Poly(phenylene ether) articles and compositions
View Patent ↗A composition useful for the injection molding of fluid engineering parts includes specific amounts of a high molecular weight poly(phenylene ether), a polystyrene, and glass fibers. The composition provides improved hydrostability and reduces or eliminates the butadiene monomer that is present in comparative compositions containing rubber-modified polystyrene. Fluid engineering articles prepared from the composition are described.
1. A fluid engineering article comprising a composition consisting of:
about 25 to about 50 weight percent of a poly(phenylene ether);
about 25 to about 55 weight percent of a polystyrene comprising an atactic homopolystyrene having a number average molecular weight of 30,000 to 100,000 atomic mass units;
about 5 to about 35 weight percent of glass fibers; and
optionally, up to 10 weight percent of additives selected from the group consisting of stabilizers, mold release agents, lubricants, processing aids, drip retardants, nucleating agents, UV blockers, dyes, pigments, antioxidants, anti-static agents, blowing agents, mineral oil, metal deactivators, antiblocking agents, and combinations thereof;
wherein the poly(phenylene ether) has a weight average molecular weight of at least 70,000 atomic mass units after being compounded with the polystyrene and the glass fibers;
wherein the composition comprises less than or equal to 1 milligram butadiene per kilogram of composition; and
wherein all weight percents are based on the total weight of the composition, unless a different weight basis is specified.
2. The fluid engineering article of claim 1 , selected from the group consisting of pipes, pipe liners, pipe junctions, hot and cold water device components, boiler components, central heating device components, combined hot water and central heating device components, heat exchanger components, heat pump housings, water pump housings, filter housings, water meter housings, water valves, impellers, and faucet spouts.
3. The fluid engineering article of claim 1 , wherein the poly(phenylene ether) has a weight average molecular weight of 70,000 to about 110,000 atomic mass units after being compounded with the polystyrene and the glass fibers.
4. The fluid engineering article of claim 1 , wherein the poly(phenylene ether) has a weight average molecular weight of about 60,000 to about 90,000 atomic mass units before being compounded with the polystyrene and the glass fibers.
5. The fluid engineering article of claim 1 , wherein the composition comprises less than or equal to 2 weight percent of any polymer other than the poly(phenylene ether) and the polystyrene.
6. The fluid engineering article of claim 1 ,
wherein the composition comprises about 30 to about 40 weight percent of the poly(phenylene ether);
wherein the poly(phenylene ether) comprises a poly(2,6-dimethyl-1,4-phenylene ether);
wherein the composition comprises about 47 to about 57 weight percent of the polystyrene;
wherein the composition comprises about 5 to about 15 weight percent of the glass fibers; and
wherein the composition comprises less than or equal to 0.05 milligram butadiene per kilogram of composition.
7. The fluid engineering article of claim 1 ,
wherein the composition comprises about 25 to about 35 weight percent of the poly(phenylene ether);
wherein the poly(phenylene ether) comprises a poly(2,6-dimethyl-1,4-phenylene ether);
wherein the composition comprises about 42 to about 52 weight percent of the polystyrene;
wherein the composition comprises about 15 to about 25 weight percent of the glass fibers; and
wherein the composition comprises less than or equal to 0.05 milligram butadiene per kilogram of composition.
8. The fluid engineering article of claim 1 ,
wherein the composition comprises about 32 to about 42 weight percent of the poly(phenylene ether);
wherein the poly(phenylene ether) comprises a poly(2,6-dimethyl-1,4-phenylene ether);
wherein the composition comprises about 25 to about 35 weight percent of the polystyrene;
wherein the composition comprises about 25 to about 35 weight percent of the glass fibers; and
wherein the composition comprises less than or equal to 0.05 milligram butadiene per kilogram of composition.
9. A composition consisting of:
about 25 to about 50 weight percent of a poly(phenylene ether);
about 25 to about 55 weight percent of a polystyrene comprising an atactic homopolystyrene having a number average molecular weight of 30,000 to 100,000 atomic mass units;
about 5 to about 35 weight percent of glass fibers; and
optionally, up to 10 weight percent of additives selected from the group consisting of stabilizers, mold release agents, lubricants, processing aids, drip retardants, nucleating agents, UV blockers, dyes, pigments, antioxidants, anti-static agents, blowing agents, mineral oil, metal deactivators, antiblocking agents, and combinations thereof;
wherein the poly(phenylene ether) has a weight average molecular weight of at least 70,000 atomic mass units after being compounded with the polystyrene and the glass fibers;
wherein the composition comprises less than or equal to 1 milligram butadiene per kilogram of composition; and
wherein all weight percent are based on the total weight of the composition, unless a different weight basis is specified.
10. The composition of claim 9 , wherein the poly(phenylene ether) has a weight average molecular weight of 70,000 to about 110,000 atomic mass units after being compounded with the polystyrene and the glass fibers.
11. The composition of claim 9 , wherein the poly(phenylene ether) has a weight average molecular weight of about 60,000 to about 90,000 atomic mass units before being compounded with the polystyrene and the glass fibers.
12. The composition of claim 9 , comprising less than or equal to 2 weight percent of any polymer other than the poly(phenylene ether) and the polystyrene.
13. The composition of claim 9 ,
wherein the composition comprises about 30 to about 40 weight percent of the poly(phenylene ether);
wherein the poly(phenylene ether) comprises a poly(2,6-dimethyl-1,4-phenylene ether);
wherein the composition comprises about 47 to about 57 weight percent of the polystyrene;
wherein the composition comprises about 5 to about 15 weight percent of the glass fibers; and
wherein the composition comprises less than or equal to 0.05 milligram butadiene per kilogram of composition.
14. The composition of claim 9 ,
wherein the composition comprises about 25 to about 35 weight percent of the poly(phenylene ether);
wherein the poly(phenylene ether) comprises a poly(2,6-dimethyl-1,4-phenylene ether);
wherein the composition comprises about 42 to about 52 weight percent of the polystyrene;
wherein the composition comprises about 15 to about 25 weight percent of the glass fibers; and
wherein the composition comprises less than or equal to 0.05 milligram butadiene per kilogram of composition.
15. The composition of claim 9 ,
wherein the composition comprises about 32 to about 42 weight percent of the poly(phenylene ether);
wherein the poly(phenylene ether) comprises a poly(2,6-dimethyl-1,4-phenylene ether);
wherein the composition comprises about 25 to about 35 weight percent of the polystyrene;
wherein the composition comprises about 25 to about 35 weight percent of the glass fibers; and
wherein the composition comprises less than or equal to 0.05 milligram butadiene per kilogram of composition.