Filter for electrochemical cell
View Patent ↗An electrochemical cell system is configured to utilize an ionically conductive liquid flowing through a plurality of electrochemical cells. One or more hydrophilic filters for venting of gas from the cells are provided along a flow path for the ionically conductive liquid, so as to permit gasses that evolve in the ionically conductive liquid during charging or discharging to vent outside the cell system, while constraining the ionically conductive liquid within the flow path of the electrochemical cell system.
1. An electrochemical cell system comprising:
a fuel electrode comprising a metal fuel;
an oxidant electrode for absorbing and reducing a gaseous oxidant;
a chamber configured to contain a volume of ionically conductive liquid therein, wherein the ionically conductive liquid contains a salt dissolved therein and conducts ions between the fuel and oxidant electrodes, and wherein the oxidant electrode separates the ionically conductive liquid from the gaseous oxidant; and
a filter configured to separate gas in the cell from the ionically conductive liquid, the filter comprising:
a wick configured to absorb a portion of the ionically conductive liquid therein; and
a hydrophilic body portion positioned generally above the volume of ionically conductive liquid, coupled to said wick so as to receive the absorbed portion of the ionically conductive liquid from said wick;
wherein the hydrophilic body portion contains pores therein so as to permit permeation of the gas therethrough, and
wherein the wick extends from the hydrophilic body portion towards and into the volume of ionically conductive liquid.
2. The electrochemical cell system of claim 1 , wherein the wick is integrally formed with the hydrophilic body portion.
3. The electrochemical cell system of claim 1 , wherein the hydrophilic body portion comprises a plurality of winds between a side of the hydrophilic body portion distal to the wick and a side of the hydrophilic body portion proximal to the wick, wherein the absorbed portion of the ionically conductive liquid is drawn from the wick along each of the plurality of winds while gas passes through the pores in each of the plurality of winds from the side of the hydrophilic body portion proximal to the wick to the side of the hydrophilic body portion distal to the wick.
4. The electrochemical cell system of claim 3 , wherein the pores of each of the plurality of winds are progressively smaller from the side of the hydrophilic body portion proximal to the wick to the side of the hydrophilic body portion distal to the wick.
5. The electrochemical cell system of claim 3 , wherein the pores of each of the plurality of winds are approximately the same size throughout the hydrophilic body portion.
6. The electrochemical cell system of claim 1 , further comprising a housing substantially surrounding the hydrophilic body portion so as to form a filter channel.
7. The electrochemical cell system of claim 6 , wherein a bottom portion of the housing is angled towards the volume of ionically conductive liquid such that excess amounts of the absorbed portion of the ionically conductive liquid in the channel is directed towards the volume of the ionically conductive liquid.
8. The electrochemical cell system of claim 7 , wherein the bottom portion is angled towards the ionically conductive liquid at an angle greater than zero degrees but less than approximately 90 degrees.
9. The electrochemical cell system of claim 8 , wherein the bottom portion is angled towards the ionically conductive liquid at an angle greater than zero degrees but less than approximately 45 degrees.
10. The electrochemical cell system of claim 9 , wherein the bottom portion is angled towards the ionically conductive liquid at an angle greater than zero degrees but less than approximately 25 degrees.
11. The electrochemical cell system of claim 6 , further comprising a channel exit at an end of the filter channel distal from the volume of ionically conductive liquid.
12. The electrochemical cell system of claim 11 , wherein the channel exit comprises a gas vent configured to permit permeation of the gas therethrough, while preventing permeation of the ionically conductive liquid.
13. The electrochemical cell system of claim 12 , wherein the gas vent comprises a hydrophobic membrane extending across the filter channel.
14. The electrochemical cell system of claim 6 , wherein the filter channel is vertically oriented such that excess amounts of the absorbed portion of the ionically conductive liquid in the channel may fall directly towards the volume of the ionically conductive liquid.
15. The electrochemical cell system of claim 14 , wherein the filter body is positioned spaced from the top of the filter channel.
16. The electrochemical cell system of claim 1 , wherein at least some of the gas is encapsulated within bubbles of ionically conductive liquid.
17. The electrochemical cell system of claim 16 , wherein the pores of the hydrophilic body portion are configured to capture the bubbles.
18. The electrochemical cell of claim 16 , wherein said gas comprises bubbles of ionically conductive liquid within the chamber.