IP Library Granted Patent US 9,663,641
Granted Patent B2
US 9,663,641 · App. 13/700,497 · Granted May 30, 2017

Method of formulating low gravity sponge rubber for automotive weatherstrips

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Quick Facts
Patent No.
US 9,663,641
App. No.
13/700,497
Granted
May 30, 2017
Kind
B2
Abstract

The invention relates to automotive weatherstrip material. More specifically, the invention utilizes thermo-expandable microspheres in the sponge bulb member of the weatherstrip to produce a microcellular structure which provides a lower weight weatherstrip material with improved surface appearance and comparable stiffness to known materials for use in the automotive industry, and exhibiting a blown specific gravity of less than about 0.60 g/cc.

Claims (32)

1. An automotive weatherstrip comprising a dense main body member and a less dense sponge bulb member, wherein the sponge bulb member comprises:

an inner pore structure comprising open pores having a cross-sectional diameter of up to about 110 μm, and

a smooth exterior surface finish;

wherein the sponge bulb member has a blown specific gravity of less than or equal to about 0.40 g/cc;

wherein the sponge bulb member does not comprise thermoplastic vulcanizates;

wherein the sponge bulb member comprises an ethylene propylene diene terpolymer (EPDM);

wherein the EPDM of the sponge bulb member is a thermoset material; and

wherein the main body member comprises a thermoset EPDM.

2. The automotive weatherstrip of claim 1 wherein the sponge bulb portion is formed from a composition comprising the thermoset EPDM and a thermoexpandable microsphere physical blowing agent.

3. The automotive weatherstrip of claim 2 wherein the thermoexpandable microsphere blowing agent is included as about 40% to about 100% of the total blowing agent.

4. The automotive weatherstrip of claim 2 wherein the thermoexpandable microsphere blowing agent comprises microspheres having an acrylonitrile shell and a hydrocarbon fill.

5. The automotive weatherstrip of claim 4 wherein at process temperatures of about 80°-205° C. the shell ruptures and releases the hydrocarbon fill which has volatilized, rendering a substantially uniform microcellular structure within the sponge bulb member wherein the pores exhibit a cross-sectional diameter of about 100 μm.

6. The weatherstrip of claim 2 , wherein the thermoexpandable microsphere physical blowing agent has an average particle diameter of from about 5 μm to about 50 μm.

7. The weatherstrip of claim 2 , wherein the thermoexpandable microsphere physical blowing agent has an average particle diameter of from about 8 μm to about 16 μm.

8. The automotive weatherstrip of claim 1 wherein the pores are substantially spherical.

9. The weatherstrip of claim 1 , wherein the blown specific gravity is less than or equal to 0.358 g/cc.

10. The weatherstrip of claim 1 , wherein the sponge bulb member has a compression load deflection of from 0.1833 N/mm 2 to 0.2120 N/mm 2 .

11. An automotive weatherstrip comprising:

a dense main body member including a mounting member that secures the body member to a first surface of abutting, first and second surfaces of an associated vehicle; and

a sponge bulb member extending from the body member and dimensioned to selectively engage the second surface of the associated vehicle, wherein the sponge bulb member is less dense than the main body member, and comprises:

an inner pore structure comprising open pores having a cross-sectional diameter of up to about 110 μm, and

a smooth exterior surface finish;

wherein the sponge bulb member has a blown specific gravity of less than or equal to 0.40 g/cc;

wherein the sponge bulb member does not comprise thermoplastic vulcanizates;

wherein the sponge bulb member comprises an ethylene propylene diene terpolymer (EPDM);

wherein the EPDM of the sponge bulb member is a thermoset material; and

wherein the main hod member comprises a thermoset EPDM.

12. The weatherstrip of claim 11 wherein the sponge bulb member has a substantially uniform microcellular structure within the sponge bulb member wherein the pores exhibit a cross-sectional diameter of about 100 μm.

13. The weatherstrip of claim 11 wherein the pores are substantially spherical.

14. The weatherstrip of claim 11 wherein the main body member comprises at least in part a thermoplastic component.

15. The weatherstrip of claim 11 wherein the sponge bulb member has a Shore A hardness of at least 42, +/−2.

16. The weatherstrip of claim 11 wherein the sponge bulb member has a percent water absorption of approximately 8%.

Assignments (11)
RELEASE OF SECURITY INTEREST IN PATENTS PREVIOUSLY RECORDED AT REEL/FRAME (062545/0715) Recorded Mar 4, 2026
From: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
To: COOPER-STANDARD AUTOMOTIVE INC.; COOPER-STANDARD INDUSTRIAL AND SPECIALTY GROUP, LLC
Reel/Frame 075022/0267 →
RELEASE OF SECURITY INTEREST IN PATENTS PREVIOUSLY RECORDED REEL/FRAME (062544/0357) Recorded Mar 4, 2026
From: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
To: COOPER-STANDARD AUTOMOTIVE INC.; COOPER-STANDARD INDUSTRIAL AND SPECIALTY GROUP, LLC
Reel/Frame 075022/0543 →
PATENT SECURITY AGREEMENT (3RD LIEN) Recorded Jan 30, 2023
From: COOPER-STANDARD AUTOMOTIVE INC.; COOPER-STANDARD INDUSTRIAL AND SPECIALTY GROUP, LLC
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 062545/0715 →
PATENT SECURITY AGREEMENT (1ST LIEN) Recorded Jan 30, 2023
From: COOPER-STANDARD AUTOMOTIVE INC.; COOPER-STANDARD INDUSTRIAL AND SPECIALTY GROUP, LLC
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 062544/0357 →
TERMINATION AND RELEASE OF SECURITY INTEREST PREVIOUSLY RECORDED AT REEL/FRAME (032608/0179) Recorded Jan 29, 2023
From: DEUTSCHE BANK AG NEW YORK BRANCH, AS COLLATERAL AGENT
To: COOPER-STANDARD AUTOMOTIVE INC.
Reel/Frame 062540/0124 →
TERMINATION AND RELEASE OF SECURITY INTEREST PREVIOUSLY RECORDED AT REEL/FRAME (052788/0392) Recorded Jan 27, 2023
From: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION (SUCCESSOR IN INTEREST TO U.S. BANK NATIONAL ASSOCIATION), AS COLLATERAL AGENT
To: COOPER-STANDARD AUTOMOTIVE INC
Reel/Frame 062540/0108 →
PATENT SECURITY AGREEMENT Recorded May 29, 2020
From: COOPER-STANDARD AUTOMOTIVE INC.
To: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 052788/0392 →
AMENDED AND RESTATED PATENT SECURITY AGREEMENT Recorded Nov 2, 2016
From: COOPER-STANDARD AUTOMOTIVE INC.
To: BANK OF AMERICA, N.A., AS AGENT
Reel/Frame 040545/0476 →
SECURITY INTEREST Recorded Apr 4, 2014
From: COOPER STANDARD AUTOMOTIVE INC.
To: BANK OF AMERICA, N.A., AS AGENT
Reel/Frame 032611/0388 →
SECURITY INTEREST Recorded Apr 4, 2014
From: COOPER-STANDARD AUTOMOTIVE INC.
To: DEUTSCHE BANK AG NEW YORK BRANCH, AS COLLATERAL AGENT
Reel/Frame 032608/0179 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 28, 2012
From: GOPALAN, KRISHNAMA CHARI; LENHART, ROBERT
To: COOPER STANDARD AUTOMOTIVE INC.
Reel/Frame 029362/0991 →