Thermoplastic multi-ply film with metallic appearance
Laminated multi-ply films where one film layer is substantially unpigmented and the other film layer is substantially pigmented can provide a metallic appearance when the substantially unpigmented film layer is cold stretched either prior to lamination or during the lamination step. This surprising result provides an inexpensive way to produce films with a metallic appearance. Trash bags having an inner bag and an outer bag laminated together may be formed according to this process.
1. A laminated multi-ply thermoplastic film comprising:
a first film ply being substantially un-pigmented and cold stretched; and
a second film ply being substantially pigmented with a nonmetallic pigment;
wherein the first film ply and the second film ply are laminated by a lamination process resulting in lamination selected from the group consisting of discontinuous lamination, partially discontinuous lamination, and grided discontinuous lamination; and
wherein the laminated multi-ply thermoplastic film has a metallic appearance.
2. The film of claim 1 , wherein the lamination process comprises cold stretched lamination.
3. The film of claim 2 , wherein the lamination process comprises MD ring rolling.
4. The film of claim 2 , wherein the lamination process comprises TD ring rolling.
5. The film of claim 2 , wherein the lamination process comprises strainable network formation.
6. The film of claim 1 , wherein the lamination process comprises un-stretched lamination.
7. The film of claim 1 , wherein the nonmetallic pigment is carbon black.
8. The film of claim 1 , wherein the lamination process in partially discontinuous lamination.
9. The film of claim 1 , wherein the lamination process in gridded discontinuous lamination.
10. A laminated multi-ply thermoplastic film comprising:
a first film ply being substantially unpigmented; and
a second film ply being substantially pigmented with a nonmetallic pigment;
wherein the first film ply and the second film ply are laminated by a lamination process resulting in lamination selected from the group consisting of discontinuous lamination, partially discontinuous lamination, and grided discontinuous lamination, wherein the lamination process that results in cold stretching of the first film ply; and
wherein the laminated multi-ply thermoplastic film has a metallic appearance.
11. The film of claim 10 , wherein the substantially pigmented ply comprises pigmented with carbon black.
12. The film of claim 10 , wherein the lamination process comprises MD ring rolling.
13. The film of claim 10 , wherein the lamination process comprises TD ring rolling.
14. The film of claim 10 , wherein the lamination process comprises strainable process network formation.