Process for producing environmentally-friendly steel sheet for container material, environmentally-friendly steel sheet for container material, and laminated and pre-coated steel sheet for container material using the same
View Patent ↗A method for the cathodic electrocoating of a tin-coated steel sheet in a treatment solution that does not contain any Cr compound, F or nitrite nitrogen. A tin oxide layer that is not subjected to a cathodic electrocoating treatment yet and is arranged on a tin-coated steel sheet is thinned to a specified thickness or less by a cathodic electrocoating treatment in an aqueous solution containing sodium carbonate or sodium hydrogen carbonate or an aqueous sulfuric acid solution immersion treatment, and the tin oxide layer is subjected to a cathodic electrocoating treatment in an aqueous solution of an alkaline metal sulfate containing a zirconium compound having a specified composition. In this manner, a coating film is formed on the tin oxide layer at a specific adhered amount in terms of Zr content.
1. A process for producing an environmentally friendly steel sheet for a container material, comprising:
removing a tin oxide layer present on a tin-plated steel sheet by a cathodic electrolytic treatment in an aqueous solution containing sodium carbonate or sodium hydrogen carbonate, or by an immersion treatment in an aqueous sulfuric acid solution, so as to provide a thickness of from 0 mC/cm 2 to 3.5 mC/cm 2 as measured by an electrolytic stripping method, and;
subsequently, forming a coating film by subjecting the tin-plated steel sheet to a cathodic electrolytic coating treatment in an aqueous solution of an alkali metal sulfate not containing a chromium compound, fluorine, or a nitrate nitrogen, but containing a zirconium compound,
wherein said aqueous solution of an alkali metal sulfate has an electric conductivity of from 0.2 S/m to 6.0 S/m and a pH of from 1.5 to 2.5, and
wherein the coating film has a film coating amount converted to zirconium of from 0.1 mg/m 2 to 20 mg/m 2 .
2. The process for producing an environmentally friendly steel sheet for a container material according to claim 1 , wherein a concentration of zirconium in the aqueous solution of the alkali metal sulfate coining a zirconium compound is from 10 mg/L to 2000 mg/L.
3. The process for producing an environmentally friendly steel sheet for a container material according to claim 2 , wherein the alkali metal sulfate is sodium sulfate.
4. The process for producing an environmentally friendly steel sheet for a container material according to claim 2 , wherein the alkali metal sulfate is potassium sulfate.
5. The process for producing an environmentally friendly steel sheet for a container material according to claim 2 , wherein the concentration of the alkali metal sulfate contained in the aqueous solution of the alkali metal sulfate is from 0.1 mass % to 8.0 mass %.
6. The process for producing an environmentally friendly steel sheet for a container material according to claim 1 , wherein the alkali metal sulfate is sodium sulfate.
7. The process for producing an environmentally friendly steel sheet for a container material according to claim 1 , wherein the alkali metal sulfate is potassium sulfate.
8. The process for producing an environmentally friendly steel sheet for a container material according to claim 1 , wherein the concentration of the alkali metal sulfate contained in the aqueous solution of the alkali metal sulfate is from 0.1 mass % to 8.0 mass %.