MULTILAYER FILM WITH OXYGEN PERMEATION BARRIER FOR THE PRODUCTION OF PHOTOVOLTAIC MODULES
A multilayered film and a photovoltaic module where the oxidation-sensitive solar cell is protected against ingress of oxygen provided. The solar cell is protected by the multilayer film as a back cover. The multilayer film comprises the following layers in direct succession: a solar cell-facing layer of a moulding composition comprising at least 70% by weight of EVOH, an adhesion promoter layer, a middle layer of a thermoplastic moulding composition, an optional adhesion promoter layer, and an outer layer comprising at least 35% by weight of polyamide.
1 . A multilayer film, comprising, in the order listed:
a) a layer of a moulding composition which comprises at least 70% by weight, based on the overall layer moulding composition, of an ethylene-vinyl alcohol (EVOH) copolymer;
b) an adhesion promoter layer;
c) a layer of a moulding composition which comprises a thermoplastic polymer;
d) optionally, an adhesion promoter layer; and
e) a layer comprising at least 35% by weight, based on the overall moulding composition, of polyamide.
2 . The multilayer film according to claim 1 , wherein
when the layer c) comprises a thermoplastic polymer selected from the group consisting of a polyamide, a polyester and a polyolefin, the adhesion promoter layer b) comprises at least 35% by weight of a polyolefin having 0.1 to 5% by weight of acid anhydride groups, or
when the layer c) comprises a thermoplastic polymer selected from the group consisting of a polyamide and a polyester, the adhesion promoter layer b) comprises a polyamine-polyamide graft copolymer
3 . The multilayer film according to claim 1 , wherein
a thickness of the layer a) is from 50 to 250 μm.
4 . The multilayer film according to claim 3 , wherein
a thickness of the layer b) is from 15 to 100 μm,
a thickness of the layer c) is from 100 to 500 μm, and
a thickness of the layer e) is from 15 to 100 μm.
5 . The multilayer film according to claim 4 , which comprises a layer d) and a thickness of the layer d) is from 3 to 100 μm.
6 . The multilayer film according to claim 1 , wherein
an ethylene content of the EVOH is from 25 to 60 mol %.
7 . The multilayer film according to claim 1 , wherein at least the polyamide of layer e) comprises at least one selected from the group consisting of a partly crystalline polyamide having an enthalpy of fusion of more than 25 J/g, a semicrystalline polyamide having an enthalpy of fusion of from 4 to 25 J/g and an amorphous polyamide having an enthalpy of fusion of less than 4 J/g.
8 . The multilayer film according to claim 1 , wherein the polyolefin is selected from the group consisting of polyethylene, anisotactic or atactic homopolypropylene, a random copolymer of propene with ethene, a random copolymer of propene, ethene and 1-butene, and an ethylene-propylene block copolymer any of which optionally comprising an impact-modifying component.
9 . The multilayer film according to claim 1 wherein at least one of the layer a), the layer b) and the layer c) further comprises titanium dioxide.
10 . A photovoltaic module, comprising;
a solar cell embedded in a sealing layer; and
the multilayer film according to claim 1 as a back cover;
wherein the layer a) of the laminate film is bonded to the sealing layer.
11 . The photovoltaic module according to claim 10 ,
wherein a thickness of the layer a) is from 50 to 250 μm.
12 . The photovoltaic module according to claim 11 , wherein
a thickness of the layer b) is from 15 to 100 μm,
a thickness of the layer c) is from 100 to 500 μm, and
a thickness of the layer e) is from 15 to 100 μm.
13 . The photovoltaic module according to claim 12 ,
which comprises a layer d) and a thickness of the layer d) is from 3 to 100 μm.
14 . The photovoltaic module according to claim 12 , wherein an ethylene content of the EVOH is from 25 to 60 mol %.
15 . The photovoltaic module according to claim 10 , wherein
the layer a) comprises ethylene vinyl alcohol and titanium dioxide,
the layer b) comprises a polyamine-polyamide graft copolymer and a EVOH compatible polyamide,
the layer c) comprises a polyolefin,
the layer d) is present and comprises a polyamide and polyolefin, and
the layer e) further comprises titanium dioxide.