IP Library Granted Patent US 8,765,004
Granted Patent B2
US 8,765,004 · App. 13/640,650 · Granted Jul 1, 2014

Composition comprising 2,3,3,3-tetrafluoropropene and 1,1,1,2-tetrafluoroethane, chillers containing same and methods of producing cooling therein

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Quick Facts
Patent No.
US 8,765,004
App. No.
13/640,650
Granted
Jul 1, 2014
Kind
B2
Abstract

Disclosed herein is a chiller apparatus containing a composition comprising from about 6 to about 70 weight percent 2,3,3,3-tetrafluoropropene and from about 30 to about 94 weight percent 1,1,1,2-tetrafluoroethane. Also disclosed herein is a method for producing cooling in a chiller comprising (a) evaporating a liquid refrigerant comprising from about 6 to 70 weight percent 2,3,3,3-tetrafluoropropene and from about 30 to 94 weight percent 1,1,1,2-tetrafluoroethane in an evaporator having a heat transfer medium passing therethrough thereby producing a vapor refrigerant; and (b) compressing the vapor refrigerant in a compressor. Also disclosed herein is a method for replacing a refrigerant in a chiller designed for using HFC-134a or CFC-12 as refrigerant, comprising charging said chiller with a composition comprising a refrigerant consisting essentially of from about 6 to 70 weight percent 2,3,3,3-tetrafluoropropene and from about 30 to 94 weight percent 1,1,1,2-tetrafluoroethane.

Claims (15)

1. A chiller apparatus containing a composition comprising from about 38 to about 67 weight percent 2,3,3,3-tetrafluoropropene and from about 62 to about 33 weight percent 1,1,1,2-tetrafluoroethane, wherein the chiller apparatus is a centrifugal chiller.

2. The chiller apparatus of claim 1 suitable for use with HFC-134a.

3. The chiller apparatus of claim 1 suitable for use with CFC-12.

4. The chiller apparatus of claim 1 , wherein said composition comprises from about 54 to about 67 weight percent 2,3,3,3-tetrafluoropropene and from about 46 to about 33 weight percent 1,1,1,2-tetrafluoroethane.

5. The chiller apparatus of claim 1 , wherein said composition comprises from about 54.0 to about 56.0 weight percent 2,3,3,3-tetrafluoropropene and from about 46.0 to about 44.0 weight percent 1,1,1,2-tetrafluoroethane.

6. The chiller apparatus of claim 5 , wherein said composition comprises about 55 weight percent 2,3,3,3-tetrafluoropropene and about 45 weight percent 1,1,1,2-tetrafluoroethane.

7. The chiller apparatus of claim 1 , wherein said composition comprises from about 58.0 to about 59.5 weight percent 2,3,3,3-tetrafluoropropene and from about 42.0 to about 40.5 weight percent 1,1,1,2-tetrafluoroethane.

8. The chiller apparatus of claim 7 , wherein said composition comprises about 59 weight percent 2,3,3,3-tetrafluoropropene and about 41 weight percent 1,1,1,2-tetrafluoroethane.

9. A method for producing cooling in a chiller comprising (a) evaporating a liquid refrigerant comprising from about 38 to 67 weight percent 2,3,3,3-tetrafluoropropene and from about 62 to 33 weight percent 1,1,1,2-tetrafluoroethane in an evaporator having a heat transfer medium passing therethrough thereby producing a vapor refrigerant; and (b) compressing the vapor refrigerant in a compressor, wherein the volumetric cooling capacity of the refrigerant is greater than the individual volumetric cooling capacities of 2,3,3,3-tetrafluoropropene alone and 1,1,1,2-tetrafluoroethane alone, wherein the chiller apparatus is a centrifugal chiller.

10. The method of claim 9 , wherein the weight ratio of 2,3,3,3-tetrafluoropropene to 1,1,1,2-tetrafluoroethane in the liquid refrigerant is essentially the same as the weight ratio of 2,3,3,3-tetrafluoropropene to 1,1,1,2-tetrafluoroethane in the vapor refrigerant.

11. The method of claim 9 , wherein the heat transfer medium passes out of the evaporator to a body to be cooled.

12. A method for replacing a refrigerant in a chiller designed for using HFC-134a or CFC-12 as refrigerant, comprising charging said chiller with a composition comprising a refrigerant consisting essentially of from about 38 to 67 weight percent 2,3,3,3-tetrafluoropropene and from about 62 to 33 weight percent 1,1,1,2-tetrafluoroethane thereby increasing the cooling capacity of the chiller, wherein the chiller apparatus is a centrifugal chiller.

13. The chiller apparatus of claim 1 , wherein said composition consists of 2,3,3,3-tetrafluoropropene and 1,1,1,2-tetrafluoroethane.

14. A chiller apparatus containing a composition comprising from about 20 to about 60 weight percent 2,3,3,3-tetrafluoropropene and from about 80 to about 40 weight percent 1,1,1,2-tetrafluoroethane, wherein the chiller apparatus is a centrifugal chiller.

15. The chiller apparatus of claim 14 , wherein said composition consists of 2,3,3,3-tetrafluoropropene and 1,1,1,2-tetrafluoroethane.

Assignments (4)
RELEASE OF SECURITY INTEREST Recorded Apr 4, 2018
From: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
To: THE CHEMOURS COMPANY FC, LLC
Reel/Frame 045845/0913 →
SECURITY INTEREST Recorded Apr 4, 2018
From: THE CHEMOURS COMPANY FC, LLC
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 045846/0011 →
SECURITY AGREEMENT Recorded Jun 10, 2015
From: THE CHEMOURS COMPANY FC LLC; THE CHEMOURS COMPANY TT, LLC
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 035839/0675 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 15, 2015
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: THE CHEMOURS COMPANY FC, LLC
Reel/Frame 035432/0023 →