Blown and stripped plant-based oils
View Patent ↗A method for producing a high viscosity, low volatiles blown stripped plant-based oil is provided. The method may include the steps of: (i) obtaining a plant-based oil; (ii) heating the oil to at least 90° C.; (iii) passing air through the heated oil to produce a blown oil having a viscosity of at least 50 cSt at 40° C.; (iv) stripping the blown oil from step (iii) to reduce an acid value of the blown oil to from 5 mg KOH/g to about 9 mg KOH/g; (v) adding a polyol to the stripped oil from (iv); and (vi) stripping the oil from step (v) to reduce the acid value of the oil to less than 5.0 mg KOH/g or less.
1. A method for producing a high viscosity, low volatiles blown stripped plant-based oil, the method comprising the steps of:
(a) obtaining a plant-based oil;
(b) heating the oil to at least 90° C.;
(c) passing air through the heated oil to produce a blown oil having a viscosity of at least 50 cSt at 40° C.;
(d) stripping the blown oil from step (c) to reduce an acid value of the blown oil to from 5 mg KOH/g to about 9 mg KOH/g; and
(e) adding a polyol to the stripped oil from (d); and
(f) stripping the oil from step (e) to reduce the acid value of the oil to less than 5.0 mg KOH/g or less.
2. The method of claim 1 wherein the oil resulting from step (f) exhibits a viscosity at 40° C. of at least 150 cSt.
3. The method of claim 1 , wherein the oil resulting from step (f) exhibits: a viscosity at 40° C. of at least 500 cSt; an acid value of 4 mg KOH/gram or less; a hydroxyl number of less than 50 mg KOH/gram; and a flash point of at least 293° C., in particular aspects, a flash point of at least 296° C.
4. The method of claim 1 wherein a catalyst comprising a peroxide or a metal selected from the groups consisting of Transition Elements and Group IV is added to the oil prior to or during step (c).
5. The method of claim 1 wherein a catalyst is added to the oil prior to or during step (c), the catalyst comprising a metal selected from the group consisting of: tin, cobalt, iron, zirconium, titanium, and combinations thereof.
6. The method of claim 1 wherein the polyol added comprises glycerin, and sufficient glycerin is added to obtain a molar ratio of added hydroxyl group to fatty acid groups present in the oil resulting from step (d) is from about 1:5 to less than about 1:1, in particular aspects, from about 2:5 to about 8:10.
7. The method of claim 1 wherein the plant-based oil of step (a) is selected from the group consisting of: soybean oil, sunflower oil, safflower oil, canola oil, rapeseed oil, cottonseed oil, corn oil, corn stillage oil and mixtures thereof.
8. The method of claim 1 wherein the plant-based oil of step (a) comprises corn stillage oil having an initial acid value from about 12 to about 34 mg KOH/gram, preferably from about 16 to about 32 mg KOH/gram.
9. A method for producing a high viscosity, low volatiles blown, stripped, corn stillage oil, the method comprising the steps of:
(a) obtaining a corn stillage oil having an initial acid value of from about 12 mg KOH/gram to about 34 mg KOH/gram;
(b) heating the oil to at least 90° C.;
(c) passing air through the heated to produce a blown-corn stillage oil;
(d) stripping the blown-corn stillage oil to reduce the acid value of the blown-corn stillage oil from about 6 mg KOH/gram to about 9 mg KOH/gram;
(e) adding a sufficient amount of glycerin to the stripped oil from (d) to obtain a molar ratio of hydroxyl groups from the added glycerin to the free fatty acids present in the oil from (d) of from about 1:5 to less than 1:1; and
(f) stripping the oil from step (e) to produce a blown, stripped corn stillage oil having a hydroxyl number less than about 50 mg KOH/gram and a final acid value of 3.5 mg KOH/gram or less.
10. The method of claim 9 , wherein sufficient glycerin is added to obtain a molar ratio of hydroxyl groups from the added glycerin to the free fatty acids present in the oil from (d) of from about 1:4 to about 9:10.
11. The method of claim 9 , wherein sufficient glycerin is added to obtain a molar ratio of hydroxyl groups from the added glycerin to the free fatty acids present in the oil from (d) of from about 2:5 to about 4:5.
12. The method of claim 9 wherein the oil resulting from step (f) has a flash point of at least 293° C.
13. The method of claim 9 wherein, the oil resulting from step (f) has a flash point of at least 296° C. and exhibits a viscosity of at least 680 cSt at 40° C.
14. The method of claim 9 wherein the oil from step (f) has a flash point of at least 310° C.
15. A method for producing a high viscosity blown, stripped plant-based oil, the method comprising the steps of:
(a) obtaining a plant-based oil;
(b) heating the oil to at least 105° C.;
(c) passing air through the heated oil to produce a blown plant-based oil having a viscosity of at least 50 cSt at 40° C.;
(d) adding a polyol to blown plant-based oil from step (c); and
(e) stripping the blown oil from step (d) to reduce an acid value of the blown oil to less than 5.0 mg KOH/gram.
16. The method of claim 15 , wherein the plant-based oil comprises a corn stillage oil and the blown oil resulting from step (c) has a viscosity of at least 1500 cSt at 40° C.
17. The method of claim 15 wherein the polyol exhibits a boiling point of at least 250° C. and has a hydroxyl number of at least 200 mg KOH/gram.
18. The method of claim 15 wherein the polyol exhibits a boiling point of at least 270° C. and is selected from the group consisting of polyglycerol, trimethylol propane, glycerin, polyethylene glycol, pentaerythritol, and mixtures thereof.
19. The method of claim 15 wherein the polyol comprises glycerin.
20. The method of claim 15 wherein sufficient polyol is added to obtain a molar ratio of hydroxyl groups added to free fatty acid groups of from about 1:1 to about 2:1.
21. The method of claim 15 , wherein the blown plant-based oil has a viscosity of at least 200 cSt at 40° C.