Purification of trichlorosilane
View Patent ↗Systems and methods for removing boron-containing contaminants from a composition comprising trichlorosilane to form a purified product comprising trichlorosilane are disclosed. Purification columns and devices, having various locations of inlet and outlet ports, are fluidly connected to each other in order to remove various types of boron species and other impurities present in TCS.
1. A method of removing at least one boron-containing contaminant from a composition comprising trichlorosilane to form a purified product comprising trichlorosilane, the method comprising the steps of:
i) partially removing the boron-containing contaminant from the composition by feeding the composition into a first column through an upper inlet port proximal to a top end thereof, and removing from the first column
a) a first top boron-containing contaminant stream through a top outlet port, and
b) a partially purified composition comprising trichlorosilane through a bottom outlet port thereof, and
ii) feeding the partially purified composition into a purification column through a side inlet port and removing from the purification column
a) a top boron-containing contaminant stream through a top outlet port,
b) a bottom boron-containing contaminant stream through a bottom outlet port, and
c) a purified composition comprising trichlorosilane through a side outlet port.
2. The method of claim 1 , wherein the side outlet port of the purification column is above the side inlet port of the purification column.
3. The method of claim 1 , wherein the side outlet port of the purification column is below the side inlet port of the purification column.
4. The method of claim 1 , wherein the purified composition is the purified product.
5. The method of claim 4 , wherein the side outlet port of the purification column is above the side inlet port of the purification column.
6. The method of claim 1 , wherein the method further comprises the step of passing the purified composition through at least one additional purification device to form the purified product.
7. The method of claim 6 , wherein the additional purification device is a treatment vessel comprising at least one metal oxide.
8. The method of claim 7 , wherein the treatment vessel comprises a bed of the metal oxide.
9. The method of claim 7 , wherein the metal oxide is silica gel.
10. The method of claim 1 , wherein the purified product has a boron content of less than or equal to about 0.5 ppb by weight boron.
11. The method of claim 1 , where in the method further comprises at least one step of recycling at least one boron-containing contaminant stream.