Film composition and method of making the same
View Patent ↗Films including at least one layer of a blend of a cyclic olefin copolymer and a hydrocarbon wax are described. Particularly, films including 75.0 wt % to 99.9 wt % of a copolymer of a cyclic olefin monomer and an acyclic olefin and 0.1 wt % to 25.0 wt % of a hydrocarbon wax are described. Methods of making such films are also disclosed.
1. An oriented film comprising at least a first layer and a core layer comprising a polypropylene homopolymer or copolymer, the first layer comprising:
a) 75.0 wt % to 99.9 wt % of a copolymer of a cyclic olefin monomer and an acyclic olefin, the copolymer having a glass transition temperature, T g ; and
b) 0.1 wt % to 25.0 wt % of a hydrocarbon wax;
wherein T g is ≦ the melting point (mp) of the hydrocarbon wax;
wherein the first layer comprises less than 2.0 wt % polyethylene and has a haze value of 1.0 % or less according to ASTM D 1003;
wherein the oriented, polypropylene film is non-metallized.
2. The film of claim 1 , wherein T g ≦mp≦T g +20.0° C.
3. The film of claim 1 , wherein T g ≦mp≦T g +10.0° C.
4. The film of claim 1 , wherein the cyclic olefin monomer has 4 to 12 carbon atoms.
5. The film of claim 1 , wherein cyclic olefin monomer is a norbornene.
6. The film of claim 1 , wherein the acyclic olefin is selected from a group consisting of ethylene, propylene, butylene, and mixtures thereof.
7. The film of claim 1 , wherein hydrocarbon wax is a microcrystalline wax.
8. The film of claim 1 , wherein the first layer comprises less than 2.0 wt % to about 0.5 wt % of the hydrocarbon wax.
9. The film of claim 1 , wherein the first layer is substantially free of a polyethylene.
10. The film according to claim 1 , wherein the defect number of the film is at least 70% less than the defect number of a comparative film that lacks the hydrocarbon wax.
11. The film according to claim 1 , wherein the defect number of the film is at least 90% less than the defect number of a comparative film that lacks the hydrocarbon wax.
12. The film according to claim 1 , wherein the defect number of the film is at least 70% less than the defect number of a film that includes the same cyclic olefin copolymer resin and 2.5 wt % to 5 wt % polyethylene.
13. The film of according to claim 1 , wherein the hydrocarbon wax has a viscosity of 80 to 120 SUS according to ASTM D-88 at 99° C., a penetration value of 5 to 10 dmm according to ASTM D-1321 at 25° C., and a melting point of 80 to 100° C.
14. An oriented film comprising at least a first layer and a core layer comprising a polypropylene homopolymer or copolymer, the first layer, comprising:
a) 95 wt % to 99.9 wt % of a copolymer of a norbornene and ethylene, the copolymer having a glass transition temperature, T g ; and
b) 0.1 wt % to 5 wt % of a hydrocarbon wax having a melting point (mp), wherein the mp is within 20° C. of the T g ;
wherein the first layer comprises less than 2.0 wt % polyethylene and has a haze value of 1.0% or less according to ASTM D 1003;
wherein the film is non-metallized.
15. The film of claim 14 , wherein T g ≦mp≦T g +20.0° C.
16. The film of any of claim 14 , further comprising a second layer having an upper surface and a lower surface, wherein the upper surface of the second layer is in surface contact with a lower surface of the first layer.
17. The film of claim 16 , wherein the second layer is a tie layer or a core layer.
18. The film of claim 16 , wherein the second layer comprises 50.0 wt % to 100 wt % of a propylene-based homopolymer or copolymer and 0 wt % to 50.0 wt % of a propylene-based elastomer.
19. The film of claim 14 , wherein the hydrocarbon wax is a microcrystalline wax.
20. The film of claim 14 , wherein the hydrocarbon wax has a viscosity of 80.0 to 120.0 SUS according to ASTM D-88 at 99° C.
21. The film of claim 14 , wherein the hydrocarbon wax has a penetration value of 5 to 10 dmm according to ASTM D-1321 at 25° C.
22. A method of making a non-metallized, multilayer film comprising:
a) combining 75.0 wt % to 99.9 wt % of a copolymer of a cyclic olefin monomer having 4 to 12 carbon atoms and an acyclic olefin with 0.1 wt % to 25.0 wt % of a hydrocarbon wax to form a blend;
b) feeding the blend to an extruder;
c) co-extruding the blend with at least a polypropylene material for form a first layer of the non-metallized, multilayer film, wherein the first layer is substantially free of a polyethylene; and
d) orienting the non-metallized, multilayer film in at least one of MD, TD, or both, the non-metallized, multilayer film having a haze value of 1.0 or less according to ASTM D 1003.
23. An oriented, non-metallized, multi-layer film comprising:
a) a first layer comprising:
i) 75.0 wt % to 99.9 wt % of a copolymer of a cyclic olefin monomer and an acyclic olefin, the copolymer having a glass transition temperature, T g ; and
ii) 0.1 wt % to 25.0 wt % of a hydrocarbon wax having an average chain length between 22 and 65 carbon atoms;
b) a second polypropylene layer having a first surface and a second surface, wherein the first surface is in surface contact with the first layer; and
c) a third layer in surface contact with the second surface of the second layer, the third layer comprising:
i) 75.0 wt % to 99.9 wt % of a copolymer of a cyclic olefin monomer and an acyclic olefin, the copolymer having a glass transition temperature, T g ; and
ii) 0.1 to 25.0 wt % of a hydrocarbon wax; and
wherein the first layer comprises less than 2.0 wt % polyethylene and has a haze value of 1.0% or less according to ASTM D 1003 for the non-metallized, multi-layer film.