Fluoropolymers having diacrylate ends
View Patent ↗Disclosed herein is a telechelic diacrylate fluoropolymer and a process for manufacture of the fluoropolymer. The diacrylate copolymer is of formula CH 2 ═CR′COO—(CH 2 ) n —R—(CH 2 ) n —OOCCR′═CH 2 , wherein R is selected from the group consisting of i) an oligomer comprising copolymerized units of vinylidene fluoride and perfluoro(methyl vinyl ether), ii) an oligomer comprising copolymerized units of vinylidene fluoride and hexafluoropropylene, iii) an oligomer comprising copolymerized units of tetrafluoroethylene and perfluoro(methyl vinyl ether), and iv) an oligomer comprising copolymerized units of tetrafluoroethylene and a hydrocarbon olefin, R′ is H or—CH 3 , n is 1-4 and wherein said oligomer has a number average molecular weight of 1000 to 25,000 daltons.
1. A process for the manufacture of a telechelic diacrylate copolymer, said process comprising:
A) providing a diol of formula HO—(CH 2 ) n —R—(CH 2 ) n —OH, wherein n is 2 or 3 and R is an oligomer having a number average molecular weight of 1000 to 25,000 daltons, said oligomer selected from the group consisting of i) an oligomer comprising copolymerized units of vinylidene fluoride and perfluoro(methyl vinyl ether), ii) an oligomer comprising copolymerized units of vinylidene fluoride and hexafluoropropylene, iii) an oligomer comprising copolymerized units of tetrafluoroethylene and perfluoro(methyl vinyl ether), and iv) an oligomer comprising copolymerized units of tetrafluoroethylene and a hydrocarbon olefin; and
B) reacting said diol with CH 2 ═CR′COX, wherein X is a halide and R′ is H or —CH 3 , to form a diacrylate copolymer of formula CH 2 ═CR′COO—(CH 2 ) n —R—(CH 2 ) n —OOCCR′═CH 2 .
2. A process for the manufacture of a telechelic diacrylate copolymer of claim 1 wherein said oligomer has a number average molecular weight of 1200 to 12,000 daltons.
3. A process for the manufacture of a telechelic diacrylate copolymer of claim 2 wherein said oligomer has a number average molecular weight of 1500 to 5000 daltons.
4. A process for the manufacture of a telechelic diacrylate copolymer of claim 1 wherein said oligomer comprises copolymerized units selected from the group consisting of i) vinylidene fluoride, tetrafluoroethylene and perfluoro(methyl vinyl ether); ii) tetrafluoroethylene, perfluoro(methyl vinyl ether) and ethylene; iii) vinylidene fluoride, hexafluoropropylene and tetrafluoroethylene; and iv) tetrafluoroethylene, vinylidene fluoride and propylene.