Multilayer film having polyamide and polypropylene layers
View Patent ↗Multilayer films of polyamide and polypropylene which have good layer adhesion and are suitable for a back cover of a solar module are provided. In a first embodiment, the multilayer film contains in the order listed: a) a layer containing at least 35% by weight, of polyamide; c) a layer containing at least 35% by weight of a polypropylene; and e) a layer containing at least 35% by weight, of polyamide; wherein the layer c) further comprises a polypropylene having acid anhydride groups or a polypropylene compatible functionalized polyolefin having functional groups to adhere the layer c) to each of layers a) and e). In a second embodiment adhesion promoter layers are present between the respective polyamide and polypropylene layers.
1. A multilayer film, comprising, in the order listed:
a) a layer of a moulding composition which comprises at least 35% by weight, based on the overall layer moulding composition, of polyamide;
c) a layer of a moulding composition which comprises at least 35% by weight, based on the overall layer moulding composition, of a polypropylene;
e) a layer of a moulding composition which comprises at least 35% by weight, based on the overall moulding composition, of polyamide;
wherein
the layer c) further comprises a polypropylene having from 0.1 to 4% by weight of a copolymerized unsaturated anhydride, or
the layer c) further comprises a polypropylene compatible functionalized polyolefin which is selected from the group consisting of copolymers comprising at least 2 of ethylene, methyl acrylate and ethylacrylate which are functionalized with glycidyl methacrylate, maleic anhydride or a mixture thereof.
2. The multilayer film according to claim 1 , wherein
a thickness of the layer c) is from 100 to 500 μm.
3. The multilayer film according to claim 1 , wherein
a thickness of each of the layers a) and e) is independently from 15 to 100 μm.
4. The multilayer film according to claim 2 , wherein
a thickness of each of the layers a) and e) is independently from 15 to 100 μm.
5. The multilayer film according to claim 1 , wherein
the polyamide comprises at least one selected from the group consisting of a partly crystalline polyamide having an enthalpy of fusion of more than 25 J/g, a semicrystalline polyamide having an enthalpy of fusion of from 4 to 25 J/g and an amorphous polyamide having an enthalpy of fusion of less than 4 J/g.
6. The multilayer film according to claim 1 wherein the layer a), the layer c) or both layer a) and layer c) further comprise an impact-modifying rubber optionally modified with a polyamide compatible functional group.
7. A photovoltaic module, comprising;
a solar cell embedded in a sealing layer; and
the laminate film according to claim 1 as a back cover;
wherein the layer a) of the multilayer film is bonded to the sealing layer.
8. The photovoltaic module according to claim 7 ,
wherein a thickness of the layer c) is from 100 to 500 μm.
9. The photovoltaic module according to claim 7 ,
wherein a thickness of the layer a) and the layer e) is from 15 to 100 μm.
10. The photovoltaic module according to claim 8 ,
wherein a thickness of the layer a) and the layer e) is from 15 to 100 μm.
11. The photovoltaic module according to claim 7 , wherein the layer a), the layer c) or both layer a) and layer c) further comprise an impact-modifying rubber optionally modified with a polyamide compatible functional group.
12. A multilayer film, comprising, in the order listed:
a) a layer of a moulding composition which comprises at least 35% by weight, based on the overall layer moulding composition, of polyamide;
b) an adhesion promoter layer;
c) a layer of a moulding composition which comprises at least 35% by weight, based on the overall layer moulding composition, of a polypropylene;
d) an adhesion promoter layer; and
e) a layer of a moulding composition which comprises at least 35% by weight, based on the overall moulding composition, of polyamide;
wherein
the adhesion promoter layers b) and d) each comprise a polypropylene functionalized with an unsaturated dicarboxylic anhydride, an unsaturated dicarboxylic acid or an unsaturated dicarboxylic acid monoalkyl ester sufficient to adhere to the layer c) and to each of layer a) and layer e).
13. The multilayer film according to claim 12 wherein the functionalized polypropylene comprises from 0.1 to 4% by weight of an unsaturated anhydride.
14. A photovoltaic module, comprising;
a solar cell embedded in a sealing layer; and
the multilayer film according to claim 12 as a back cover;
wherein the layer a) of the laminate film is bonded to the sealing layer.
15. The photovoltaic module according to claim 14 ,
wherein a thickness of the layer c) is from 100 to 500 μm.
16. The photovoltaic module according to claim 14 ,
wherein a thickness of the layer a) and the layer e) is from 15 to 100 μm.
17. The photovoltaic module according to claim 15 ,
wherein a thickness of the layer a) and the layer e) is from 15 to 100 μm.