Additive to improve flow, reduce power consumption and pressure drop in heavy oil pipelines
View Patent ↗A drag reducing additive for heavy oil, such as crude oil, includes a polymeric alkyl-substituted phenol formaldehyde resin and a solvent having at least one of an ester (e.g. ethyl acetate), an aldehyde (e.g. butyraldehyde), and an aromatic hydrocarbon (e.g. toluene, xylene, and the like), or mixtures thereof. When used together with a diluent (e.g. condensate, naphtha, or the like), the additive may reduce viscosity of the combined oil, diluent, and additive by at least 20%, increase throughput by at least 6%, reduce power consumption by at least 3%, reduce the diluent proportion by at least 3%, or some combination of these effects, as compared with an otherwise identical heavy oil without the additive.
1. A drag reducing additive comprising:
a polymeric alkyl-substituted phenol formaldehyde resin; and
a solvent selected from the group consisting of an aldehyde, and an aldehyde together with an ester.
2. The drag reducing additive of claim 1 where the amount of polymeric alkyl-substituted phenol formaldehyde resin in the additive ranges from about 1 to about 20 wt %.
3. The drag reducing additive of claim 1 where the alkyl group of the polymeric alkyl-substituted phenol formaldehyde resin is a linear or branched alkyl group having from 2 to 20 carbon atoms, and where the polymeric alkyl-substituted phenol formaldehyde resin has a weight average molecular weight ranging from about 1,500 to about 30,000.
4. The drag reducing additive of claim 1 where the additive has a component selected from the group consisting of the following with the indicated proportions, based on the solvent in the total additive:
from about 10 to about 95 wt % ester; and
from about 10 to about 95 wt % aldehyde.
5. The drag reducing additive of claim 1 where:
the ester is selected from the group consisting of ethyl formate, methyl formate, methyl acetate, ethyl acetate, ethyl propionate, dimethyl carbonate, diethyl carbonate, ethyl lactate, and combinations thereof; and
the aldehyde is selected from the group consisting of formaldehyde, acetaldehyde, propionaldehyde, butyraldehyde, benzaldehyde, and combinations thereof.
6. A drag reducing additive comprising:
from about 1 to about 20 wt % of a polymeric alkyl-substituted phenol formaldehyde resin having a weight average molecular weight ranging from about 1,500 to about 30,000, where the alkyl group of the polymeric alkyl-substituted phenol formaldehyde resin is a linear or branched alkyl group having from 2 to 20 carbon atoms; and
a solvent selected from the group consisting of an aldehyde, and an aldehyde together with an ester.
7. The drag reducing additive of claim 6 where the additive has a component selected from the group consisting of the following with the indicated proportions, based on the solvent in the total additive:
from about 10 to about 95 wt % ester; and
from about 10 to about 95 wt % aldehyde.
8. The drag reducing additive of claim 6 where:
the ester is selected from the group consisting of ethyl formate, methyl formate, methyl acetate, ethyl acetate, ethyl propionate, dimethyl carbonate, diethyl carbonate, ethyl lactate, and combinations thereof; and
the aldehyde is selected from the group consisting of formaldehyde, acetaldehyde, propionaldehyde, butyraldehyde, benzaldehyde, and combinations thereof.
9. A drag reducing additive comprising:
a polymeric alkyl-substituted phenol formaldehyde resin; and
a solvent selected from the group consisting of an aldehyde and an aldehyde together with an ester:
where the ester is selected from the group consisting of ethyl formate, methyl formate, methyl acetate, ethyl acetate, ethyl propionate, dimethyl carbonate, diethyl carbonate, ethyl lactate, and combinations thereof,
where the aldehyde is selected from the group consisting of formaldehyde, acetaldehyde, propionaldehyde, butyraldehyde, benzaldehyde, and combinations thereof;
where the additive has a component selected from the group consisting of the following with the indicated proportions, based on the solvent in the total additive:
from about 10 to about 95 wt % ester; and
from about 10 to about 95 wt % aldehyde.
10. The drag reducing additive of claim 9 where the amount of polymeric alkyl-substituted phenol formaldehyde resin in the additive ranges from about 1 to about 20 wt %.
11. The drag reducing additive of claim 9 where the alkyl group of the polymeric alkyl-substituted phenol formaldehyde resin is a linear or branched alkyl group having from 2 to 20 carbon atoms, and where the polymeric alkyl-substituted phenol formaldehyde resin has a weight average molecular weight ranging from about 1,500 to about 30,000.