Polycarbonate composition having improved optical and thermal properties
View Patent ↗The invention relates to aromatic polycarbonates which comprise dioxydiarylcycloalkane structural units, and which have improved optical and thermal properties. It also relates to an improved process to produce the said polycarbonates from dihydroxydiphenylcyloalkanes, and also to mixtures of these polycarbonates with polymers, with fillers, with dyes and with conventional additives.
1. A process for producing a polycarbonate composition by an interfacial process or a melt transesterification process using bisphenol TMC and bisphenol A, characterized in that the sulphur content of the bisphenols used to produce the polycarbonate is less than 1.5 ppm;
wherein the polycarbonate composition comprises at least one polycarbonate component comprising structural units of the general formula (I):
where R 1 and R 2 , independently of one another, are H, halogen, C 1 -C 8 -alkyl, C 5 -C 6 -cycloalkyl, C 6 -C 10 -aryl and C 7 -C 12 -arylalkyl, where m is 4 or 5, where R 3 and R 4 are freely selectable for each X and, independently of one another, are H or C 1 -C 8 -alkyl, where X is carbon, characterized in that the sulphur content in the composition is less than 2.0 ppm;
wherein the at least one polycarbonate component is an aromatic polycarbonate made from 30 to 70 mol % of 3,3,5-trimethyl-1,1-bis(4-hydroxyphenyl)cyclohexane (bisphenol TMC) and 30 to 70 mol % bisphenol A, based on the total amount of bisphenols; and
wherein the polycarbonate composition optionally comprises polymer additives or mixture constituents selected from the group of mould-release agents, flow aids, heat stabilizers, antioxidants, UV absorbers and/or IR absorbers, flame retardants, antistatic agents, dyes and pigments, fillers, thermoplastics or elastomers.
2. The process according to claim 1 , characterized in that the sulphur content of the bisphenols used for the production process is less than 1.0 ppm.
3. A method for producing transparent or translucent or opaque or coloured mouldings comprising:
mixing bisphenol A and bisphenol TMC and optional polymer additives to form a polycarbonate composition, wherein the sulphur content in the composition is less than 1.5 ppm, and compounding and extruding them in the melt at temperatures of from 240° C. to 300° C.;
wherein the polycarbonate composition comprises at least one polycarbonate component comprising structural units of the general formula (I):
where R 1 and R 2 , independently of one another, are H, halogen, C 1 -C 8 -alkyl, C 5 -C 6 -cycloalkyl, C 6 -C 10 -aryl and C 7 -C 12 -arylalkyl, where m is 4 or 5, where R 3 and R 4 are freely selectable for each X and, independently of one another, are H or C 1 -C 8 -alkyl, where X is carbon, characterized in that the sulphur content in the composition is less than 2.0 ppm;
wherein the at least one polycarbonate component is an aromatic polycarbonate made from 30 to 70 mol % of 3,3,5-trimethyl-1,1-bis(4-hydroxyphenyl)cyclohexane (bisphenol TMC) and 30 to 70 mol % bisphenol A, based on the total amount of bisphenols; and
wherein the polycarbonate composition optionally comprises polymer additives or mixture constituents selected from the group of mould-release agents, flow aids, heat stabilizers, antioxidants, UV absorbers and/or IR absorbers, flame retardants, antistatic agents, dyes and pigments, fillers, thermoplastics or elastomers.
4. The process according to claim 1 , characterized in that the sulphur content of the bisphenols used for the production process is less than 0.87 ppm.
5. The process according to claim 1 , wherein the bisphenol TMC is used in an amount of from 44 to 67% by weight and the bisphenol A is used in an amount of from 33 to 56% by weight.
6. The process according to claim 4 , wherein the bisphenol TMC is used in an amount of from 44 to 67% by weight and the bisphenol A is used in an amount of from 33 to 56% by weight.
7. The process according to claim 1 , wherein the polycarbonate composition has a yellowness index after hot-air aging at 150° C. for a period of 250 hours of less than 7.0.
8. The process according to claim 1 , wherein the organic sulphur content of the bisphenols used to produce the polycarbonate is less than 1.5 ppm.