IP Library Granted Patent US 8,795,418
Granted Patent B2
US 8,795,418 · App. 13/657,109 · Granted Aug 5, 2014

Adsorptive member and apparatus using the same

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Quick Facts
Patent No.
US 8,795,418
App. No.
13/657,109
Granted
Aug 5, 2014
Kind
B2
Abstract

The present invention provides an adsorptive member which is used in a heat exchanger such as an adsorptive heat pump or a humidity control apparatus such as a desiccant system and which is excellent in heat resistance and adhesion between adsorptive particles and a base material. The adsorptive member comprising a base material and an adsorptive material layer formed on the base material, wherein the adsorptive material layer comprises adsorptive particles and a binder as essential components, and the binder is an epoxy cured product comprising the following structural units (a) and (b): (a): a bisphenol type structural unit; and (b): a linear hydrocarbon structural unit having 4 or more carbon atoms, and/or a polyalkylene ether structural unit having 3 or more ether oxygen atoms.

Claims (26)

1. An adsorptive member comprising a base material and an adsorptive material layer formed on the base material,

wherein the adsorptive material layer comprises adsorptive particles and a binder as essential components,

and the binder is an epoxy cured product comprising the following structural units (a) and (b):

(a): a bisphenol type structural unit; and

(b): a linear hydrocarbon structural unit having 4 or more carbon atoms, and/or a polyalkylene ether structural unit having 3 or more ether oxygen atoms.

2. The adsorptive member according to claim 1 , wherein a glass transition temperature (Tg) of the epoxy cured product lies within a temperature range of the adsorptive member upon use.

3. The adsorptive member according to claim 1 , wherein the adsorptive material layer has a pencil hardness of not less than 4H at 20° C., less than 4H at 100° C. and not less than 6B at 150° C.

4. The adsorptive member according to claim 1 , wherein the binder further comprises a phenoxy resin.

5. The adsorptive member according to claim 1 , wherein the adsorptive particles are formed of at least one material selected from the group consisting of zeolite, silica gel and mesoporous silica.

6. The adsorptive member according to claim 1 , wherein the adsorptive particles are formed of zeolite comprising a material selected from the group consisting of an aluminosilicate and an aluminophosphate, or zeolite comprising combination of any two or more thereof.

7. The adsorptive member according to claim 1 , wherein the adsorptive particles have a change in adsorption of not less than 0.10 g/g when a change in relative vapor pressure is 0.15 in a relative vapor pressure range of not less than 0.01 and not more than 0.5 in a water vapor adsorption isotherm curve as measured at 25° C.

8. The adsorptive member according to claim 1 , wherein the base material is in the form of at least one selected from the group consisting of a plate, a tube, a honeycomb, a sheet, a net and a nonwoven fabric.

9. The adsorptive member according to claim 1 , wherein the base material is at least one material selected from the group consisting of metals, ceramic materials and inorganic fibers.

10. The adsorptive member according to claim 1 , wherein the adsorptive material layer is formed by

applying a slurry comprising at least the adsorptive particles and an aqueous emulsion of the following specific epoxy resin, and a curing agent, onto the base material, and then drying and

curing the slurry thus applied;

wherein said epoxy resin is

an epoxy resin comprising the following structural units (a) and (b),

a combination of an epoxy resin comprising at least one of the following structural units (a) and (b) and an epoxy resin comprising at least the other of the following structural units (a) and (b), or

a combination of an epoxy resin comprising the following structural unit (a) and a chain extender capable of adding the following structural unit (b) to the epoxy resin by reacting with the epoxy resin;

wherein the structural unit (a) is a bisphenol type structural unit and the structural unit (b) is a linear hydrocarbon structural unit having 4 or more carbon atoms and/or a polyalkylene ether structural unit having 3 or more ether oxygen atoms.

11. A heat exchanger comprising the adsorptive member as defined in claim 1 .

12. An adsorptive heat pump comprising the heat exchanger as defined in claim 11 .

13. A warm water and/or cold water production apparatus comprising the adsorptive heat pump as defined in claim 12 .

14. A humidity control apparatus comprising the adsorptive member as defined in claim 1 .

15. The humidity control apparatus according to claim 14 , wherein the apparatus is a desiccant rotor.

Assignments (3)
CHANGE OF NAME Recorded Sep 5, 2017
From: MITSUBISHI RAYON CO., LTD.
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 043750/0834 →
MERGER Recorded Aug 31, 2017
From: MITSUBISHI PLASTICS, INC
To: MITSUBISHI RAYON CO., LTD.
Reel/Frame 043746/0912 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 12, 2012
From: TABATA, DAIKI; OKAMOTO, KUMIKO; TANIGUCHI, KOUICHIROU; KUBOKAWA, SEIICHI
To: MITSUBISHI PLASTICS, INC.
Reel/Frame 029451/0350 →