Polyurethane ballast layer, the method for preparing the same and the use thereof
View Patent ↗The present invention relates to a polyurethane ballast layer, the method for preparing the same and a railway comprising the polyurethane ballast layer. The polyurethane ballast layer provided in this invention comprises a polyurethane-filled ballast layer and a polyurethane external protective layer, wherein the polyurethane-filled ballast layer comprises ballasts and polyurethane foam filled in the space among the ballasts. The polyurethane ballast layer provided in this invention can reduce the probability of ballast crashing, shifting and cracking under heavy load, and separate the ballast track from the outside environment to prevent rain, snow and wastes from entering into the internal space of the ballast track bed. Furthermore, the polyurethane ballast layer can keep the polyurethane foam filled in the ballasts layer away from water in the outside environment to avoid hydrolysis. The polyurethane ballast layer presented in this invention can be used in the railway ballast track bed to extend the track bed maintenance cycle, and save maintenance cost significantly.
1. A method comprising
providing a polyurethane-filled ballast layer
spraying a first reaction system onto a surface of the polyurethane-filled ballast layer to form a polyurethane external protective layer, wherein the first reaction system comprises
1a) one or more polyisocyanates having a general formula R(NCO) n , wherein, R is selected from the group consisting of an aliphatic alkyl group comprising 2 to 18 carbon atoms, an aromatic alkyl group comprising 6 to 15 carbon atoms and an arylated alkyl group comprising 8-15 carbon atoms, and n is an integer from 2 to 4;
1b) one or more polyether polyols and/or amine terminated polyether, having an average molecular weight of more than 200 and a functionality from 2 to 6;
1c) one or more extender; and
1d) from 0 to 0.5% by weight of one or more blowing agent, based on 100% by weight of 1b) and 1c);
wherein the tensile strength of the polyurethane external protective layer is from 4 to 20 MPa.
2. The method as claimed in claim 1 , wherein the density of the polyurethane external protective layer is from 0.6 to 1.5 g/cm 3 , the hardness of the polyurethane external protective layer is from 10 to 90 Shore A, and the elongation at break of the polyurethane external protective layer is from 100 to 550%.
3. The method as claimed in claim 1 , wherein the polyurethane-filled ballast layer comprises ballasts and polyurethane foam filled among the ballasts, wherein the polyurethane foam comprises a reaction product of a second reaction system comprising the reaction components of
2a) one or more polyisocyanates having a general formula R(NCO)n, wherein, R is selected from the group consisting of an aliphatic alkyl group comprising from 2 to 18 carbon atoms, an aromatic alkyl group comprising from 6 to 15 carbon atoms, and an arylated alkyl group comprising from 8 to 15 carbon atoms, n is an integer from 2 to 4;
2b) one or more polyols selected from the group consisting of polyether polyol, polyester polyol, polycarbonate polyol, polycaprolactone polyol and polytetrahydrofuran polyol;
2c) one or more extender; and
2d) from 0.3 to 4.5% by weight of one or more blowing agent, based on 100% by weight of 2b) and 2c);
wherein the elongation at break of the polyurethane foam is from 120 to 400%.
4. The method as claimed in claim 3 , wherein the density of the polyurethane foam is from 0.02 to 0.5 g/cm 3 , the hardness of the polyurethane foam is from 5 to 60 Asker C, and the tensile strength of the polyurethane foam is from 0.2 to 5 MPa.
5. A railway track bed comprising a polyurethane-filled ballast layer and a polyurethane external protective layer, wherein the polyurethane external protective layer comprises a reaction product of a first reaction system, wherein the first reaction system is sprayed onto a surface of the polyurethane-filled ballast layer, and wherein the first reaction system comprises the following reaction components:
1a) one or more polyisocyanates having a general formula R(NCO)n, wherein, R is selected from the group consisting of an aliphatic alkyl group comprising from 2 to 18 carbon atoms, an aromatic alkyl group comprising from 6 to 15 carbon atoms, and an arylated alkyl group comprising from 8 to 15 carbon atoms, n is an integer from 2 to 4;
1b) one or more polyether polyols and/or amine terminated polyether, having an average molecular weight of greater than 200 and a functionality from 2 to 6;
1c) one or more extender; and
1d) from 0 to 0.5% by weight of one or more blowing agent, based on 100% by weight of 1b) and 1c);
wherein the tensile strength of the polyurethane external protective layer is from 4 to 20 MPa.
6. The railway track bed as claimed in claim 5 , wherein the polyurethane external protective layer has a density of from 0.6 to 1.5 g/cm 3 , a hardness of from 10 to 90 Shore A, and an elongation at break of from 100 to 550%.
7. The railway track bed as claimed in claim 5 , wherein the polyurethane-filled ballast layer comprises ballasts and polyurethane foam filled among the ballasts, wherein the polyurethane foam comprises a reaction product of a second reaction system which comprises the reaction components of
2a) one or more polyisocyanates having a general formula R(NCO)n, wherein, R is selected from the group consisting of an aliphatic alkyl group comprising from 2 to 18 carbon atoms, an aromatic alkyl group comprising from 6 to 15 carbon atoms, and an arylated alkyl group comprising from 8 to 15 carbon atoms, n is an integer from 2 to 4;
2b) one or more polyols, selected from the group consisting of polyether polyol, polyester polyol, polycarbonate polyol, polycaprolactone polyol and polytetrahydrofuran polyol;
2c) one or more extender; and
2d) from 0.3 to 4.5% by weight of one or more blowing agent, based on 100% by weight of 2b) and 2c);
wherein the polyurethane foam has an elongation at break of from 120 to 400%.
8. The railway track bed as claimed in claim 7 , wherein the polyurethane foam has a density of from 0.02 to 0.5 g/cm 3 , a hardness of from 5 to 60 Asker C, and a tensile strength of from 0.2 to 5 MPa.
9. The railway track bed as claimed in claim 5 further comprising a railway road bed, wherein the polyurethane-filled ballast layer and the polyurethane external protective layers is positioned on top of the railway road bed.
10. A method of constructing a railway track bed as claimed in claim 5 , which comprises
providing a railway road bed, and
applying the polyurethane-filled ballast layer and the polyurethane external protective layer to a railway road bed.