less.
2. The magnesium-based alloy wire according to claim 1 , wherein it contains, in mass %, 0.1 to less than 2.0% Al, and 0.1 to 1.0% Mn, and wherein its necking-down rate is 40% or more and its elongation is 12% or more.
3. The magnesium-based alloy wire according to claim 1 , wherein it contains, in mass %, 0.1 to less than 2.0% Al, and 0.1 to 1.0% Mn, and wherein its necking-down rate is 30% or more and its elongation is 6% or more and less than 12%.
4. The magnesium-based alloy wire according to claim 1 , wherein it contains, in mass %, 2.0 to less than 12.0% Al, and 0.1 to 1.0% Mn, and wherein its tensile strength is 300 MPa or more.
5. The magnesium-based alloy wire according to claim 1 , wherein said wire has a YP ratio of 0.75 or more and the ratio of τ 0.2 /τ max in a torsion test is 0.50 or more, wherein τ 0.2 is the wire's 0.2% offset strength and τ max is the wire's maximum shear strength.
6. The magnesium-based alloy wire according to claim 1 , wherein said wire has:
a fatigue strength of 105 MPa or more when a repeat push-pull stress amplitude is applied 1×10 7 times; and
an axial residual stress of 10 MPa or less.
7. The magnesium-based alloy wire of claim 1 , wherein the drawing is carried out at a temperature elevation speed to working temperature of 1° C./sec to 100° C./sec; a working temperature of 50° C. to 150° C.; a formability of 10% or more; and a wire speed of 1 msec or more; followed by cooling the wire and heat treating it at 150° C. to 300° C. for 5 minutes or more.