Polyalkyl(meth)acrylate for improving lubricating oil properties
View Patent ↗The invention relates to a polyalkyl (meth) acrylate for improving lubricating oil properties, which comprises repetition units which are derived from (meth) acrylates having 6 to 22 carbon atoms in the alcohol residues, and repetition units which are derived from amine derivatives of an ethylenically unsaturated monomer. The invention further relates to methods for producing and using the present polyalkyl (meth) acrylate.
1. A polyalkyl(meth)acrylate being a graft copolymer, wherein:
a graft base of the graft copolymer comprises:
a) from 0 to 40% by weight of a repeat unit derived from a (meth)acrylate of formula (I)
b) from 20 to 99.9% by weight of a repeat unit derived from a (meth)acrylate of formula (II)
and
c) from 0 to 20% by weight of a repeat unit derived from a (meth)acrylate of formula (III)
wherein each R is independently hydrogen or methyl,
R 1 is an alkyl radical having from 1 to 5 carbon atoms,
R 2 is an alkyl radical having from 6 to 22 carbon atoms, and
R 3 is an alkyl radical having from 23 to 4000 carbon atoms, and
a graft of the graft copolymer comprises
d) from 0.1 to 10% by weight of a repeat unit derived from an amine derivative of a polar ethylenically unsaturated monomer,
wherein the polar ethylenically unsaturated monomer is maleic acid anhydride and the amine derivative is derived from N-phenyl-1,4-phenylenediamine.
2. The polyalkyl(meth)acrylate of claim 1 ,
wherein the polyalkyl(meth)acrylate has a specific viscosity in the range from 5 to 35 ml/g at 100° C.
3. The polyalkyl(meth)acrylate of claim 1 , comprising:
a repeat unit derived from a styrene monomer.
4. The polyalkyl(meth)acrylate of claim 3 ,
wherein the polyalkyl(meth)acrylate comprises 0.1 to 20% by weight of the repeat unit derived from a styrene monomer.
5. The polyalkyl(meth)acrylate of claim 1 , comprising:
a) from 0 to 40% by weight of a repeat unit derived from a (meth)acrylate of formula (I)
b) from 50 to 999% by weight of a repeat unit derived from a (meth)acrylate of formula (II)
c) from 0.5 to 20% by weight of a repeat unit derived from a (meth)acrylate of formula (III)
and
d) from 0.1 to 10% by weight of a repeat unit derived from an amine derivative of a polar ethylenically unsaturated monomer,
wherein each R is independently hydrogen or methyl,
R 1 is an alkyl radical having from 1 to 5 carbon atoms,
R 2 is an alkyl radical having from 6 to 22 carbon atoms, and
R 3 is an alkyl radical having from 23 to 4000 carbon atoms.
6. A process for preparing the polyalkyl(meth)acrylate of claim 1 , the process comprising:
preparing the graft base: subsequently
grafting the polar ethylenically unsaturated monomer onto the graft base, and then reacting the resulting polymer with an amine.
7. The process of claim 6 , wherein the polymerizing comprises:
preparing a graft base by polymerizing the (meth)acrylate having from 6 to 22 carbon atoms, and subsequently
grafting the polar ethylenically unsaturated monomer onto the graft base.
8. A lubricant composition comprising the polyalkyl(meth)acrylate of claim 1 .
9. The lubricant composition of claim 8 , comprising from 0.01 to 30% by weight of the polyalkyl(meth)acrylate.
10. A method of reducing friction, comprising:
applying the composition of claim 8 to a composition or apparatus in need thereof.
11. The polyalkyl(meth)acrylate of claim 1 , wherein the repeat unit derived from the (meth)acrylate of formula (III) comprises a polyolefin-based repeat unit having a number-average molecular weight of from 500 to 50,000 g/mol.
12. The polyalkyl(meth)acrylate of claim 5 , wherein the repeat unit derived from the (meth)acrylate of formula (III) comprises a polyolefin-based repeat unit having a number-average molecular weight of from 500 to 50,000 g/mol.