Deposition chamber cleaning system and method

1. A method of cleaning a deposition chamber comprising:

pulsing a reactive gas comprising a hydrogen halide into a deposition chamber containing a metal chalcogenide formed on a deposition chamber surface to form a purgable material; and

purging the purgable material from the deposition chamber.

2. The method of claim 1 , wherein the purgable material includes a vapor or a particulate.

3. The method of claim 1 , wherein the hydrogen halide comprises hydrogen chloride.

4. The method of claim 1 , wherein purging the purgable material from the deposition chamber comprises pulsing an inert gas into the deposition chamber to flush the purgable material out of the chamber.

5. The method of claim 2 , further comprising heating the deposition chamber to maintain the purgable vapor material as a vapor.

6. The method of claim 1 , further comprising introducing a chemically reactive plasma into the deposition chamber to react with metal chalcogenide.

7. The method of claim 1 , further comprising pulsing a second reactive gas into the deposition chamber after pulsing the reactive gas into the deposition chamber.

8. The method of claim 7 , wherein the second reactive gas comprises an acid, oxygen, fluorine, or tetrafluoromethane.

9. The method of claim 4 , wherein the inert gas comprises helium or nitrogen.

10. A method of manufacturing a semiconductor device, comprising:

transporting a substrate into a deposition chamber;

forming a buffer layer adjacent to the substrate, wherein forming the buffer layer comprises pulsing at least one metal precursor and pulsing at least one chalcogen precursor into the chamber;

transporting the substrate with the deposited buffer layer out of the chamber; and

pulsing a reactive gas comprising a hydrogen halide into the deposition chamber to react with a metal chalcogenide formed on a deposition chamber surface to form a purgable material; and

purging the purgable material from the deposition chamber.

11. The method of claim 10 , wherein the purgable material comprises a vapor or a particulate.

12. The method of claim 10 , wherein the hydrogen halide comprises hydrogen chloride.

13. The method of claim 10 , wherein purging the purgable material from the deposition chamber comprises pulsing an inert gas into the deposition chamber to flush the purgable material out of the chamber.

14. The method of claim 11 , further comprising heating the deposition chamber to maintain the purgable vapor material as a vapor.

15. The method of claim 10 , further comprising pulsing a second reactive gas into the deposition chamber after pulsing the reactive gas, wherein the second reactive gas comprises a material selected from the group consisting of an acid, oxygen, fluorine, and tetrafluoromethane.

16. The method of claim 10 , wherein the inert gas comprises a material selected from the group consisting of helium and nitrogen.

17. The method of claim 10 , further comprising heating the substrate before pulsing a precursor.

18. The method of claim 10 , further comprising forming a chemically reactive plasma in the deposition chamber to react with the metal chalcogenide.

19. The method of claim 10 , wherein the semiconductor device comprises a photovoltaic device.