Activated carbon and use therefor
View Patent ↗An activated carbon having a high catalytic activity as an oxidation catalyst or a decomposition catalyst, and use therefor are provided. The activated carbon has (a) an oxygen content in a range from 1.40 to 4.30% by mass, (b) a nitrogen content in a range from 0.90 to 2.30% by mass, (c) a sulfur content in a range from 0.50 to 1.20% by mass, and (d) a hydrogen content in a range from 0.40 to 0.65% by mass. The activated carbon may have at least one characteristic of (e) an amount of an acidic surface functional group of 0.10 to 0.36 meq/g, (f) an amount of a basic surface functional group of 0.50 to 1.30 meq/g, and (g) a benzene adsorption capacity of 25 to 50%. The activated carbon catalyzes an oxidation reaction of N-(phosphonomethyl)iminodiacetic acid with a peroxide (e.g., hydrogen peroxide) and achieves an efficient production of N-(phosphonomethyl)glycine even after repetitive use. The activated carbon also efficiently decomposes a chloramine.
1. An activated carbon, comprising, based on a total mass of the activated carbon:
(a) from 1.40 to 4.30% by mass of oxygen;
(b) from 0.90 to 2.30% by mass of nitrogen;
(c) from 0.50 to 1.20% by mass of sulfur; and
(d) from 0.40 to 0.65% by mass of hydrogen.
2. A decomposition catalyst, comprising an activated carbon comprising, based on a total mass of the activated carbon:
(a) from 1.40 to 4.30% by mass of oxygen;
(b) from 0.90 to 2.30% by mass of nitrogen;
(c) from 0.50 to 1.20% by mass of sulfur; and
(d) from 0.40 to 0.65% by mass of hydrogen.
3. The decomposition catalyst of claim 2 , wherein the activated carbon comprises, based on a total mass of the activated carbon:
(a) from 1.40 to 3.5% by mass of oxygen;
(b) from 0.90 to 2.0% by mass of nitrogen;
(c) from 0.50 to 1.00% by mass of sulfur; and
(d) from 0.40 to 0.65% by mass of hydrogen.
4. The decomposition catalyst of claim 2 , wherein the activated carbon comprises, based on a total mass of the activated carbon:
(a) from 1.40 to 3.0% by mass of oxygen;
(b) from 0.90 to 1.75% by mass of nitrogen;
(c) from 0.50 to 0.90% by mass of sulfur; and
(d) from 0.40 to 0.65% by mass of hydrogen.
5. The decomposition catalyst of claim 2 , satisfying at least one selected from the group consisting of:
(e) further comprising an amount of an acidic surface functional group in a range from 0.10 to 0.36 meq/g;
(f) further comprising an amount of a basic surface functional group in a range from 0.50 to 1.30 meq/g; and
(g) having a benzene adsorption capacity in a range from 25 to 50%.
6. The decomposition catalyst of claim 2 , satisfying at least one selected from the group consisting of:
(e) comprising an amount of an acidic surface functional group in a range from 0.10 to 0.30 meq/g;
(f) comprising an amount of a basic surface functional group in a range from 0.50 to 1.00 meq/g; and
(g) having a benzene adsorption capacity in a range from 25 to 47%.
7. The decomposition catalyst of claim 2 , further comprising (e) an amount of an acidic surface functional group in a range from 0.10 to 0.36 meq/g.
8. The decomposition catalyst of claim 2 , further comprising (f) an amount of a basic surface functional group in a range from 0.50 to 1.30 meq/g.
9. The decomposition catalyst of claim 2 , having (g) a benzene adsorption capacity in a range from 25 to 50%.
10. The decomposition catalyst of claim 2 , further comprising (e) an amount of an acidic surface functional group in a range from 0.10 to 0.30 meq/g.
11. The decomposition catalyst of claim 2 , further comprising (f) an amount of a basic surface functional group in a range from 0.50 to 1.00 meq/g.
12. The decomposition catalyst of claim 2 , having (g) a benzene adsorption capacity in a range from 25 to 47%.
13. A process for producing N-(phosphonomethyl)glycine, the process comprising:
oxidizing N-(phosphonomethyl)iminodiacetic acid with an oxidizing agent in the presence of an activated carbon,
wherein the activated carbon comprises, based on a total mass of the activated carbon:
(a) from 1.40 to 4.30% by mass of oxygen;
(b) from 0.90 to 2.30% by mass of nitrogen;
(c) from 0.50 to 1.20% by mass of sulfur; and
(d) from 0.40 to 0.65% by mass of hydrogen, and
wherein the oxidizing agent comprises a peroxide.
14. The process of claim 13 , wherein the amount of the activated carbon is 0.5 to 300 parts by weight, relative to 100 parts by weight of the N-(phosphonomethyl)iminodiacetic acid.
15. The process of claim 13 , wherein the amount of the peroxide is 10 to 100 parts by weight, relative to 100 parts by weight of the N-(phosphonomethyl)iminodiacetic acid.
16. The process of claim 13 , wherein the peroxide is hydrogen peroxide.
17. The process of claim 16 , wherein a decomposition rate of hydrogen peroxide is not less than 1,000 mg-H 2 O 2 /g-activated carbon/hr.
18. A process for removing a peroxide or a chloramine, the process comprising:
contacting a peroxide or a chloramine with an activated carbon comprising, based on a total mass of the activated carbon
(a) from 1.40 to 4.30% by mass of oxygen;
(b) from 0.90 to 2.30% by mass of nitrogen;
(c) from 0.50 to 1.20% by mass of sulfur; and
(d) from 0.40 to 0.65% by mass of hydrogen.