Anti-reflection film and method for manufacturing the same
Disclosed is an anti-reflection film comprising a high refractive index layer comprising a first binder including a crosslinked polymer of a multifunctional (meth)acrylate compound, and nano silica particles dispersed in the first binder; and a low refractive index layer laminated on the high refractive index layer, and comprising a second binder including a crosslinked copolymer of a multifunctional (meth)acrylate compound and a fluorine-based (meth)acrylate compound, and hollow silica particles and hollow silica particles coated with a fluorine-based compound on the surface, which are dispersed in the second binder, wherein the weight ratio of the hollow silica particles to the hollow silica particles coated with a fluorine-based compound is 1:1˜10. Also disclosed is a method for manufacturing the anti-reflection film using a composition that is separated into at least two layers by phase separation after single layer coating by a more simplified process.
1. An anti-reflection film comprising:
a high refractive index layer comprising a first binder including a crosslinked polymer of a multifunctional (meth)acrylate compound, and nano silica particles dispersed in the first binder; and
a low refractive index layer laminated on the high refractive index layer, and comprising a second binder including a crosslinked copolymer of a multifunctional (meth)acrylate compound and a fluorine-based (meth)acrylate compound, and hollow silica particles and hollow silica particles coated with a fluorine-based compound on the surface, which are dispersed in the second binder,
wherein the weight ratio of the hollow silica particles to the hollow silica particles coated with the fluorine-based compound in the low refractive index layer is 1:1˜10, and
wherein the hollow silica particles coated with a fluorine-based compound on the surface in the low refractive index layer has a distribution gradient increasing toward a direction away from the high refractive index layer.
2. The anti-reflection film according to claim 1 , wherein the high refractive index layer has a refractive index of 1.5 to 1.58, and the low refractive index has a refractive index of 1.1 to 1.45.
3. The anti-reflection film according to claim 1 , wherein the fluorine-based compound coated on the hollow silica particles has a refractive index of 1.3˜1.4 and surface tension of 10˜25 mN/m.
4. The anti-reflection film according to claim 1 , wherein the fluorine-based compound coated on the hollow silica particles is a fluorine-containing alkoxysilane compound.
5. The anti-reflection film according to claim 1 , wherein the fluorine-based compound coated on the hollow silica particles is at least one selected from the group consisting of tridecafluorooctyl triethoxy silane, heptadecafluorodecyl trimethoxy silane, and heptadecafluorodecyl triisopropoxy silane.
6. The anti-reflection film according to claim 1 , wherein the fluorine-based (meth)acrylate compound is at least one selected from the group consisting of the following Chemical Formula 1 to 5:
in the Chemical Formula 1, R 1 is a hydrogen or C1-C6 alkyl group, a is an integer of from 0 to 7, and b is an integer of from 1 to 3;
in the Chemical Formula 2, c is an integer of form 1 to 10;
in the Chemical Formula 3, d is an integer of from 1 to 11;
in the Chemical Formula 4. e is an integer of from 1 to 5:
in the Chemical Formula 5, f is an integer of from 4 to 10.
7. The anti-reflection film according to claim 1 , wherein the nano silica particles in the high refractive index layer have a number average particle diameter of 100 nm or less.
8. The anti-reflection film according to claim 1 , wherein the hollow silica particles and the hollow silica particles coated with the fluorine-based compound in the low refractive index layer respectively have a number average particle diameter of 1 to 200 nm.