Multi-layered coating providing corrosion resistance to zirconia based electrolytes
View Patent ↗A solid oxide fuel cell (SOFC) stack including a plurality of SOFCs and a plurality of interconnects. Each interconnect is located between two adjacent SOFCs, and each interconnect contains a Mn or Co containing, electrically conductive metal oxide layer on an air side of the interconnect. The SOFC stack also includes a barrier layer located between the electrically conductive metal oxide layer and an adjacent SOFC. The barrier layer is configured to prevent Mn or Co diffusion from the electrically conductive metal oxide layer to the adjacent SOFC.
1. A planar interconnect for a solid oxide fuel cell (SOFC) comprising:
a fuel inlet riser opening;
a fuel outlet riser opening;
a plurality of first flow channels on an air side of the interconnect;
a plurality of second flow channels on a fuel side of the interconnect;
an electrically conductive metal oxide layer covering the air side of the interconnect;
a barrier layer over the conductive metal oxide layer in regions adjacent to the fuel inlet riser opening and the fuel outlet riser opening;
wherein the electrically conductive metal oxide layer contains Mn or Co, and the barrier layer is configured to prevent Mn or Co diffusion from the electrically conductive metal oxide layer to an adjacent SOFC in a stack of SOFCs.
2. The planar interconnect of claim 1 , wherein the barrier layer comprises at least one of a clay, a ceramic, an alkali earth silicate or a glass ceramic.
3. The planar interconnect of claim 2 , wherein the barrier layer comprises Al 2 O 3 , ZrO 2 , ZrSiO 4 , (Ca, Ba, Mg) silicate, feldspar or combinations thereof.
4. The planar interconnect of claim 1 , wherein the barrier layer is formed as rings around the fuel inlet and fuel outlet riser openings.
5. The planar interconnect of claim 4 , wherein the barrier layer is not located on a plurality of the first flow channels.
6. The planar interconnect of claim 1 , wherein the electrically conductive metal oxide layer comprises a perovskite layer or a spinel layer.
7. The planar interconnect of claim 6 , wherein the electrically conductive metal oxide layer comprises lanthanum strontium manganate (LSM), lanthanum strontium cobaltite, lanthanum strontium manganate-cobaltite, or Mn x Co 3-x O 4 spinel, where x ranges between 1 and 2.
8. The planar interconnect of claim 2 , wherein the barrier layer comprises the clay.
9. The planar interconnect of claim 2 , wherein the barrier layer comprises the ceramic.
10. The planar interconnect of claim 2 , wherein the barrier layer comprises the alkali earth silicate.
11. The planar interconnect of claim 2 , wherein the barrier layer comprises the glass ceramic.
12. The planar interconnect of claim 2 , wherein the barrier layer comprises a combination of at least two materials selected from Al 2 O 3 , ZrO 2 , ZrSiO 4 , (Ca, Ba, Mg) silicate, and feldspar.
13. The planar interconnect of claim 2 , wherein the barrier layer comprises ZrSiO 4 .
14. The planar interconnect of claim 2 , wherein the barrier layer comprises (Ca, Ba, Mg) silicate.
15. The planar interconnect of claim 2 , wherein the barrier layer comprises feldspar.
16. The planar interconnect of claim 1 , further comprises a glass or glass ceramic seal located over the barrier layer, wherein the barrier layer is located over the conductive metal oxide layer.
17. The planar interconnect of claim 1 , further comprises a glass or glass ceramic seal located between the barrier layer and the conductive metal oxide layer.
18. The planar interconnect of claim 4 , further comprises a glass or glass ceramic ring seal located over the barrier layer which is located over the conductive metal oxide layer.
19. The planar interconnect of claim 4 , further comprises a glass or glass ceramic ring seal located between the barrier layer and the conductive metal oxide layer.