COMPOSITIONS FOR ALGAE TREATMENT IN RECIRCULATING AND STAGNANT WATER SYSTEMS
The present invention provides a composition for treating recirculating or stagnant water. The composition contains a phosphorus-containing compound, which is metaphosphate compound, a polyphosphoric acid or a polyphosphate, and one or more zinc compounds. The phosphorus-containing compound is a compound which is not readily hydrolyzable to an orthophosphate. In another aspect of the present invention, provided is a method of controlling algae in a body of recirculating or stagnant water using the composition.
1 . A composition for treating recirculating or stagnant water, said composition comprising
a phosphorus-containing compound selected from the group consisting of metaphosphate compound, a polyphosphoric acid and a polyphosphate; and
one or more water soluble zinc compounds,
wherein the phosphorus-containing compound is a compound which is not readily hydrolyzable to an orthophosphate.
2 . The composition according to claim 1 , wherein the zinc compound and the phosphorus-containing compound are present in a weight ratio of zinc compound to phosphorus-containing compound in the range of 10:1 to 1:100.
3 . The composition of according to claim 2 , wherein zinc compound and the phosphorus-containing compound are present in a weight ratio of zinc compound to phosphorus-containing compound in the range of 2:1 to 1:20.
4 . The composition according to claim 3 , wherein the zinc compound and the phosphorus-containing compound are present in a weight ratio of zinc compound to phosphorus-containing compound in the range of 1:1 to 1:7.
5 . The composition according to claim 1 , wherein the phosphorous-containing compound is a metaphosphate compound.
6 . The composition according to claim 5 , wherein the metaphosphate compound is selected from the group consisting of a sodium, potassium, calcium or aluminum salts of trimetaphosphate, a hexametaphosphate, and a polyphosphate.
7 . The composition according to claim 1 , wherein the phosphorous-containing compound comprises sodium hexametaphosphate.
8 . The composition of claim 1 , wherein said zinc compound comprises zinc oxide, zinc hydroxide or a zinc salt selected from the group consisting of anhydrous zinc sulfate, zinc chloride, zinc sulfate monohydrate (ZnSO 4 .H 2 O), zinc sulfate heptahydrate (ZnSO 4 .7H 2 O), zinc carbonate (ZnCO 3 ), zinc nitrate (Zn(NO 3 ) 2 ), zinc borate, zinc phosphate, and combinations thereof.
9 . The composition according to claim 8 , wherein the phosphorus-containing compound comprises sodium hexametaphosphate.
10 . The composition according to claim 9 , wherein the zinc compound and sodium hexametaphosphate are present in a weight ratio of zinc compound to sodium hexametaphosphate compound is in the range of 1:1 to 1:7.
11 . The composition according to claim 10 , wherein the zinc compound comprises zinc sulfate monohydrate.
12 . The composition according claim 1 , wherein said zinc compound is in liquid or solution form and comprises from 0.1 up to 10 percent by weight, based on the total weight of said composition and the phosphorus-containing compound is in liquid or solution form and comprises from 0.1 up to 40 percent by weight, based on the total weight of the composition.
13 . The composition according claim 1 , further comprising one or more additional ingredients selected from the group consisting of chlorite and hypochlorite salts, chlorinated isocyanurates, chloroisocyanuric acid, polybiguanides, persalts, halide salts, halogenated hydantoins and combinations thereof.
14 . The composition according claim 1 , further comprising one or more additional ingredients selected from the group consisting of clarifiers organic and inorganic, enzymes, stabilizers cyanuric acid, borates, water softeners, dyes, pigments, organic or inorganic algaecides, water balance components, scale inhibitors, corrosion inhibitors, oxidizers, and combinations thereof.
15 . A method of controlling algae in a body of recirculating or stagnant water, comprising the steps of:
a) providing a body of recirculating or stagnant water containing algae; and
b) adding to said body of recirculating or stagnant water an effective amount of a composition comprising a phosphorus-containing compound selected from the group consisting of metaphosphate compound, a polyphosphoric acid and a polyphosphate, and one or more water soluble zinc compounds,
wherein the phosphorus-containing compound is a compound which is not readily hydrolyzable to an orthophosphate.
16 . The method according to claim 15 , wherein said zinc compound is selected from the group consisting zinc oxide, zinc hydroxide or a zinc salt selected from the group consisting of anhydrous zinc sulfate, zinc chloride, zinc sulfate monohydrate (ZnSO 4 .H 2 O), zinc sulfate heptahydrate (ZnSO 4 .7H 2 O), zinc carbonate (ZnCO 3 ), zinc nitrate (Zn(NO 3 ) 2 ), zinc borate, zinc phosphate, and combinations thereof.
17 . The method according claim 16 , wherein said adding said composition comprises adding the composition in an amount to the water that results in a final concentration of zinc ion in said water of between 0.5 and 10 ppm, and a final concentration of phosphorus-containing compound in said water of between 1 and 50 ppm.
18 . The method according to claim 17 , wherein the composition in an amount to the water that results in a final concentration of zinc ion in said water of between 1.0 and 5 ppm, and a final concentration of phosphorus-containing compound in said water of between 2 and 25 ppm.
19 . The method according to claim 18 , wherein the composition in an amount to the water that results in a final concentration of zinc ion in said water of between 2.0 and 4.0 ppm, and a final concentration of phosphorus-containing compound in said water of between 5 and 10 ppm.
20 . The method according to claim 19 , wherein the phosphorus-containing compound comprises sodium hexametaphosphate and the zinc compound comprises zinc sulfate monohydrate.