Functionalized matrices for dispersion of nanostructures
View Patent ↗Matrixes doped with semiconductor nanocrystals are provided. In certain embodiments, the semiconductor nanocrystals have a size and composition such that they absorb or emit light at particular wavelengths. The nanocrystals can comprise ligands that allow for mixing with various matrix materials, including polymers, such that a minimal portion of light is scattered by the matrixes. The matrixes are optionally formed from the ligands. The matrixes of the present invention can be used as refractive index matching components, filters and antireflective coatings on optical devices and as down-converting layers. Processes for producing matrixes comprising semiconductor nanocrystals are also provided. Nanostructures having high quantum efficiency, small size, and/or a narrow size distribution are also described, as are methods of producing indium phosphide nanostructures and core-shell nanostructures with Group II-VI shells.
1. A composition comprising:
a nanostructure;
a polymeric ligand, which ligand comprises
a silicone backbone, and
one or more alcohol moieties coupled to the silicone backbone, and
a radical or cationic initiator, wherein the polymeric ligand comprises one or more dicarbinol moieties coupled to the silicone backbone.
2. The composition of claim 1 , wherein the silicone backbone of the polymeric ligand is linear.
3. The composition of claim 1 , wherein the polymeric ligand is provided in excess, whereby some molecules of the ligand are bound to a surface of the nanostructure and other molecules of the ligand are not bound to the surface of the nanostructure.
4. The composition of claim 1 , wherein the polymeric ligand comprises at least two different types of monomer units, at least one of which comprises the alcohol moiety and at least one of which lacks the alcohol moiety.
5. The composition of claim 4 , wherein monomer units comprising the alcohol moiety are present in the ligand at a molar percentage between 0.5% and 20%.
6. The composition of claim 4 , wherein monomer units comprising the alcohol moiety are present in the ligand at a molar percentage between 0.5% and 10%.
7. The composition of claim 4 , wherein monomer units comprising the alcohol moiety comprise a single dicarbinol moiety per monomer unit.
8. The composition of claim 4 , wherein the at least one type of monomer unit which lacks the alcohol moiety comprises a monomer unit that comprises an alkyl group, a polymerizable group, an epoxide group, an amine group, or a carboxylic acid group.
9. The composition of claim 1 , wherein the polymeric ligand comprises 1-200 dicarbinol moieties per ligand molecule.
10. The composition of claim 1 , wherein the nanostructures are semiconductor nanocrystals.
11. The composition of claim 1 , comprising a solvent.
12. The composition of claim 1 , comprising a crosslinker.
13. A composition comprising:
a nanostructure;
a polymeric ligand, which ligand comprises
a silicone backbone, and
one or more alcohol moieties coupled to the silicone backbone, and
a radical or cationic initiator,
wherein the polymeric ligand is
where R comprises a dicarbinol moiety and is a group comprising the alcohol moiety, where R′ and R″ are independently an alkyl or aryl group, where R″ is an alkyl group, a polymerizable group, a group comprising an epoxide group, a group comprising an amine group, or a group comprising a carboxylic acid group, where x is a positive integer, where y is zero or a positive integer, and where n is zero or a positive integer.
14. The composition of claim 13 , wherein y is zero, n is a positive integer, and R′ and R″ are methyl groups.
15. The composition of claim 13 , wherein y and n are positive integers and R′ and R″ are methyl groups.
16. A composition comprising:
a nanostructure;
a polymeric ligand, which ligand comprises
a silicone backbone, and
one or more alcohol moieties coupled to the silicone backbone, and
a radical or cationic initiator,
wherein the polymeric ligand is selected from the group consisting of:
where m, n, x, and y are positive integers.
17. A method of making a composite material, the method comprising:
providing a population of nanostructures, wherein the nanostructures have a polymeric ligand bound to a surface of the nanostructures, which ligand comprises a silicone backbone and one or more alcohol moieties coupled to the silicone backbone;
incorporating the polymeric ligand into a silicone matrix in which the nanostructures are embedded;
providing an excess of the polymeric ligand, which excess polymeric ligand is not bound to the surface of the nanostructures; wherein incorporating the polymeric ligand into the silicone matrix comprises incorporating the excess polymeric ligand and the polymeric ligand bound to the nanostructures into the silicone matrix; and
wherein incorporating the polymeric ligand into the silicone matrix comprises providing a crosslinker and reacting the crosslinker with hydroxyl moieties on the ligand.
18. The method of claim 17 , wherein the polymeric ligand comprises one or more dicarbinol moieties coupled to the silicone backbone.
19. A composite material produced by the method of claim 17 .
20. A device comprising the composite material of claim 19 .
21. A method of making a composite material, the method comprising:
providing a population of nanostructures, wherein the nanostructures have a polymeric ligand bound to a surface of the nanostructures, which ligand comprises a silicone backbone and one or more alcohol moieties coupled to the silicone backbone;
incorporating the polymeric ligand into a silicone matrix in which the nanostructures are embedded;
providing an excess of the polymeric ligand, which excess polymeric ligand is not bound to the surface of the nanostructures; wherein incorporating the polymeric ligand into the silicone matrix comprises incorporating the excess polymeric ligand and the polymeric ligand bound to the nanostructures into the silicone matrix; and
wherein the polymeric ligand comprises at least two different types of monomer units, at least one of which comprises the alcohol moiety and at least one of which lacks the alcohol moiety but comprises a polymerizable group or an epoxide group; wherein incorporating the polymeric ligand into the silicone matrix comprises reacting the polymerizable or epoxide groups on different molecules of the polymeric ligand with each other.