Curable composition and cured product for dental use
View Patent ↗The present invention provides a curable composition allowing a cured product having high aesthetic quality, strength and durability along with having high surface lubricating property. A curable composition in the present invention comprises: an inorganic powder and a polymerizable monomer, wherein the inorganic powder contains a spherical composite powder, the spherical composite powder has a complex of silicon dioxide and at least one of alumina and zirconia, and an amorphous part and a crystalline part are mixed in the spherical composite powder. A refractive index difference is not more than 0.05 between the spherical composite powder and a cured product obtained by curing only a compound excluded the spherical composite powder.
1. A process of producing a curable composition comprising:
an inorganic powder and
a polymerizable monomer,
wherein
the inorganic powder contains a spherical composite powder,
the spherical composite powder has a complex of silicon dioxide and at least one of alumina and zirconia,
an amorphous part and a crystalline part are mixed in the spherical composite powder,
the sphericity of particles in the spherical composite powder is defined as at least 0.95, and
a refractive index difference is not more than 0.05 between the spherical composite powder and a cured product obtained by curing only a compound excluded the spherical composite powder, and
the process comprises:
obtaining the spherical composite powder in a flame fusion method, and
obtaining the curable composition by mixing the inorganic powder containing the spherical composite powder with the polymerizable monomer.
2. The process of producing a curable composition according to claim 1 , wherein the spherical composite powder has a refractive index in the range of 1.48 to 1.60.
3. The process of producing a curable composition according to claim 1 , wherein the spherical composite powder has a relative background level of 3 to 18 in X-ray diffraction spectrum.
4. The process of producing a curable composition according to claim 1 , wherein the spherical composite powder has an average particle size in the range of 0.01 to 50 μm.
5. The process of producing the curable composition according to claim 1 , further comprising a polymerization catalyst, wherein the spherical composite powder content is in the range of 5 to 95 mass %.
6. The process of producing a curable composition according to claim 1 , wherein the polymerizable monomer contains at least one of an acrylate monomer and a methacrylate monomer, and a content of the spherical composite powder is in the range of 55 to 95 mass %.
7. A process of production of a cured product for dental use,
the process comprising:
producing the curable composition by process of producing a curable composition according to claim 1 , and
forming the curable composition as defined in claim 1 to the cured product for treatment of a tooth.
8. The process of production the curable composition according to claim 1 , further comprising:
subjecting the spherical composite powder to a heat treatment.
9. The process of producing a curable composition according to claim 8 , wherein a heat treatment temperature in the heat treatment is defined as not more than 1700°C.
10. The process of producing a curable composition according to claim 8 , wherein a heat treatment time in the heat treatment is defined as at least 0.01 hours.