IP Library Granted Patent US 8,971,476
Granted Patent B2
US 8,971,476 · App. 13/670,808 · Granted Mar 3, 2015

Deposition of integrated protective material into zirconium cladding for nuclear reactors by high-velocity thermal application

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 8,971,476
App. No.
13/670,808
Granted
Mar 3, 2015
Kind
B2
Abstract

A zirconium alloy nuclear reactor cylindrical cladding has an inner Zr substrate surface ( 10 ), an outer volume of protective material ( 22 ), and an integrated middle volume ( 20 ) of zirconium oxide, zirconium and protective material, where the protective material is applied by impaction at a velocity greater than 340 meters/second to provide the integrated middle volume ( 20 ) resulting in structural integrity for the cladding.

Claims (13)

1. A zirconium alloy nuclear reactor cylindrical cladding, subject to a nuclear reactor environment, the cladding having

an inner surface and inner volume of zirconium alloy,

an outer surface and outer volume of a protective material,

wherein the protective material is a Ti—Al—C ceramic, and

an integrated middle volume of zirconium oxide, zirconium, and excess sound velocity-impacted protective material,

where the highest density of protective material is at the cladding outer surface to protect the cladding from reactor environment and any further oxidation of the zirconium,

where the integrated middle volume provides structural integrity for the cladding.

2. The nuclear reactor cylindrical cladding of claim 1 , wherein the protective material penetrates through zirconium oxide and into zirconium alloy due to an impact velocity greater than 340 meters/second.

3. The nuclear reactor cylindrical cladding of claim 1 , wherein the protective material penetrates through zirconium oxide and into zirconium alloy due to impact velocity between 400 m/s and 1,200 m/s.

4. The nuclear reactor cylindrical cladding of claim 1 , wherein the protective material was applied by either a cold spray process or a thermal kinetic deposition.

5. The nuclear reactor cylindrical cladding of claim 4 , wherein the temperature of the cold spray process is between 250° C. and 1,200° C., and for thermal-kinetic deposition, is between 1,200° C. and 3,500° C.

6. The nuclear reactor cylindrical cladding of claim 1 , wherein the protective material particle size is between 1 μm and 500 μm.

7. The nuclear reactor cylindrical cladding of claim 1 , wherein the thickness of deposition of protective material is between 1 μm and 200 μm.

Assignments (9)
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Jan 30, 2024
From: CREDIT SUISSE AG, CAYMAN ISLANDS, AS COLLATERAL AGENT
To: WESTINGHOUSE ELECTRIC COMPANY LLC; FAUSKE AND ASSOCIATES LLC
Reel/Frame 066380/0392 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Jan 30, 2024
From: BANK OF MONTREAL, AS COLLATERAL AGENT
To: WESTINGHOUSE ELECTRIC COMPANY LLC; BHI ENERGY I SPECIALTY SERVICES LLC
Reel/Frame 066380/0599 →
SECURITY INTEREST Recorded Jan 26, 2024
From: WESTINGHOUSE ELECTRIC COMPANY LLC; BHI ENERGY I SPECIALTY SERVICES LLC; STONE & WEBSTER, L.L.C. (FORMERLY STONE & WEBSTER, INC.)
To: DEUTSCHE BANK AG NEW YORK BRANCH, AS COLLATERAL AGENT
Reel/Frame 066373/0604 →
PATENT SECURITY AGREEMENT Recorded May 27, 2022
From: WESTINGHOUSE ELECTRIC COMPANY LLC; BHI ENERGY I SPECIALTY SERVICES LLC
To: BANK OF MONTREAL, AS COLLATERAL AGENT
Reel/Frame 060791/0372 →
CONFIRMATORY LICENSE Recorded Nov 26, 2019
From: WESTINGHOUSE ELECTRIC COMPANY, LLC
To: UNITED STATES DEPARTMENT OF ENERGY
Reel/Frame 051115/0058 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Aug 1, 2019
From: GOLDMAN SACHS BANK USA, AS COLLATERAL AGENT
To: WESTINGHOUSE ELECTRIC COMPANY LLC; FAUSKE AND ASSOCIATES LLC
Reel/Frame 049937/0032 →
SECURITY INTEREST Recorded Aug 1, 2018
From: WESTINGHOUSE ELECTRIC COMPANY LLC; FAUSKE AND ASSOCIATES LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 046708/0222 →
SECURITY INTEREST Recorded Aug 1, 2018
From: WESTINGHOUSE ELECTRIC COMPANY LLC; FAUSKE AND ASSOCIATES LLC
To: GOLDMAN SACHS BANK USA, AS COLLATERAL AGENT
Reel/Frame 046708/0332 →
SECURITY INTEREST Recorded Aug 1, 2018
From: WESTINGHOUSE ELECTRIC COMPANY LLC; FAUSKE AND ASSOCIATES LLC
To: BANK OF MONTREAL, AS ADMINISTRATIVE AGENT
Reel/Frame 046708/0639 →