High flowability long chain branched polypropylene
View Patent ↗The present invention relates to a polypropylene composition showing a high melt flow rate and high melt strength while maintaining high impact strength. The composition of the present invention is obtainable by using a low molecular weight linear isotactic polypropylene as melt flow enhancer for a high molecular weight polypropylene having a high melt strength and impact strength. The inventive composition could be used for the production of different articles.
1. A polypropylene composition comprising
(A) 70 to 95 wt %, based on the total weight of the polypropylene composition, of a high molecular weight polypropylene component having a strain hardening factor in a range of 3.5 to 15 when measured at a strain rate of 3.0 s −1 and a Hencky strain of 2.5, and
(B) 5 wt % to 30 wt %, based on the total weight of the polypropylene composition, of a low molecular weight linear isotactic polypropylene component having a MFR 2 in a range of 500 to 5000 g/10 min measured according to ISO 1133 (230° C., 2.16 kg load).
2. The polypropylene composition according to claim 1 wherein the polypropylene composition has a MFR 2 of 5.0 to 30 g/10 min measured according to ISO 1133 (230° C., 2.16 kg load).
3. The polypropylene composition according to claim 1 , wherein the high molecular weight polypropylene component (A) has an MFR 2 of 0.5 to 5.0 g/10 min measured according to ISO 1133 (230° C., 2.16 kg load).
4. The polypropylene composition according to claim 1 , wherein the high molecular component (A) has a LAOS non-linearity factor (LAOS-NLF) in a range of 4.0 to 10.
5. The polypropylene composition according to claim 1 , wherein the high molecular component (A) has a F30 melt strength as determined in the Rheotens test at 200° C. in a range of 6.0 to 30 cN.
6. The polypropylene composition according to claim 1 , wherein the high molecular weight polypropylene component is a homopolymer component.
7. The polypropylene composition according to claim 1 , wherein the polypropylene composition has a Charpy notched impact strength of 3.5 to 10 kJ/m 2 at 23° C. measured on an injection molded specimen according to ISO 179:2000 1eA.
8. The polypropylene composition according to claim 1 , wherein the polypropylene composition has a tensile modulus in a range of 1600 to 4000 MPa measured on an injection molded specimen according to ISO 572-2.
9. The polypropylene composition according to claim 1 , wherein the polypropylene composition has a crystallization temperature in a range of 120 to 145° C.
10. The polypropylene composition according to claim 1 , wherein the polypropylene composition has a strain hardening factor (SHF) of 2.0 to 9.0 when measured at a strain rate of 3.0 s −1 and a Hencky strain of 2.5.
11. The polypropylene composition according to claim 1 , wherein the polypropylene composition has a LAOS non-linearity factor (LAOS-NLF) in a range of 2.5 to 8.0.
12. The polypropylene composition according to claim 1 , wherein the polypropylene composition has F30 melt strength as determined in the Rheotens test at 200° C. in a range of 4.0 to 30 cN.
13. An article made of the polypropylene composition according to claim 1 .
14. A method for producing a polypropylene composition according to claim 1 comprising mixing a low molecular weight linear isotactic polypropylene with a high molecular weight polypropylene,
wherein the low molecular weight linear isotactic polypropylene has a MFR 2 in a range of 500 to 5000 g/10 min measured according to ISO 1133 (230° C., 2.16 kg load) and the high molecular weight polypropylene has a strain hardening factor in a range of 3.5 to 15 when measured at a strain rate of 3.0 s −1 and a Hencky strain of 2.5;
and wherein the polypropylene composition comprises from 70 to 95 wt % of the high molecular weight polypropylene, and from 5 wt % to 30 wt % of the low molecular weight linear isotactic polypropylene, based on the total weight of the polypropylene composition.