Vinylbenzyl ethers of polycyclopentadiene polyphenol
View Patent ↗Embodiments include vinylbenzyl ethers of polycyclopentadiene polyphenol that can be obtained by reacting a polycyclopentadiene polyphenol with a vinylbenzyl halide. Embodiments also include thermosettable compositions including the vinylbenzyl ethers of a polycyclopentadiene polyphenol and products obtained by curing the thermosettable compositions. Formula (I).
1. A vinylbenzyl ether of polycyclopentadiene polyphenol of Formula I:
in which each n independently has a value from zero to 20; each m independently has a value of zero to 3; p has a value of zero to 20; each R is independently a halogen, a nitrile group, a nitro group, an alkyl group, an alkoxy group, an alkenyl group, or an alkenyloxy group, where the alkyl group, the alkoxy group, the alkenyl group, and the alkenyloxy group each independently contain 1 to 6 carbon atoms; each Q is independently hydrogen or an alkyl group containing 1 to 6 carbon atoms; and each X is a group of Formula II
in which each R 1 is independently a halogen, a nitrile group, a nitro group, an alkyl group, an alkoxy group, an alkenyl group, or an alkenyloxy group, where the alkyl group, the alkoxy group, the alkenyl group, and the alkenyloxy group each independently contain 1 to 6 carbon atoms; and each q independently has a value of zero to 4.
2. The vinylbenzyl ether of polycyclopentadiene polyphenol of claim 1 , wherein each R halogen and each R 1 halogen is independently selected from the group of fluorine, chlorine, and bromine.
3. The vinylbenzyl ether of polycyclopentadiene polyphenol of claim 1 , wherein each n independently has a value from zero to 8.
4. The vinylbenzyl ether of polycyclopentadiene polyphenol of claim 1 , wherein p has a value from zero to 1.
5. The vinylbenzyl ether of polycyclopentadiene polyphenol of claim 1 , wherein each alkyl group independently contains 1 to 2 carbon atoms.
6. The vinylbenzyl ether of polycyclopentadiene polyphenol of claim 1 , wherein each alkoxy group independently contains 1 to 2 carbon atoms.
7. The vinylbenzyl ether of polycyclopentadiene polyphenol of claim 1 , wherein m is zero.
8. A thermosettable composition comprising the vinylbenzyl ether of polycyclopentadiene polyphenol as in claim 1 .
9. The thermosettable composition of claim 8 , further comprising a comonomer selected from the group consisting of polymaleimides, polycyanates, polycyanamides, epoxy compounds, compounds containing one or more polymerizable ethylenically unsaturated group(s), and combinations thereof.
10. The thermosettable composition of claim 9 , wherein the comonomer is from 5 weight percent to 90 weight percent of a total weight percent the monomers included in the thermosettable composition.
11. A product obtainable by curing the thermosettable composition of claim 8 .
12. The product as in claim 11 , where the product comprises a B-staged product.
13. The product of claim 11 , where the product comprises an infusible polymer network.