Heterophasic polypropylene with excellent creep performance

1. Heterophasic propylene copolymer (HECO) comprising:

(a) a matrix (M) being a polypropylene (PP), said polypropylene (PP) has a polydispersity index (PI) of at least 5.0, and

(b) an elastomeric propylene copolymer (EC) dispersed in said matrix (M), wherein

(i) said heterophasic propylene copolymer (HECO) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 of equal or below 1.0 g/10 min,

(ii) the amorphous phase (AM) of the xylene cold soluble fraction (XCS) of the heterophasic propylene copolymer (HECO) has an intrinsic viscosity (IV) measured according to ISO 1628-1 (at 135° C. in decaline) in the range of 3.8 to 6.0 dl/g and a comonomer content in the range of 25.0 to 40.0 wt. %, and wherein the polypropylene (PP) comprises at least three polypropylene fractions, the three polypropylene fractions differ from each other by the melt flow rate MFR2 (230° C.) measured according to ISO 1133 and at least one of the three polypropylenes is a propylene homopolymer and the remaining two polypropylenes are either a homopolymer or a copolymer.

2. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has

(i) a polydispersity index (PI) of at least 4.5, and/or

(ii) a shear thinning index SHI (3/100) measured according to ISO 6271-10 (200° C.) of at least 25.0, and/or

(iii) a crossover frequency ω c measured according to ISO 6271-10 (200° c.) of equal or below 3.0 rad/s.

3. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has:

(i) a comonomer content in the range of 2.0 to 14.0 wt. %, and/or

(ii) a xylene cold soluble (XCS) fraction measured according to IS06427 (23° C.) of below 15.0 wt. %.

4. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has:

(i) a melting temperature Tm of at least 158° C., and/or

(ii) a crystallization temperature Tc of at least 120° C., and/or

(iii) a charpy notched impact strength measured according to ISO 179 (1 eA; 23° C.) of at least 30 kJ/m 2 , and/or

(iv) a tensile modulus measured according to ISO 527-2 of at least 1400 MPa.

5. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the polypropylene (PP) has:

(i) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 of equal or below 1.0 g/10 min and/or

(ii) a comonomer content equal or below 1.0 wt. %, and/or

(iii) a shear thinning index SHI (3/100) measured according to ISO 6271-10 (200° C.) of at least 20.0, and/or

(iv) a xylene cold soluble (XCS) fraction measured according to IS06427 (23° C.) of equal or below 3.5 wt. %.

6. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the polypropylene (PP) comprises:

(a) a first polypropylene (PP1) being a first propylene homopolymer (H-PP1) or a first random propylene copolymer (R-PP1),

(b) a second polypropylene (PP2) being a second propylene homopolymer (H-PP2) or a second random propylene copolymer (R-PP2),

(c) a third polypropylene (PP3) being a third propylene homopolymer (H-PP3) or a third random propylene copolymer (R-PP3),

with the proviso that at least one of the three polypropylenes PP1, PP2, and PP3 is a propylene homopolymer, wherein further

(i) the first polypropylene (PP1) has the lowest the melt flow rate MFR2 (230° C.) measured according to ISO 1133 of the three polypropylenes PP1, PP2 and PP3, and/or

(ii) the three polypropylenes PP1, PP2 and PP3 differ in the melt flow rate MFR2 (230° C.) measured according to ISO 1133.

7. Heterophasic propylene copolymer (HECO) according to claim 6 , wherein the first polypropylene (PP1) being a first propylene homopolymer (H-PP1) has

(i) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 of not more than 0.1 g/10 min, and/or

(ii) comonomer content is not more than 2.5 wt. %, and/or

(iii) a xylene cold soluble (XCS) fraction measured according to IS06427 (23° C.) of equal or below 5.0 wt. %.

8. Heterophasic propylene copolymer (HECO) according to claim 6 , wherein:

(i) the second polypropylene (PP2) being a second propylene homopolymer (H-PP2) has a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of 0.005 to 2.0 g/10 min, and/or

(ii) the third polypropylene (PP3) being a third propylene homopolymer (HPP3) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 of at least 4.0 g/10 min.

9. Heterophasic propylene copolymer (HECO) according to claim 6 , wherein the weight ratio between the first polypropylene (PP1) and the second polypropylene (PP2) is 80:20 to 25:75.

10. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the comonomers of the elastomeric copolymer (EC) are ethylene and/or at least one C 4 to C 10 α-olefin.

11. Heterophasic propylene copolymer (HECO) claim 1 , wherein the comonomer content of the amorphous phase (AM) of the xylene cold soluble fraction (XCS) of the heterophasic propylene copolymer (HECO) is below 40.0 wt. %.

12. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) comprises:

(a) 80.0 to 94.0 wt. % of the polypropylene (PP), and

(b) 6.0 to 20.0 wt. % of the elastomeric copolymer (EC), based on the total amount of the polypropylene (PP) and the elastomeric copolymer (BC).

13. Heterophasic propylene copolymer (HECO) according to claim 6 , wherein the polypropylene (PP) comprises:

(a) 15.0 to 35.0 wt. % of the first polypropylene (PP1),

(b) 29.0 to 48.0 wt. % of the second polypropylene (PP2), and

(c) 18.0 to 55.0 wt. % of the third polypropylene (PP3),

based on the total amount of the first polypropylene (PP1), the second polypropylene (PP2), and the third polypropylene (PP3).

14. Process for the preparation of a heterophasic propylene copolymer (HECO) according to claim 1 in a sequential polymerization process, said heterophasic propylene copolymer (HECO) comprises a first polypropylene (PP1), a second polypropylene (PP2) and a third polypropylene (PP3), wherein said process comprises the steps of:

(a1) polymerizing propylene and at least one ethylene and/or optionally at least one C 4 to C 12 α-olefin in a first reactor (R1) obtaining the first polypropylene (PP1), said first polypropylene (PP1) is a first propylene homopolymer (H-PP1),

(b1) transferring the first polypropylene (PP1) in a second reactor (R2),

(c1) polymerizing in the second reactor (R2) and in the presence of said first polypropylene (PP1) propylene and optionally at least one ethylene and/or a C 4 to C 12 α-olefin obtaining thereby the second polypropylene (PP2), said second polypropylene (PP2) is a second propylene homopolymer (H-PP2), the first polypropylene (PP1) being mixed with the second polypropylene (PP2),

(d1) transferring the mixture of step (c1) in a third reactor (R3),

(e1) polymerizing in the third reactor (R3) and in the presence of the mixture obtained in step (c1) propylene and optionally at least one ethylene and/or a C 4 to C 12 α-olefin obtaining thereby a third polypropylene (PP3), said third polypropylene (PP3) is a third propylene homopolymer (H-PP3), the first polypropylene (PP1), the second polypropylene (PP2) and the third polypropylene (PP3) form the polypropylene (PP),

(f1) transferring the polypropylene (PP) in a fourth reactor (R4), and

(g1) polymerizing in the fourth reactor (R4) and in the presence of the polypropylene (PP) propylene and at least one ethylene and/or a C 4 to C 12 α-olefin obtaining thereby a elastomeric propylene copolymer (EC), the polypropylene (PP) and the elastomeric propylene copolymer (EC) form the heterophasic propylene copolymer (HECO), or

(a2) polymerizing propylene and at least one ethylene and/or a C 4 to C 20 α-olefin in a first reactor (R1) obtaining the second polypropylene (PP2), said second polypropylene (PP2) is a second propylene homopolymer (H-PP2),

(b2) transferring the second polypropylene (PP2) in a second reactor (R2),

(c2) polymerizing in the second reactor (R2) and in the presence of said second polypropylene (PP2) propylene and optionally at least one ethylene and/or a C 4 to C 12 α-olefin obtaining thereby the third polypropylene (PP3), said third polypropylene (PP3) is a third propylene homopolymer (H-PP3), the second polypropylene (PP2) being mixed with the third polypropylene (PP3),

(d2) transferring the mixture of step (c2) in a third reactor (R3),

(e2) polymerizing in the third reactor (R3) and in the presence of the mixture obtained in step (c2) propylene and optionally at least one ethylene and/or a C 4 to C 12 α-olefin obtaining thereby a first polypropylene (PP1), said first polypropylene (PP1) is a first propylene homopolymer (H-PP1), the first polypropylene (PP1), the second polypropylene (PP2) and the third polypropylene (PP3) form the polypropylene (PP),

(f2) transferring the polypropylene (PP) in a fourth reactor (R4), and

(g2) polymerizing in the fourth reactor (R4) and in the presence of the polypropylene (PP) propylene and at least one ethylene and/or a C 4 to C 12 α-olefin obtaining thereby a elastomeric propylene copolymer (EC), the polypropylene (PP) and the elastomeric propylene copolymer (EC) form the heterophasic propylene copolymer (HECO).

15. Pipes comprising a heterophasic propylene copolymer (HECO) according to claim 1 .