Silicone-based material
Surface-structured, cross-linked silicone-based material and method for making the same. Embodiments of silicone-based materials described herein are useful, for example, in applications of light capture, anti-reflection, light redirection, light diffusion, hydrophobic surfaces, hydrophilic surfaces, light guiding, light collimation, light concentration, Fresnel lens, retro-reflection, drag reduction, air bleed adhesives, release liner, abrasion resistance, and anti-fouling.
1. A method of making a surface-structured, cross-linked silicone-based material, the method comprising:
providing a surface-structured silicone-based material, wherein the surface-structured material is substantially free of catalysts and initiators; and
exposing the surface-structured silicone-based material to an electron-beam to cross-link the silicone-based material, the cross-linked silicone-based material comprising a silicone pressure sensitive adhesive having a non-tacky structured surface, wherein the structured surface has peak to valley measurements of less than 250 micrometers.
2. The method of claim 1 , wherein the silicone-based material is a nonfunctionalized silicone.
3. The method claim 2 , wherein the silicone-based material is a polysiloxane.
4. The method of claim 2 , further comprising:
providing a replication tool having a major surface having at least one of nano-sized or micro-sized surface structures, and
applying the silicone-based material that is substantially free of the catalysts and initiators onto at least a portion of the major surface of the replication tool to form the surface-structured silicone-based material that is substantially free of the catalysts and initiators.
5. The method of claim 2 , further comprising:
providing a substrate having a first major surface;
coating the silicone-based material that is substantially free of the catalysts and initiators on at least a portion of the major surface of the substrate; and
contacting the coated composition with a major surface of a replication tool having at least one of nano-sized or micro-sized surface structures on the major surface to form the surface-structured silicone-based material that is substantially free of the catalysts and initiators.
6. The method of claim 5 , further comprising:
applying a primer coating composition onto at least a portion of the major surface of the substrate before coating the silicone-based material that is substantially free of the catalysts and initiators thereon.
7. The method of claim 1 , wherein the silicone-based material comprises a siloxane backbone and at least one functional group.
8. The method of claim 7 , wherein all functional groups are hydroxyl groups.
9. The method of claim 1 , wherein the silicone-based material is a polysiloxane.
10. The method of claim 1 , further comprising:
providing a replication tool having a major surface having at least one of nano-sized or micro-sized surface structures, and
applying the silicone-based material that is substantially free of the catalysts and initiators onto at least a portion of the major surface of the replication tool to form the surface-structured silicone-based material that is substantially free of the catalysts and initiators.
11. The method of claim 1 , further comprising:
providing a substrate having a first major surface;
coating the silicone-based material that is substantially free of the catalysts and initiators on at least a portion of the major surface of the substrate; and
contacting the coated composition with a major surface of a replication tool having at least one of nano-sized or micro-sized surface structures on the major surface to form the surface-structured silicone-based material that is substantially free of the catalysts and initiators.
12. The method of claim 11 , further comprising:
applying a primer coating composition onto at least a portion of the major surface of the substrate before coating the silicone-based material that is substantially free of the catalysts and initiators thereon.
13. The method of claim 1 , wherein the surface-structured, cross-linked silicone-based material has two generally opposed major surfaces with a first cross link density on one major surface and a cross link density on the generally opposed major surface, wherein the first cross-link density is greater than the second cross-link density.
14. The method of claim 13 , further comprising exposing the cross-linked surface-structured silicone-based material to a second pass of the electron-beam.
15. The method of claim 1 , wherein the surface-structured, cross-linked silicone-based material comprises a base portion integrally formed with the structured surface.
16. A method of making a release liner, the method comprising:
providing a surface-structured composition comprising silicone-based material on a substrate, wherein the composition is substantially free of catalysts and initiators;
exposing the surface-structured composition to an electron-beam to cross-link the silicone-based material to provide a release liner with a surface-structured, cross-linked silicone-based material, wherein the surface-structured, cross-linked silicone-based material comprises a structured surface having peak to valley measurements of less than 250 micrometers.
17. The method of claim 16 , wherein the silicone-based material is a nonfunctionalized silicone.
18. The method of claim 17 , wherein the silicone-based material comprises a siloxane backbone and at least one functional group.
19. The method of claim 18 , wherein all functional groups are hydroxyl groups.
20. The method of claim 16 , wherein the silicone-based material a polysiloxane.