Neutral, stable and transparent photocatalytic titanium dioxide sols
View Patent ↗A method for preparing a neutral, stable and transparent photocatalytic titanium dioxide sol is provided. The method comprises (1) contacting an alkaline titanium dioxide sol with an alkaline peptizing agent to provide a peptized alkaline titanium dioxide sol; (2) neutralizing the peptized alkaline titanium dioxide sol; and (3) obtaining or collecting the neutral, stable and transparent photocatalytic titanium dioxide sol. The titanium dioxide sol is stable and transparent over a range of pH of about 7.0 to about 9.5. The titanium dioxide sol may include crystallites of titanium dioxide having an average particle size of less than about 10 nm with at least 90% of the crystallites being in the anatase form.
1. A method for preparing a neutral, stable and transparent photocatalytic titanium dioxide sol, comprising the steps of:
(1) reacting a hydrous titanium dioxide gel with an alkaline alkylamine peptizing agent to provide a peptized alkaline titanium dioxide sol; and
(2) neutralizing the peptized alkaline titanium dioxide sol with a combination of phosphoric acid and acetic acid to obtain a neutral, stable and transparent photocatalytic titanium dioxide sol comprising in the range of from about 0.5 to about 20 wt % titanium dioxide.
2. The method of claim 1 , wherein the alkaline alkylamine peptizing agent is present in the neutral, stable and transparent photocatalytic titanium dioxide sol in an amount of at least about 7 wt %, based on the combined weight of the alkaline alkylamine peptizing agent and titanium dioxide.
3. The method of claim 1 , wherein the alkaline alkylamine peptizing agent is present in the neutral, stable and transparent photocatalytic titanium dioxide sol in an amount of at least about 18 wt %, based on the combined weight of the alkaline alkylamine peptizing agent and titanium dioxide.
4. The method of claim 1 wherein the peptized alkaline alkylamine titanium dioxide sol is neutralized with a combination of phosphoric acid and acetic acid; wherein the weight ratio of the phosphoric acid to the acetic acid is in the range of from about 0.8:1 to about 1.2:1, and wherein the phosphoric acid and the acetic acid are simultaneously added to the peptized alkaline alkaline alkylamine titanium dioxide sol.
5. The method of claim 1 , wherein the alkaline alkylamine is diethyl amine.
6. The method of claim 1 , wherein the neutral, stable and transparent photocatalytic titanium dioxide sol comprises titanium dioxide crystallites having an average particle size of less than about 50 nm, at least 90% of which are in the anatase form.
7. The method of claim 1 wherein the neutral, stable and transparent photocatalytic titanium dioxide sol is doped with a metal, wherein the metal is selected from the group consisting of Ag, Zn, Mg, Sn, Fe, Co, Ni, Se, Ce, Cu and combinations thereof.
8. The method of claim 1 wherein the neutral, stable and transparent photocatalytic titanium dioxide sol is washed with demineralized water such that the concentration of calcium ions is less than about 71 ppm and the concentration of sodium ions is less than about 13 ppm in the resulting washed neutral, stable and transparent photocatalytic titanium dioxide sol, and wherein the filtrate conductivity is equal to or less than 500 μS.
9. The method of claim 8 wherein the viscosity of the washed neutral, stable and transparent photocatalytic titanium dioxide sol is less than about 100 centipoise after at least 4 weeks at room temperature.