Method for improving the flatness of graphite film, graphite film, and method for producing same
View Patent ↗When a raw material graphite film bad in flatness is laminated onto another material, creases and other defects may be caused. In particular, when a graphite film having a large area is laminated, defects such as creases may be often caused. In order to solve such defects, a flatness correction treatment step is performed wherein a raw material graphite film is subjected to heat treatment up to 2000° C. or higher while a pressure is applied thereto. This flatness correction treatment gives a graphite film good in flatness. Furthermore, when the flatness of the raw material graphite film is corrected by use of a thermal expansion of a core, a graphite film small in sagging can be obtained.
1. A method for producing a single layer graphite film, comprising a flatness correction treatment step of subjecting a raw material graphite film consisting of a graphite single layer to heat treatment at a temperature of 2000 C or higher while a pressure is applied to the raw material graphite film.
2. The method for producing a graphite film according to claim 1 , wherein the raw material graphite film employed in the flatness correction treatment step is a raw material graphite film obtained by heat treatment and then caused to undergo a condition of a temperature lower than 2000° C. at least once prior to the flatness correction treatment step.
3. The method for producing a graphite film according to claim 1 , wherein a carbonizing step and the flatness correction treatment step are included in a series of steps for producing the graphite film.
4. The method for producing a graphite film according to claim 1 , wherein the raw material graphite film has a thermal diffusivity of 0.15 cm 2 /s or more in a plane direction of the film.
5. The method for producing a graphite film according to claim 1 , wherein after the flatness correction treatment step is performed, the value obtained by dividing a sagging Zgs of the graphite film in sagging evaluation described in JIS C2151 by a width Ugs thereof, of Zgs/Ugs is 0.2 or less.
6. The method for producing a graphite film according to claim 1 , wherein in the flatness correction treatment step, the raw material graphite film is subjected to the heat treatment in a state of being wound around a core.
7. The method for producing a graphite film according to claim 6 , wherein the core has a diameter of 20 mm or more.
8. The method for producing a graphite film according to claim 6 , wherein the core has a thermal expansion coefficient of 0.3×10 −6 /K or more and 7.5×10 −6 /K or less.
9. The method for producing a graphite film according to claim 1 , comprising, before the flatness correction treatment step, a re-winding step of winding the raw material graphite film around a core.
10. The method for producing a graphite film according to claim 9 , wherein in the re-winding step, the raw material graphite film is wound and fastened with a winding fastening strength of 10 N·m/m or more.
11. A method for correcting the flatness of a single layer graphite film, wherein a raw material graphite film consisting of a graphite single layer is subjected to heat treatment at a temperature of 2000 C or higher while a pressure is applied to the raw material graphite film.
12. The method for producing a graphite film according to claim 1 , wherein the resulting graphite film has a thermal diffusivity in a plane direction of 5.0 cm 2 /s or more, a thickness of 7 μm or more and 120 μm or less, a width Ugs of 100 mm or more, and an area of 5 m 2 or more.