Miktopolymer compositions
View Patent ↗The present invention provides a block copolymer composition and method of making the same having the structures (A 2 -B) n -X-(A 1 ) or (A 2 -B 2 ) n -X-(B 1 A 1 ), where A 1 and A 2 are each a polymer block of a monoalkenyl arene and B, B 1 , and B 2 are each a polymer block of one or more conjugated dienes or a hydrogenated diene polymer, n is an integer from 2 to 30 and X is the residue of a coupling agent.
1. An elastomeric polymer composition comprising miktopolymers of the structure (A 2 -B 2 ) n -X-(B 1 -A 1 ), where
a. A 1 and A 2 are each a polymer block of a monoalkenyl arene and B 1 and B 2 are polymer blocks of one or more conjugated dienes or hydrogenated polymer blocks of one or more conjugated dienes;
b. n is an integer from 2 to 30; and
c. X is the residue of a coupling agent;
and wherein:
i. τ is an asymmetry parameter of monoalkenyl arene associated with the A 1 and A 2 blocks according to the formula τ=NA 1 /(NA 1 +NA 2 ) where NA 1 is the number of monomer units in the A 1 monoalkenyl arene block and NA 2 is the number of monomer units in an A 2 monoalkenyl arene block;
ii. f is the volume fraction of monoalkenyl arene in said miktopolymer;
iii. τ has a value of 0.7 to 0.95;
iv. f has a value greater than or equal to 0.5;
v. block A 1 has a peak molecular weight of between 10,000 and 300,000, and the ratio of the peak molecular weight of A 1 to A 2 is greater than or equal to 2; and
vi. B 2 has a peak molecular weight of between 20,000 and 150,000 and B 1 has a peak molecular weight of between 200 and 5,000.
2. The composition according to claim 1 , wherein said mono alkenyl arene for the A l and A 2 blocks is styrene and said conjugated diene for the B 2 block is selected from the group consisting of isoprene, 1,3-butadiene and mixtures thereof and the conjugated diene for the B 1 block is 1,3-butadiene.
3. The composition according to claim 2 wherein at least 90% of the unsaturated bonds in the B 1 and B 2 blocks of the polymer are hydrogenated and the conjugated diene for the B 2 block is 1,3-butadiene and wherein about 20 to about 80 mol percent of the condensed butadiene units in the B 1 and B 2 blocks have 1,2-configuration.
4. The composition according to claim 2 wherein the monoalkenyl arene content ranges from about 40 to about 75 weight percent for the total block copolymer.
5. The composition according to claim 4 wherein said block A l has a peak molecular weight of between 10,000 and 300,0006, said A 2 block has a peak molecular weight of between 5,000 and 30,000, said block B 2 has a peak molecular weight of between 20,000 and 100,000 and said block B 1 has a peak molecular weight of between 200 and 3,000.
6. The composition according to claim 1 , wherein n is an integer from 4 to 10.
7. A composition according to claim 1 , wherein the composition is catalytically hydrogenated and at least about 90 percent of the conjugated diene double bonds have been reduced and between 0 to about 10 percent of the arene double bonds have been reduced.