Interlock and process
View Patent ↗The present invention relates to production of polymer, and in particular provides an interlock for use in a process for production of a polymer in a reactor, which process comprises: a. polymerising a monomer and optionally a comonomer in the reactor to produce polymer, optionally in the presence of an inert hydrocarbon, and b. withdrawing produced polymer from the reactor, said interlock being based on the temperature in the reactor, and comprising: 1. measuring the temperature in the reactor or a temperature representative of the temperature in the reactor, and 2. comparing said measured temperature to a threshold temperature, said interlock being characterized in that withdrawal is allowed if the measured temperature is greater than the threshold temperature but is prevented if the measured temperature is lower than the threshold temperature.
1. An interlock for use in a process for production of a polymer in a reactor, which process comprises:
a. polymerising a monomer and optionally a comonomer in the reactor to produce polymer, optionally in the presence of an inert hydrocarbon, and
b. withdrawing produced polymer from the reactor, said interlock being based on the temperature in the reactor, and comprising the capabilities of:
1. measuring the temperature in the reactor or a temperature representative of the temperature in the reactor, and
2. comparing said measured temperature to a threshold temperature, said interlock being characterised in that withdrawal is allowed if the measured temperature is greater than the threshold temperature but is prevented if the measured temperature is lower than the threshold temperature.
2. An interlock for use in a process for production of a polymer in a reactor, which process comprises:
a. polymerising a monomer and optionally a comonomer in the reactor to produce polymer, optionally in the presence of an inert hydrocarbon, and
b. withdrawing produced polymer from the reactor,
said interlock being based on the pressure and the temperature in the reactor, and comprising the capabilities of:
1. measuring the pressure in the reactor or a pressure representative of the pressure in the reactor,
2. measuring the temperature in the reactor or a temperature representative of the temperature in the reactor,
3. comparing said measured pressure to a threshold pressure,
4. comparing said measured temperature to a threshold temperature, said interlock being characterised in that withdrawal is allowed if either:
1. the measured pressure in the reactor is less than the threshold pressure, or
2. the measured pressure in the reactor is greater than the threshold pressure and the measured temperature is greater than the threshold temperature,
but is prevented if the measured pressure in the reactor is greater than the threshold pressure but the measured temperature is lower than the threshold temperature.
3. An interlock according to claim 2 wherein the threshold pressure is between 500 and 1500 kPa.
4. An interlock according to claim 1 wherein the threshold temperature is variable and is based on the total partial pressure in the reactor of hydrocarbons.
5. An interlock according to claim 2 wherein the threshold temperature is variable and is based on the total partial pressure in the reactor of hydrocarbons.
6. An interlock according to claim 1 wherein the polymerisation reaction of step (a) is a gas phase process, for example a fluidised bed or stirred bed gas phase polymerisation process.
7. An interlock according to claim 2 wherein the polymerisation reaction of step (a) is a gas phase process, for example a fluidised bed or stirred bed gas phase polymerisation process.
8. An interlock according to claim 6 , wherein the process comprises:
a. polymerising a monomer and optionally a comonomer in the reactor in the gas phase to produce polymer, in the presence of one or more inert hydrocarbons having 5 or more carbon atoms, and
b. withdrawing produced polymer from the reactor, and characterised in that the threshold temperature is dependent on the partial pressure in the reactor of inert hydrocarbons having 5 or more carbon atoms.
9. An interlock according to claim 8 wherein the threshold temperature varies according to the formula:
T t =T f +Σ i A i ·PP i (1)
wherein:
T t is the threshold temperature,
T f is a temperature constant,
i is at least 5 and is the number of carbon atoms in an inert hydrocarbon present in the reactor,
A i , is a positive constant (for inert hydrocarbons with i carbon atoms), and
PP i , is the partial pressure in the reactor of inert hydrocarbons having i carbon atoms.
10. An interlock according to claim 9 wherein T f is in the range 70 to 80° C., and A i 's are in the range 0.5 to 2.5° C. per 10 kPa (5 to 25°/bar).
11. An interlock according to claim 10 wherein A 5 is in the range 0.5 to 1.0° C. per 10 kPa (5 to 10°/bar), A 6 is in the range 1.0 to 1.5° C. per 10 kPa (10 to 15°/bar) and A8 is in the range 1.5 to 2.0° C. per 10 kPa (15 to 20°/bar).
12. An interlock according to claim 7 , wherein the process comprises:
a. polymerising a monomer and optionally a comonomer in the reactor in the gas phase to produce polymer, in the presence of one or more inert hydrocarbons having 5 or more carbon atoms, and
b. withdrawing produced polymer from the reactor, and characterised in that the threshold temperature is dependent on the partial pressure in the reactor of inert hydrocarbons having 5 or more carbon atoms.
13. An interlock according to claim 12 wherein the threshold temperature varies according to the formula:
T t =T f +Σ i A i ·PP i (1)
wherein:
T t is the threshold temperature,
T f is a temperature constant,
i is at least 5 and is the number of carbon atoms in an inert hydrocarbon present in the reactor,
A i , is a positive constant (for inert hydrocarbons with i carbon atoms), and
PP i , is the partial pressure in the reactor of inert hydrocarbons having i carbon atoms.
14. An interlock according to claim 13 wherein T f is in the range 70 to 80° C., and i 's are in the range 0.5 to 2.5° C. per 10 kPa (5 to 25°/bar).
15. An interlock according to claim 14 wherein A 5 is in the range 0.5 to 1.0° C. per 10 kPa (5 to 10°/bar), A 6 is in the range 1.0 to 1.5° C. per 10 kPa (10 to 15°/bar) and A8 is in the range 1.5 to 2.0° C. per 10 kPa (15 to 20°/bar).
16. An interlock according to claim 1 wherein the polymerisation reaction of step (a) is a process for polymerisation of ethylene or propylene as monomer.
17. An interlock according to claim 16 wherein there is used a comonomer having 4 to 12 carbon atoms, for example 1-butene, 1-hexene or 1-octene.
18. An interlock according to claim 2 wherein the polymerisation reaction of step (a) is a process for polymerisation of ethylene or propylene as monomer.
19. An interlock according to claim 18 wherein there is used a comonomer having 4 to 12 carbon atoms, for example 1-butene, 1-hexene or 1-octene.
20. A process for production of a polymer in a reactor, which process comprises:
a. polymerising a monomer and optionally a comonomer in the reactor to produce polymer, optionally in the presence of an inert hydrocarbon, and
b. withdrawing produced polymer from the reactor, said process using an interlock according to claim 1 .
21. A process according to claim 20 wherein the process is a process for polymerisation of ethylene or propylene as monomer.
22. A process according to claim 21 wherein the process is a gas phase process, for example a fluidised bed or stirred bed gas phase polymerisation process.
23. A process for production of a polymer in a reactor, which process comprises:
a. polymerising a monomer and optionally a comonomer in the reactor to produce polymer, optionally in the presence of an inert hydrocarbon, and
b. withdrawing produced polymer from the reactor, said process using an interlock according to claim 2 .
24. A process according to claim 23 wherein the process is a process for polymerisation of ethylene or propylene as monomer.
25. A process according to claim 24 wherein the process is a gas phase process, for example a fluidised bed or stirred bed gas phase polymerisation process.