Method of manufacturing an electrochromic article

1. A process for manufacturing an electrochromic article comprising the following successive steps:

(a) the deposition of a layer of an electrochromic compound on the surface of a transparent or translucent electrically conductive substrate, said layer of electrochromic compound covering only one portion of the surface of said electrically conductive substrate and leaving free at least one other portion thereof,

(b) the deposition of a layer comprising a redox agent which is a reducing agent or an oxidizing agent for the electrochromic compound, on the portion of the surface of the electrically conductive substrate not covered by the layer of electrochromic compound,

(c) the contacting of the layer of electrochromic compound, deposited in step (a), and of the layer of redox agent, deposited in step (b), with a liquid electrolyte for a sufficient time to enable the reduction or the oxidation of the electrochromic compound by the redox agent, and

(d) the removal of the electrolyte by rinsing and/or drying.

2. The process as claimed in claim 1 , wherein the redox agent is a reducing agent for the electrochromic compound.

3. The process as claimed in claim 1 , wherein the electrically conductive substrate consists of tin-doped indium oxide (ITO), tin-doped fluorine oxide (FTO) or conductive organic polymers.

4. The process as claimed in claim 1 , wherein the reducing agent is chosen from the group formed by Ni, Mo, Cu, Co, In, Fe, Zn, Si, Ag, Ti, Al, all these metals being in the metallic state.

5. The process as claimed in claim 4 , wherein the reducing agent is chosen from the group formed by Cu, Ni, Ag, Ti and Al.

6. The process as claimed in claim 1 , wherein the electrochromic compound is chosen from hexacyanometallates, WO 3 , V 2 O 5 , NiO, and electrochromic polymers.

7. The process as claimed in claim 1 , wherein the redox agent is deposited so as to be in contact with the edges of the layer of electrochromic compound or in the vicinity of these edges.

8. The process as claimed in claim 1 , wherein the redox agent is deposited in one or more continuous regions or in a multitude of discrete points.

9. The process as claimed in claim 1 , wherein the contacting in step (c) is carried out by immersion in the liquid electrolyte or by spraying of the liquid electrolyte.

10. The process as claimed in claim 1 , wherein the contacting time, in step (c), is between 30 seconds and 15 minutes.

11. The process as claimed in claim 10 , wherein the contacting time, in step (c), is between 1 minute and 8 minutes.

12. A process for manufacturing an electrochromic article comprising the following successive steps:

(a) the deposition of a layer comprising a redox agent, which is a reducing agent or an oxidizing agent for an electrochromic compound, on the surface of a transparent or translucent electrically conductive substrate, said redox agent covering only one portion of the substrate of said electrically conductive substrate and leaving free at least one other portion thereof;

(b) the deposition of a layer of the electrochromic compound on the portion of the surface of the electrically conductive substrate not covered by the redox agent;

(c) the contacting of the layer of redox agent, deposited in step (a), and the layer of electrochromic compound, deposited in step (b), with a liquid electrolyte for a sufficient time to enable the reduction or the oxidation of the electrochromic compound by the redox agent; and

(d) the removal of the electrolyte by rinsing and/or drying.