Eco-friendly poly(alkylene carbonate) resin composition for high-transparency and high-gloss sheet
View Patent ↗Provided is an eco-friendly poly(propylene carbonate) resin composition for a sheet, which is characterized by using a poly(alkylene carbonate) resin developed by efficiently utilizing carbon dioxide, which is a major contributor to global warding, as a main material, and including appropriate additives, such as, a strength modifier, and a flexibilizer, thereby completely solving environmental hazards controversy of the existing polyvinyl chloride resin products; exhibiting excellent mechanical and thermal properties, processability, post processability (printability, embossing and surface treatment, laminating characteristics) and superior anti-flaming property (low smoke density) and elongation characteristics as compared with the existing polyvinyl chloride resin products; and overcoming an extruding production method which is a small-sized production manner, corresponding to a big defect in thermoplastic plastics emerged as substitutes for polyvinyl chloride resin products and thus applying a calendering process method which is a mass production manner.
1. A poly(alkylene carbonate) resin composition for a high-transparency and high-gloss sheet, comprising: based on 100 parts by weight of a poly(alkylene carbonate) resin, 0.1˜100 parts by weight of a strength modifier, 0.1˜50 parts by weight of a flexibilizer, and 0.1˜5 parts of a lubricant, wherein it has smoke density (ASTM E662) of 10˜50 m 2 /g.
2. The poly(alkylene carbonate) resin composition of claim 1 , wherein it satisfies Formulas 1 and 2 below:
10≦T DS ≦50 [Formula 1]
60≦T HRR ≦65 [Formula 2]
(wherein in Formula 1, T DS represents a smoke density (ASTM E662, m 2 /g) value and in Formula 2, T HRR represents a heat emission (MJ/m 2 ) value).
3. The poly(alkylene carbonate) resin composition of claim 1 , wherein the poly(alkylene carbonate) resin is prepared by copolymerization of carbon dioxide and at least one epoxide compound selected from the group consisting of (C2-C20)alkyleneoxide substituted or unsubstituted with halogen, (C1-C20)alkyloxy, (C6-C20)aryloxy, or (C6-C20)ar(C1-C20)alkyl(aralkyl)oxy; (C4-C20)cycloalkyleneoxide substituted or unsubstituted with halogen, (C1-C20)alkyloxy, (C6-C20)aryloxy or (C6-C20)ar(C1-C20)alky(aralkyl)oxy; and (C8-C20)styreneoxide substituted or unsubstituted with halogen, (C1-C20)alkyloxy, (C6-C20)aryloxy, (C6-C20)ar(C1-C20)alkyl(aralkyl)oxy, or (C1-C20)alkyl.
4. The poly(alkylene carbonate) resin composition of claim 1 , wherein the poly(alkylene carbonate) resin is represented by Chemical Formula 1 below:
(wherein in the Chemical Formula 1, w is an integer of 2 to 10, x is an integer of 5 to 100, y is an integer of 0 to 100, n is an integer of 1 to 3, and R is hydrogen, (C1-C4) alkyl, or —CH 2 —O—R′ (R′ is (C1-C8) alkyl).
5. The poly(alkylene carbonate) resin composition of claim 1 , wherein the poly(alkylene carbonate) resin has a weight average molecular weight of 50,000 to 1,000,000.
6. The poly(alkylene carbonate) resin composition of claim 1 , wherein the poly(alkylene carbonate) resin has a specific weight of 1.1 to 1.2 g/cm 3 .
7. The poly(alkylene carbonate) resin composition of claim 1 , wherein the poly(alkylene carbonate) resin is obtained by copolymerization of polypropylene oxide and carbon dioxide.
8. The poly(alkylene carbonate) resin composition of claim 1 , wherein the strength modifier is at least one selected from poly(methyl methacrylate) based resin, linear low-density polyethylene, low-density polyethylene, random polypropylene, random ter-polypropylene, impact polypropylene, acrylonitrile rubber, polyester, ethylene propylene diene copolymer, polylactic acid, poly glycolic acid, polycaprolactone, poly(lactide-co-glycolide), polyethylene adipate, polyhydroxy alcanoate, and poly acrylic nitrite.
9. The poly(alkylene carbonate) resin composition of claim 8 , wherein the polymethylmethacrylate based resin is polymethylmethacrylate alone or a mixture of 50˜85% of polymethacrylate, 15˜5% of polymethyl acrylate, and 35˜5% of polybutyl acrylate, and has a glass transition temperature (Tg) of 85˜165° C.
10. The poly(alkylene carbonate) resin composition of claim 8 , wherein the polyacrylonitrile has an acrylonitrile content of 20˜50%, Mooney density (ML1+4, 100° C.) of 40˜100, and a specific weight of 0.96˜1.00.
11. The poly(alkylene carbonate) resin composition of claim 8 , wherein the polyester has a structure of Chemical Formula 3 below:
(wherein in Chemical Formula 3, m is an integer of 2 to 10; n is an integer of 0 to 18; p is an integer of 2 to 10; and v, w, x, and y each are an integer of 0 to 100).
12. The poly(alkylene carbonate) resin composition of claim 8 , wherein the ethylenepropylenediene copolymer has an ethylene content of 50 to 75 wt. % and Mooney viscosity (ML1+4, 125° C.) of 20 to 110.
13. The poly(alkylene carbonate) resin composition of claim 8 , wherein the linear low-density polyethylene has density of 0.91 g/cm 2 or lower.
14. The poly(alkylene carbonate) resin composition of claim 8 , wherein the low-density polyethylene has density of 0.91˜0.925 g/cm 2 .
15. The poly(alkylene carbonate) resin composition of claim 1 , wherein the flexibilizer is at least one selected from acrylate based compounds and glutaric acid compounds.
16. The poly(alkylene carbonate) resin composition of claim 1 , wherein, the lubricant is at least one selected from stearic acid, dioctylterephthalate, and silicon oil.
17. The poly(alkylene carbonate) resin composition of claim 1 , further comprising: 0.1 to 5 parts by weight of at least one compatibilizer selected from the group consisting of a polyethylene based compound including polyethylene and maleic anhydride; an ethylene vinylacetate based compound including ethylene vinylacetate, polystyrene, and maleic anhydride; and a low low-density polyethylene based compound including low low-density polyethylene and maleic anhydride.
18. An article manufactured by using the composition of claims 1 .