Methods to improve filtration for the Bayer process
View Patent ↗The invention provides methods and compositions for improving the production of alumina trihydrate. The invention involves adding one or more cross-linked polysaccharides to a filter used to separate solids from liquid in the Bayer process. The one or more polysaccharides can be a cross-linked polysaccharide (such as cross-linked dextran or cross-linked dihydroxypropyl cellulose). The cross-linked polysaccharides can impart a number of advantages including greater flow rate and lower residual moisture in the resulting cake.
1. A method of enhancing filtration of slurry produced within a Bayer process, the method comprising: adding a composition comprising at least one cross-linked polysaccharide to the slurry to create a treated slurry; and filtering the treated slurry.
2. The method of claim 1 , wherein the composition consists essentially of cross-linked polysaccharide.
3. The method of claim 1 , wherein solids obtained from the filtering have less residual moisture than a filtered sample of the slurry in which either no composition was added or in which a composition comprising the same type and amount of polysaccharides but in a non-cross linked form was added.
4. The method of claim 1 , wherein the treated slurry has a faster filtration rate than a filtered sample of the slurry in which either no composition was added or in which a composition comprising the same type and amount of polysaccharides but in a non-cross linked form was added.
5. The method of claim 1 , wherein the treated slurry further comprises red mud and is filtered via red mud security filtration.
6. The method of claim 5 , wherein the treated slurry further comprises alumina trihydrate product and is filtered via alumina trihydrate product filtration.
7. The method of claim 1 , wherein the treated slurry further comprises alumina trihydrate seeds and is filtered via alumina trihydrate seed filtration.
8. The method of claim 1 , wherein the treated slurry further comprises red mud and is filtered via red mud filtration.
9. The method of claim 1 , further comprising contacting solids obtained from the filtering with at least one of washwater and washwater containing a dewatering aid.
10. The method of claim 1 , wherein the at least one cross-linked polysaccharide is produced from at least one of dihydroxypropyl cellulose and dextran.
11. The method of claim 1 , wherein the at least one cross-linked polysaccharide is produced from one or more cross-linking agents selected from the group consisting of: epochlorohydrin; dichloroglycerol; divinyl sulfone; bisepoxide; phosphorus oxychloride; a trimetaphosphate; dicarboxylic acid anhydride; N,N′-methylenebisacrylamide; 2,4,6-trichloro-s-triazine and combinations thereof.
12. The method of claim 1 , wherein the at least one cross-linked polysaccharide is a copolymer comprising monomers other than saccharides.
13. The method of claim 1 , wherein the filtering incorporates the application of vacuum, pressure, gravity, and combinations thereof.
14. The method of claim 1 , wherein the composition comprising the at least one cross-linked polysaccharide is added to the slurry as a solid or a liquid.
15. The method of claim 1 , wherein the slurry selected from the group consisting of: underflow from a settler in a clarification stage, overflow from a settler in a clarification stage, underflow from a washer in a red mud washing stage, underflow from a settler in a classification stage, underflow from a hydrocyclone, and overflow from a hydrocyclone.
16. The method of claim 1 , further comprising adding scleroglucan to at least one of the slurry and the treated slurry.