Cyclopropene compositions
Stabilized liquid cyclopropene compositions are provided which comprise flowable, non-aqueous dispersion concentrates comprising a) a continuous substantially water-immiscible liquid phase and b) a dispersed solid phase comprising cured polymer particles prepared from a polymerizable thermoset resin which particles contain at least one cyclopropene complex, optionally a non-porous particulate mineral, and optionally a non-cross-linkable mobile chemical distributed therein, and wherein the outside surfaces of the particles comprise a colloidal solid material. The compositions of the invention can be used directly or with dilution to combat pests or as plant growth regulators.
1. A non-aqueous liquid dispersion concentrate composition comprising
(a) a continuous substantially water-immiscible, non-aqueous liquid phase which is selected from the group consisting of vegetable oils, silicone oils, methylated vegetable oils, refined paraffinic hydrocarbons, mineral oils, and mixtures thereof;
(b) a dispersed solid phase comprising polymer particles having a complex of α-cyclodextrin and 1-methylcyclopropene distributed therein prepared from:
(i) dissolving or suspending the α-cyclodextrin 1-methylcyclopropene complex in a nonaqueous curable liquid mixture comprising a curable or polymerizable thermoset epoxy
(ii) emulsifying said solution or suspension into a water-immiscible, non-aqueous liquid to a mean droplet size of 1-200 microns, which liquid also contains a colloidal solid emulsion stabilizer, and
(iii) effecting crosslinking, polymerization or cure of the curable or polymerizable thermoset epoxy resin mixture to produce the dispersed polymer particles having the α-cyclodextrin 1-methylcyclopropene complex distributed therein.
2. The composition of claim 1 , wherein the dispersed phase comprises at least one non-cross-linkable mobile chemical such that the extraction of this chemical from the disperse phase renders it porous in a manner that allows the 1-methylcyclopropene to diffuse out at a controlled rate.
3. The composition of claim 1 , wherein the continuous phase (a) further comprises at least one agrochemically active ingredient.
4. The composition of claim 1 , wherein (a) further comprises one or more surfactants or dispersants.
5. The composition of claim 1 , wherein (b) further comprises a particulate inorganic material distributed within the polymer particles.
6. The composition of claim 1 , wherein the polymer particles are from bisphenol A epoxy resin.
7. The composition of claim 1 , wherein the polymer particles are from biodegradable thermoset resin.
8. The composition of claim 6 , wherein (b) comprises a cured epoxy resin polymer matrix prepared from curing an epoxy resin selected from the group consisting of di- and polyepoxide monomers, prepolymers or blends thereof with a hardener selected from rimary and secondary amines and their adducts, cyanamide, dicyandiamide, polycarboxylic acids, anhydrides of polycarboxylic acids, polyamines, polyamino-amides, polyadducts of amines and polyepoxides, polyols and mixtures thereof.
9. The composition of claim 2 , wherein the non-cross-linkable mobile chemical in the disperse phase also functions as a surfactant or dispersant.
10. A method of regulating plant growth by diluting an effective amount of concentrate composition according to claim 1 with an aqueous liquid carrier selected from water and liquid fertilizer, and applying the dilute composition to the plant species or locus thereof.
11. The composition of claim 1 , wherein the colloidal solids at the surface of the polymer particles are dispersed in the non-aqueous liquid after polymerization or curing.
12. The composition of claim 1 , wherein the colloidal solids are embedded in the polymer particle.
13. A non-aqueous liquid dispersion concentrate composition, comprising:
a polymer particle, comprising:
a body formed from a polymerizable resin;
an alkyl-cyclopropene and a molecular encapsulating agent complex dispersed within the body; and
a colloidal solid embedded within the body; and
a continuous substantially water-immiscible, non-aqueous liquid phase which is selected from the group consisting of vegetable oils, silicone oils, methylated vegetable oils, refined paraffinic hydrocarbons, mineral oils, and mixtures thereof.