Active energy ray-curable resin composition, and production method for products with surfaces of fine concave-convex structures

1. A production method for a product having a cured resin layer with a fine concave-convex structure formed on a surface of a substrate, the method comprising filling a space between a mold having a fine concave-convex structure composed of anodized alumina on a surface thereof and a substrate with an active energy ray-curable resin composition, and curing the composition by irradiation with active energy rays, thereby forming a cured resin layer into which the fine concave-convex structure has been transferred on a surface of the substrate, wherein

(A) the method comprises treating a surface of the mold with a release agent, at least at transfer initiation,

(B) the active energy ray-curable resin composition comprises a polymerizable compound, a polymerization initiator, and a (poly)oxyethylene alkyl phosphate ester compound, and

an average spacing between convex protrusions or concave recesses of the fine concave-convex structure is not more than 400 nm.

2. The production method for a product having a cured resin layer with a fine concave-convex structure formed on a surface of a substrate according to claim 1 , wherein the (poly)oxyethylene alkyl phosphate ester compound is a compound represented by a formula (1) shown below:

(HO) 3−n (O═)P[—O—(CH 2 CH 2 O) m —R 1] n   (1)

wherein R 1 represents an alkyl group, m represents an integer of 1 to 20, and n represents an integer of 1 to 3.

3. The production method for a product having a cured resin layer with a fine concave-convex structure formed on a surface of a substrate according to claim 1 , wherein an amount of the (poly)oxyethylene alkyl phosphate ester compound is within a range from 0.01 to 1 part by mass, relative to 100 parts by mass of the polymerizable compound.

4. The production method for a product having a cured resin layer with a fine concave-convex structure formed on a surface of a substrate according to claim 2 , wherein an amount of the (poly)oxyethylene alkyl phosphate ester compound is within a range from 0.01 to 1 part by mass, relative to 100 parts by mass of the polymerizable compound.

5. The production method according to claim 1 , wherein said active energy ray-curable resin composition has a viscosity of 2,000 mPa·s or less at 25° C.

6. The production method according to claim 1 , wherein said fluorine compound has a hydrolyzable silyl group.

7. The production method according to claim 5 , wherein said fluorine compound has a perfluoropolyether structure.

8. A mass production method for producing a product having a cured resin layer with a fine concave-convex structure formed on a surface of a substrate using the same mold, the method comprising

(i) filling a space between a mold having a fine concave-convex structure composed of anodized alumina on a surface thereof and a substrate with an active energy ray-curable resin composition,

(ii) curing the composition by irradiation with active energy rays, thereby forming a cured resin layer into which the fine concave-convex structure has been transferred on a surface of the substrate,

(iii) recovering the product having a cured resin layer with a fine concave-convex structure formed on a surface of the substrate, and

repeating steps (i), (ii) and (iii) in sequence using the same mold to produce corresponding numbers of the product having a cured resin layer with a fine concave-convex structure formed on a surface of the substrate, wherein

(A) the method comprises treating a surface of the mold with a fluorine compound, at Least at transfer initiation,

(B) the active energy ray-curable resin composition comprises a polymerizable Compound, a polymerization initiator, and a (poly)oxyethylene alkyl phosphate ester compound, And

an average spacing between convex protrusions or concave recesses of the fine concave-convex Structure is not more than 400 nm.

9. The mass production method according to claim 8 , wherein steps (i)-(iii) are repeated at least 1,000 times.

10. The mass production method according to claim 9 , wherein steps (i)-(iii) are repeated up to 3,000 times.

11. A mass production method for producing a product having a cured resin layer with a fine concave-convex structure formed on a surface of a substrate using a rotating roll-shaped mold having a fine concave-convex structure composed of anodized alumina on a surface thereof in which the convex protrusions or concave recesses have an average spacing therebetween of not more than 400 nm, the method comprising, while rotating the roll-shaped mold,

(i) feeding a belt-shaped substrate to the roll-shaped mold provided the surface of the substrate is spaced apart from the opposing surface of the rotating mold when conducting the feeding so as to receive an active energy ray-curable resin composition therebetween;

(ii) introducing an active energy ray-curable resin composition into the space between the rotating mold and the belt-shaped substrate when conducting the feeding to form a curable resin layer into which the fine concave-convex structure is transferred, the active energy ray-curable resin composition comprising a polymerizable compound, a polymerization initiator, and a (poly)oxyethylene alkyl phosphate ester compound;

(iii) forming the cured resin layer into which the fine concave-convex structure has been transferred on the surface of the belt-shaped substrate by irradiating the curable resin layer active energy ray-curable composition with active energy rays; and

(iv) peeling the product from the surface of the rotating roll-shaped mold, the product comprising the cured resin layer having the fine concave-convex structure formed on the surface of the belt-shaped substrate,

wherein the method includes

(v) treating a surface of the mold with a fluorine compound, at least at transfer initiation.

12. The mass production method according to claim 11 , wherein said belt-shaped substrate comprises a film.

13. The mass production method according to claim 12 , wherein (i) comprises nip rolling the belt-shaped substrate to the rotating mold, and (ii) comprises introducing the active energy ray-curable resin composition into the space so the belt-shaped substrate and the composition are nip rolled to the rotating mold.