IP Library Granted Patent US 9,329,503
Granted Patent B2
US 9,329,503 · App. 13/698,171 · Granted May 3, 2016

Multilayer mirror

Inventors: Vadim Iourievich Timoshkov (Veldhoven, NL); Jan Bernard Plechelmus van Schoot (Eindhoven, NL); Antonius Theodorus Wilhelmus Kempen ('s-Hertogenbosch, NL); Andrei Mikhailovich Yakunin (Eindhoven, NL); Edgar Alberto Osorio Oliveros (Eindhoven, NL)
Assignee: ASML Netherlands B.V.
G03F7/70958B82Y10/00C23C14/48C23C14/586G21K1/062
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Quick Facts
Patent No.
US 9,329,503
App. No.
13/698,171
Granted
May 3, 2016
Kind
B2
Abstract

There is provided a multilayer mirror ( 80 ) comprising a layer of a first material ( 84 ) and a layer of silicon ( 82 ). The layer of the first material and the layer of silicon form a stack of layers. An exposed region of the layer of silicon comprises a modification that is arranged to improve the robustness of the exposed region of silicon.

Claims (48)

1. A multilayer mirror comprising:

a layer of a first material;

a layer of silicon;

the layer of the first material and the layer of silicon forming a stack of layers;

wherein only an exposed region of the layer of silicon comprises a modification that is arranged to improve robustness of the exposed region of the layer of the silicon.

2. The multilayer mirror of claim 1 , wherein the modification is arranged to improve the robustness of the exposed region of the layer of the silicon by at least one of:

reducing a reactivity of the exposed region of the layer of silicon with hydrogen or atomic hydrogen; and

improving a sputtering resistance of the exposed region of the layer of silicon.

3. The multilayer mirror of claim 2 , wherein the reactivity of the exposed region of the layer of silicon with hydrogen or atomic hydrogen is reduced by at least one of:

one or more implanted materials provided on a surface of the exposed region of the layer of silicon, or within the exposed region of the layer of silicon; and

a passivation layer covering, or forming part of, the exposed region of the layer of silicon.

4. The multilayer mirror of claim 2 , wherein the sputtering resistance of the exposed region of the layer of silicon is improved by at least one of:

one or more implanted materials provided on a surface of the exposed region of the layer of silicon, or within the exposed region of the layer of silicon; and

a passivation layer covering, or forming part of, the exposed region of the layer of silicon.

5. The multilayer mirror of claim 1 , wherein the modification comprises at least one of:

one or more implanted materials comprising at least one of boron, nitrogen and nitride, provided on a surface of the exposed region of the layer of silicon, or within the exposed region of the layer of silicon; and

a passivation layer covering, or forming part of the exposed region of the layer of silicon.

6. The multilayer mirror of claim 5 , wherein the passivation layer comprises one or more of a nitride layer, a silicon nitride layer, a boron glass layer, or a silicon oxynitride layer.

7. The multilayer mirror of claim 1 , wherein the exposed region of the layer of silicon is a peripheral region of the layer of silicon or a sidewall of the layer of silicon.

8. The multilayer mirror of claim 1 , wherein:

the multilayer mirror comprises at least one of a plurality of layers of the first material and a plurality of layers of silicon, such that:

the plurality of layers of silicon are separated by a layer of the first material, or

the plurality of layers of the first material are separated by a layer of silicon.

9. The multilayer mirror of claim 1 , wherein a plurality of exposed regions of the layer or layers of silicon comprises the modification.

10. The multilayer mirror of claim 1 , wherein a majority or substantially all of the exposed region or regions of the layer or layers of silicon comprise the modification.

11. A lithographic apparatus comprising:

an illumination system configured to generated a beam of radiation;

a patterning device configured to modulate the beam;

a projection system configured to direct the modulated beam onto a target portion of a substrate; and

multilayer mirror within one of the illumination or projection system, the multilayer mirror comprising:

a layer of a first material;

a layer of silicon;

the layer of the first material and the layer of silicon forming a stack of layers;

wherein only an exposed region of the layer of silicon comprises a modification that is arranged to improve robustness of the exposed region of the layer of the silicon.

12. A method comprising:

forming a stack of layers including a layer of a first material and a layer of silicon; and

modifying only an exposed region of the layer of silicon to improve robustness of the exposed region of silicon.

13. The method of claim 12 , wherein the modifying comprises:

reducing a reactivity of the exposed region of the layer of silicon with hydrogen or atomic hydrogen; or improving a sputtering resistance of the exposed region of the layer of silicon.

14. The method of claim 13 , wherein the reactivity of the exposed region of the layer of silicon with hydrogen or atomic hydrogen is reduced by at least one of:

implanting one or more material on a surface of the exposed region of the layer of silicon, or within the exposed region of the layer of silicon; and

providing a passivation layer that covers, or forms part of, the exposed region of the layer of silicon.

15. The multilayer mirror of claim 13 , wherein the sputtering resistance of the exposed region of the layer of silicon is improved by at least one of:

implanting one or more material on a surface of the exposed region of the layer of silicon, or within the exposed region of the layer of silicon; and

providing a passivation layer that covers, or forms part of, the exposed region of the layer of silicon.

16. The method of claim 12 , wherein modifying comprises at least one of:

implanting one or more material on a surface of the exposed region of the layer of silicon, or within the exposed region of the layer of silicon; and

providing a passivation layer that covers, or forms part of, the exposed region of the layer of silicon.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 15, 2012
From: TIMOSHKOV, VADIM IOURIEVICH; VAN SCHOOT, JAN BERNARD PLECHELMUS; KEMPEN, ANTONIUS THEODORUS WILHELMUS; YAKUNIN, ANDREI MIKHAILOVICH; OSORIO OLIVEROS, EDGAR ALBERTO
To: ASML NETHERLANDS B.V.
Reel/Frame 029305/0494 →
Continuity (2)
Provisional Application 61348999 · May 27, 2010
Related Publication 20130057840A1 · Mar 7, 2013