PTC Device and Secondary Battery Equipped with Same
The present invention provides a PTC device which makes more compact a PTC device as well as an electrical device such as a battery pack comprising the PTC device and a secondary battery or a dry-cell type secondary battery. The PTC device includes a PTC component including a laminar polymer PTC element containing an electrically conductive filler, and a polymer material, and a metal electrode disposed on a surface of each side of the polymer PTC element. A lead is positioned at least in part on the metal electrode of the PTC component, and connected to the metal electrode by an electrically conductive material. An exposed part of the conductive material is covered by a protective member containing a material that is able to absorb or envelop an alkali.
1 . A PTC device which comprises:
(1) a PTC component comprising:
(A) a laminar polymer PTC element containing
(a) an electrically conductive filler, and
(b) a polymer material, and
(B) a metal electrode disposed on a surface of each side of the polymer PTC element; and
(2) a lead positioned at least in part on the metal electrode of the PTC component, and connected to the metal electrode by an electrically conductive material;
characterized by an exposed part of said conductive material being covered by a protective member containing a material that is able to absorb or envelop an alkali.
2 . The PTC device according to claim 1 , wherein the electrically conductive material contains tin.
3 . The PTC device according to claim 1 , wherein the material that is able to absorb or envelop the alkali is a crown ether.
4 . The PTC device according to claim 1 , wherein the protective member is in the form of a molded member enclosing the PTC component and the lead, while an end portion of the lead protrudes outwardly from the molded member.
5 . The PTC device according to claim 1 , wherein the protective member is in the form of a film enclosing the PTC component and the lead, while an end portion of the lead protrudes outwardly from the molded member.
6 . A secondary battery which comprises a positive electrode, a negative electrode, and a separator and an electrolyte disposed therebetween, characterized by a PTC device being disposed between the positive electrode and a terminal of the positive electrode, said PTC device comprising
(1) a PTC component comprising:
(A) a laminar polymer PTC element containing
(a) an electrically conductive filler, and
(b) a polymer material, and
(B) a metal electrode disposed on a surface of each side of the polymer PTC element; and
(2) a lead positioned at least in part on the metal electrode of the PTC component, and connected to the metal electrode by an electrically conductive material, an exposed part of said conductive material being covered by a protective member containing a material that is able to absorb or envelop an alkali.
7 . The secondary battery according to claim 6 , which is a dry-cell type, wherein the PTC device is disposed within a positive electrode tab space.
8 . The secondary battery according to claim 6 , which is in the form of a battery pack, wherein the PTC device, together with a protection circuit, is disposed outside of the battery.
9 . The PTC device according to claim 2 , wherein the material that is able to absorb or envelop the alkali is a crown ether.
10 . The PTC device according to claim 2 , wherein the protective member is in the form of a molded member enclosing the PTC component and the lead, while an end portion of the lead protrudes outwardly from the molded member.
11 . The PTC device according to claim 3 , wherein the protective member is in the form of a molded member enclosing the PTC component and the lead, while an end portion of the lead protrudes outwardly from the molded member.
12 . The PTC device according to claim 2 , wherein the protective member is in the form of a film enclosing the PTC component and the lead, while an end portion of the lead protrudes outwardly from the molded member.
13 . The PTC device according to claim 3 , wherein the protective member is in the form of a film enclosing the PTC component and the lead, while an end portion of the lead protrudes outwardly from the molded member.
14 . The secondary battery according to claim 6 , wherein the electrically conductive material contains tin.
15 . The secondary battery according to claim 6 , wherein the material that is able to absorb or envelop the alkali is a crown ether.
16 . The secondary battery according to claim 6 , wherein the protective member is in the form of a molded member enclosing the PTC component and the lead, while an end portion of the lead protrudes outwardly from the molded member.
17 . The secondary battery according to claim 6 , wherein the protective member is in the form of a film enclosing the PTC component and the lead, while an end portion of the lead protrudes outwardly from the molded member.