Low viscosity functional fluids
View Patent ↗Low viscosity functional fluids are described which comprises methoxy polyethylene glycol. The fluids are particularly well-suited for use as DOT 4 brake fluids and provide high ERBP, WERBP, low kinematic viscosity and low SBR volume % increase.
1. A functional fluid composition comprising
(i) an alkoxy glycol mixture in an amount of 38% to 47% by weight of the functional fluid composition, where the alkoxy glycol mixture is comprised alkoxy glycols having the formula:
wherein each of R1, R2, R3, R4, R5 is either hydrogen (H) or an alkyl group containing 1 to 8 or more carbon atoms or mixtures thereof, wherein said mixture has a first alkoxy glycol component in an amount of 36% to 73% by weight of said alkoxy glycol mixture where n=3, a second alkoxy glycol component from 17% to 43% by weight of said alkoxy glycol mixture where n=4, and a third alkoxy glycol component in an amount from 2% to 10% by weight of said alkoxy glycol mixture where n is greater than or equal to 5 and
(ii) a glycol borate ester in an amount of 53% to 62% by weight of the functional fluid composition.
2. The functional fluid composition of claim 1 , wherein the first alkoxy glycol component is methoxy triethylene glycol.
3. The functional fluid composition of claim 2 , wherein the second alkoxy glycol component is methoxy tetra ethylene glycol.
4. The functional fluid composition of claim 3 , wherein the third alkoxy glycol component is a methoxy polyethylene glycol.
5. A functional fluid composition of claim 4 , further comprising greater than 0 to 3 weight % of one or more corrosion inhibitors.
6. A functional fluid composition of claim 1 , wherein one or more corrosion inhibitors are selected from heterocyclic nitrogen-containing compounds, amine compounds including alkanol amines, alkenyl succinic anhydrides, inorganic nitrates, inorganic borates and silicate esters.
7. A functional fluid composition of claim 1 , further comprising greater than 0 to 1 weight % of one or more anti-oxidants.
8. A functional fluid composition of claim 7 , wherein one or more anti-oxidants are phenolic compounds, quinoline compounds or mixtures thereof.
9. A functional fluid composition in accordance with claim 1 , further comprising an antifoaming agent, pH stabilizer, chelating agent or mixture thereof.
10. A functional fluid composition in accordance with claim 1 , wherein the glycol borate ester is methoxy triethylene glycol borate ester.
11. A functional fluid composition in accordance with claim 10 , wherein the boron content of methoxy triethylene glycol borate ester is 2%.
12. A functional fluid composition in accordance with claim 1 , further comprising methoxy diethylene glycol.
13. A functional fluid composition in accordance with claim 1 , wherein the fluid composition has an equilibrium reflux boiling point of at least 230° C.
14. A functional fluid composition in accordance with claim 1 , wherein the fluid composition has a wet equilibrium reflux boiling point of at least 155° C.
15. A functional fluid composition in accordance with claim 1 , wherein the fluid composition has a kinematic viscosity of not more than 1800 cST at −40° C.
16. A functional fluid composition in accordance with claim 1 , wherein the fluid composition exhibits SBR Cup volume increase of not more than 10 percent tested for 70 hours at 120° C.
17. The functional fluid composition of claim 1 , wherein the glycol borate ester is an alkoxy glycol borate ester.
18. A functional fluid composition comprising
(i) an alkoxy glycol mixture in an amount of 38% to 47% by weight of the functional fluid composition, where the alkoxy glycol mixture is comprised of alkoxy glycols having the formula:
wherein each of R1, R2, R3, R4, R5 is either hydrogen (H) or an alkyl group containing 1 to 8 or more carbon atoms or mixtures thereof, wherein the alkoxy glycol mixture includes from 36% to 73% by weight of methoxy triethylene glycol based on the total weight of the alkoxy glycol mixture; from 17% to 43% methoxy tetra ethylene glycol, based on the total weight of the alkoxy glycol mixture; and from 2% to 10% methoxy polyethylene glycol, based on the total weight of the alkoxy glycol mixture, wherein the methoxy polyethylene glycol has n that is greater than or equal to 5;
(ii) a glycol borate ester in an amount of 53% to 62% by weight of the functional fluid composition;
(iii) greater than 0 to 3 weight % of one or more corrosion inhibitors, based on the total weight of the functional fluid composition; and
(iv) greater than 0 to 1 weight % of one or more antioxidants, based on the total weight of the functional fluid composition;
wherein the fluid composition has an equilibrium reflux boiling point of at least 230° C., a wet equilibrium reflux boiling point of at least 155° C., and a kinematic viscosity of not more than 1800 cST at −40° C.
19. The functional fluid composition of claim 18 , wherein the glycol borate ester is an alkoxy glycol borate ester.