Anti-glare coating composition and anti-glare coating film having superior abrasion resistance and contamination resistance
An exemplary embodiment of the present invention relates to an anti-glare coating composition and anti-glare coating film having excellent abrasion resistance and contamination resistance. The anti-glare coating composition according to the exemplary embodiment of the present invention comprises a) a binder resin; b) a fluorine-based UV curable functional group-containing compound; c) a photoinitiator; d) a surface curable photoinitiator; and e) a particulate of which a surface has an uneven pattern. In the case where a film is formed by using the anti-glare coating composition according to the exemplary embodiment of the present invention, it is possible to provide both abrasion resistance and contamination resistance by a single coating method, to maintain characteristics of abrasion resistance and contamination resistance when the film is rubbed, and to decrease and easily remove contamination by an oil component, such as a fingerprint mark.
1. An anti-glare coating composition, comprising:
a) a binder resin;
b) a fluorine-based UV curable functional group-containing compound;
c) a photoinitiator;
d) a surface curable photoinitiator; and
e) a particulate having a surface, the surface having an uneven pattern,
wherein the particulate has an average surface roughness ([Rz]) of 0.1 to 2 μm,
the content of c) the photoinitiator on the basis of 100 parts by weight of a) the binder resin is 1 to 20 parts by weight,
the content of d) the surface curable photoinitiator on the basis of 100 parts by weight of b) the fluorine-based UV curable functional group-containing compound is 5 to 40 parts by weight,
an average particle diameter of the particulate is 1 to 10 μm,
the content of e) the particulate of a surface having the uneven pattern on the basis of 100 parts by weight of a) the binder resin is 0.5 to 50 parts by weight, and
b) the fluorine-based UV curable functional group-containing compound comprises one or more selected from the compounds that are represented by the following Formulas 1 to 9:
in Formulas 1 to 9, X and Y are each independently F or CF 3 , Z is H or CH 3 , a, j and m are each an integer of 1 to 16, c, k and n are each an integer of 0 to 5, b, d, e, f and g are each an integer of 0 to 200, h and i are each an integer of 0 to 16, and PFPE has the following structures,
wherein a to i, X and Y are the same as the definitions of Formula 1.
2. The anti-glare coating composition according to claim 1 , wherein the content of b) the fluorine-based UV curable functional group-containing compound on the basis of 100 parts by weight of a) the binder resin is 1 to 50 parts by weight.
3. The anti-glare coating composition according to claim 1 , wherein a) the binder resin comprises a UV curable functional group-containing binder resin.
4. The anti-glare coating composition according to claim 1 , wherein b) the fluorine-based UV curable functional group-containing compound comprises one or more selected from acrylates, methacrylates, and vinyls comprising a perfluoro group.
5. The anti-glare coating composition according to claim 1 , wherein d) the surface curable photoinitiator comprises an alpha-hydroxyketone compound.
6. An anti-glare coating film, comprising:
the anti-glare coating composition according to claim 1 .
7. The anti-glare coating film according to claim 6 , wherein a thickness is 0.5 to 300 μm.
8. The anti-glare coating film according to claim 6 , wherein a substrate is provided on at least one side thereof.
9. A method for manufacturing an anti-glare coating film, comprising:
coating the anti-glare coating composition according to claim 1 on a substrate; and
drying and photocuring the coated anti-glare coating composition.
10. The method for manufacturing an anti-glare coating film according to claim 9 , wherein a coating thickness of the anti-glare coating composition is 0.5 to 300 μm.
11. A display device, comprising:
an anti-glare coating film according to claim 6 .
12. The display device according to claim 11 , wherein the display device comprises any one of a liquid crystal display (LCD), an organic light emitting display (OLED), and a plasma display panel (PDP).