Polarizer having enhanced photodurability and method for preparing the same
A polarizer includes boric acid, potassium iodide, and a zinc salt. The zinc salt has a concentration gradient in which the concentration of the zinc salt gradually decreases from a surface of the polarizer to an interior thereof.
1. A polarizer comprising:
boric acid;
potassium iodide; and
a zinc salt, wherein the zinc salt has a concentration gradient in which the concentration of the zinc salt gradually decreases from a surface of the polarizer to an interior thereof.
2. The polarizer as claimed in claim 1 , wherein:
on the surface of the polarizer, the concentration of the zinc salt is at least about 80% of the total concentration of the zinc salt, and
at a point of about 40% of a total thickness of the polarizer from the surface thereof, the concentration of the zinc salt is about 20% or less of the total concentration of the zinc salt.
3. The polarizer as claimed in claim 1 , wherein the concentration gradient has a concentration profile as defined by Equation 1:
C ( d )=−4.0268× Ln ( x )+39.129; [Equation 1]
wherein C(d) is the concentration of the zinc salt at a depth d of the polarizer from the surface thereof, and x is a depth from the surface of the polarizer.
4. The polarizer as claimed in claim 1 , wherein the polarizer includes:
about 15 wt % to about 30 wt % of boric acid,
about 1 wt % to about 5 wt % of potassium iodide, and
about 0.01 wt % to about 0.5 wt % of the zinc salt.
5. The polarizer as claimed in claim 1 , wherein the polarizer has a ΔE ab value less than or equal to about 3.5, as obtained by Equation 2:
Δ E ab =√{square root over (( Lc 500 −Lc 0 ) 2 +( ac 500 −ac 0 ) 2 +( bc 500 −bc 0 ) 2 ,)}{square root over (( Lc 500 −Lc 0 ) 2 +( ac 500 −ac 0 ) 2 +( bc 500 −bc 0 ) 2 ,)}{square root over (( Lc 500 −Lc 0 ) 2 +( ac 500 −ac 0 ) 2 +( bc 500 −bc 0 ) 2 ,)} [Equation 2]
wherein Lc 500 , ac 500 and bc 500 are chromaticity values of the polarizer in an orthogonal state measured after heating the polarizer at 85° C. for 500 hours, and Lc 0 , ac 0 and bc 0 are chromaticity values of the polarizer in an initial state.
6. A method for preparing a polarizer, the method comprising:
immersing a polyvinyl alcohol film in an aqueous dyeing solution containing iodine and potassium iodide to obtain a dyed polyvinyl alcohol film; immersing the polyvinyl film in a swelling bath before immersing the polyvinyl alcohol film in the aqueous dyeing solution;
immersing the dyed polyvinyl alcohol film in an aqueous cross-linking solution containing boric acid and potassium iodide to obtain a cross-linked polyvinyl alcohol film;
stretching the cross-linked polyvinyl alcohol film in an aqueous stretching solution containing boric acid and potassium iodide to obtain a stretched polyvinyl alcohol film; and
immersing the stretched polyvinyl alcohol film in an aqueous color correction solution containing boric acid, potassium iodide, and a zinc salt.
7. The method as claimed in claim 6 , wherein the aqueous color correction solution contains about 0.8 wt % to about 1.2 wt % of boric acid, about 3.6 wt % to about 4.0 wt % of potassium iodide, and about 1 wt % to about 2 wt % of zinc salt, with a balance thereof being water.
8. The method as claimed in claim 6 , wherein the aqueous stretching solution contains about 2.5 wt % to about 5.0 wt % of boric acid, about 1.0 wt % to about 5.0 wt % of potassium iodide, a balance thereof being water, the aqueous stretching solution being free of a zinc salt.
9. The method as claimed in claim 6 , further comprising immersing the polyvinyl film in a swelling bath before immersing the polyvinyl alcohol film in the aqueous dyeing solution.
10. A polarizer fabricated by the method as claimed in claim 6 , wherein, on a surface of the polarizer, the polarizer has a concentration of a zinc salt of about 80% or more of a total concentration of the zinc salt and, at a depth of about 40% of a total thickness of the polarizer from the surface thereof, the polarizer has a concentration of the zinc salt of about 20% or less of the total concentration of the zinc salt.
11. A polarizer fabricated by the method as claimed in claim 7 , wherein, on a surface of the polarizer, the polarizer has a concentration of a zinc salt of about 80% or more of a total concentration of the zinc salt and, at a depth of about 40% of a total thickness of the polarizer from the surface thereof, the polarizer has a concentration of the zinc salt of about 20% or less of the total concentration of the zinc salt.
12. A polarizer fabricated by the method as claimed in claim 8 , wherein, on a surface of the polarizer, the polarizer has a concentration of a zinc salt of about 80% or more of a total concentration of the zinc salt and, at a depth of about 40% of a total thickness of the polarizer from the surface thereof, the polarizer has a concentration of the zinc salt of about 20% or less of the total concentration of the zinc salt.