Thermoplastic resin with high thermal conductivity
View Patent ↗Provided is a thermoplastic resin having excellent thermal conductivity, in which thermoplastic resin a change in number average molecular mass caused by progress of polymerization occurring when the thermoplastic resin material is melted and a change in thermal conductivity caused by the change in number average molecular mass are low. The thermoplastic resin has (A) a specific structure and (B) ends of molecular chains sealed by a monofunctional low molecular weight compound. The resin itself has excellent thermal conductivity. The change in number average molecular mass becomes small during melting of the thermoplastic resin material, so that the change in thermal conductivity of the resin itself becomes small.
1. A thermoplastic resin wherein:
a main chain mainly has a repeating unit represented by a general formula (1);
60 mol % or more ends of molecular chains are sealed with a monofunctional low molecular weight compound; and
thermal conductivity of the thermoplastic resin itself is not less than 0.45 W/(m·K),
the general formula (1) being as follows:
-A 1 - x -A 2 - y -R- z - (1)
where: each of A 1 and A 2 independently represents a substituent group selected from the group consisting of an aromatic group, a fused aromatic group, an alicyclic group, and an alicyclic heterocyclic group; each of x, y, and z independently represents a direct bond or a bivalent substituent group selected from the group consisting of —CH 2 —, —C(CH 3 ) 2 —, —O—, —S—, —CH 2 —CH 2 —, —CH═CH—, —C≡C—, —CO—, —CO—O—, —CO—NH—, —CH═N—, —CH═N—N═CH—, —N═N—, and —N(O)═N—; and
R represents a bivalent substituent group which has a main chain length of 2 to 20 atoms and may be branched.
2. The thermoplastic resin as set forth in claim 1 , wherein the thermoplastic resin has a number average molecular mass of 3000 to 40000.
3. The thermoplastic resin as set forth in claim 1 ,
wherein the low molecular weight compound for sealing the ends of the molecular chains of the thermoplastic resin is one or two or more compounds selected from the group consisting of compounds expressed by the following Formulae (A) to (D).
where: Y represents a functional group selected from the group consisting of aldehyde, hydroxy, carboxyl, amino, imino, glycidyl ether, glycidyl ester, methyl, isocyanate, acetoxy, carboxy alkyl ester (whose alkyl group is a C1 to C4 alkyl), and carboxyphenyl ester; Z represent a substituent selected from C1 to C20 alkyl, —Cl, —Br, —OCH 3 , —CN, —NO 2 , —NH 2 , vinyl, ethynyl, acrylate, phenyl, benzil, alkyl urea, alkyl ester, and maleimide; k represents an integer from 0 to 2; and 1 represents an integer from 0 to 4.
4. The thermoplastic resin as set forth in claim 3 ,
wherein the functional group Y of the low molecular weight compound for sealing the ends of the molecular chains of the thermoplastic resin is at least one functional group selected from the group consisting of hydroxy, carboxyl, amino, and esters and glycidyl groups thereof.
5. The thermoplastic resin as set forth in claim 3 ,
wherein the acid anhydride of the lower fatty acid for sealing the ends of the molecular chains of the thermoplastic resin is at least one acid anhydride selected from the group consisting of acetic acid anhydride, propionic acid anhydride and trichloroacetic anhydride.
6. The thermoplastic resin as set forth in claim 1 ,
wherein a part corresponding to -A 1 -x-A 2 - of the thermoplastic resin is a mesogenic group expressed by the following general formula (2),
where: X represents independently aliphatic hydrocarbon group, F, Cl, Br, I, CN, or NO 2 ; n is an integer from 0 to 4; and m is an integer from 2 to 4.
7. The thermoplastic resin as set forth in claim 1 ,
wherein R of the thermoplastic resin is a linear aliphatic hydrocarbon chain.
8. The thermoplastic resin as set forth in claim 7 ,
wherein R of the thermoplastic resin has even-numbered carbon atoms.
9. The thermoplastic resin as set forth in claim 7 ,
wherein R of the thermoplastic resin is at least one selected from the group consisting of —(CH 2 ) 8 —, —(CH 2 ) 10 —, and —(CH 2 ) 12 —.
10. The thermoplastic resin as set forth in claim 1 ,
wherein -y-R-z- of the thermoplastic resin is —O—CO—R—CO—O—.